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Chemistry
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Chemistry and Chemical Reactivity
Quiz 17: Principles of Chemical Reactivity: Other Aspects of Aqueous Equilibria
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Question 1
Multiple Choice
What is the pH of a buffer that results when 0.50 mole of H
3
PO
4
is mixed with 0.25 mole of NaOH and diluted with water to 1.00 L? (The acid dissociation constants of phosphoric acid are K
a1
= 7.5 × 10
-3
,K
a2
= 6.2 × 10
-8
,and K
a3
= 3.6 × 10
-13
)
Question 2
Multiple Choice
What will be the pH of the solution when 0.10 mol of H
+
ion is added to a 2.0 liter buffered solution composed of 0.45 M ammonia,NH3,and 0.26 M ammonium fluoride,NH
4
F? (K
b
for ammonia = 1.8 × 10
-5
)
Question 3
Multiple Choice
What is the pH of a solution that is 0.044 M in HA and also 0.0044 M in NaA? (K
a
= 4.7 × 10
-6
)
Question 4
Multiple Choice
Which of the following mathematical expressions is the Henderson-Hasselbalch equation?
Question 5
Multiple Choice
What is the pH of a buffer that results when 0.40 mol NaHCO
2
is mixed with 100.0 mL of 2.00 M HCl(aq) and diluted with water to 250 mL? (K
a
of HCO
2
H = 1.8 × 10
-4
)
Question 6
Multiple Choice
A 1.0-liter solution contains 0.25 M HF and 0.33 M NaF (K
a
for HF is 7.2 × 10
-4
) . If one adds 0.30 liters of 0.020 M KOH to the solution,what will be the change in pH?
Question 7
Multiple Choice
What is the pH of the buffer that results when 12.0 g of NaH
2
PO
4
and 8.00 g of Na
2
HPO
4
are diluted with water to a volume of 0.50 L? (K
a
of H
2
PO
4
-
= 6.2 × 10
-8
,the molar masses of NaH
2
PO
4
and Na
2
HPO
4
are 120.0 g/mol and 142.0 mol,respectively)
Question 8
Multiple Choice
Which of the following combinations would be best to buffer an aqueous solution at a pH of 9.24?
Question 9
Multiple Choice
Calculate the pH of a solution made by mixing 100.0 mL of 0.627 M NH
3
with 100.0 mL of 0.100 M HCl.(K
b
for NH
3
= 1.8 × 10
-5
)
Question 10
Multiple Choice
When mixed in appropriate amounts,each of the following mixtures can produce an effective buffer solution except _____.
Question 11
Multiple Choice
A 1.0 liter solution contains 0.25 M hydrogen fluoride (HF) and 0.38 M sodium fluoride (NaF) .What is the pH of this solution? (K
a
for HF is 7.2 × 10
-4
)
Question 12
Multiple Choice
A certain weak base B has a base-ionization constant K
b
of 5.9 × 10
-4
at 25°C.If strong acid is added to a solution of B,at what pH will [B] = [BH
+
]?