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Chemistry
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Chemistry Study Set 3
Quiz 14: Chemical Equilibrium
Path 4
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Question 61
Short Answer
Consider the equilibrium equation C(s)+ H
2
O(g)+ 2296 J
CO(g)+ H
2
(g).What will happen to the concentration of carbon monoxide if the temperature of this system is raised?
Question 62
Short Answer
Consider the chemical reaction 2NH
3
(g)
N
2
(g)+ 3H
2
(g).The equilibrium is to be established in a 1.0 L container at 1,000 K, where K
c
= 4.0 * 10
-2
. Initially, 1,220 moles of NH
3
(g)are present.Estimate the equilibrium concentration of N
2
(g).
Question 63
Short Answer
Ethanol and acetic acid react to form ethyl acetate and water according to the following chemical equation: C
2
H
5
OH(l)+ CH
3
COOH(l)
CH
3
COOC
2
H
5
(l)+ H
2
O(l) When two moles each of ethanol and acetic acid are combined, equilibrium is reached when two-thirds of a mole of each of the reactants remains.Calculate the equilibrium constant for this reaction assuming total volume does not change during the course of the reaction.(Note: since water is not the solvent, but rather a product of the reaction, [H
2
O] changes during the course of the reaction, so it should be included in the equilibrium constant expression.)
Question 64
Short Answer
Consider the equilibrium equation C(s)+ H
2
O(g)+ 2296 J
CO(g)+ H
2
(g).What will happen to the mass of carbon if we add gaseous water to the system?
Question 65
Essay
Consider the reaction N
2
(g)+ 3H
2
(g)
2NH
3
(g). The production of ammonia is an endothermic reaction.Will heating the equilibrium system increase or decrease the amount of ammonia produced?
Question 66
Short Answer
The data below refer to the following reaction: 2NO(g)+ Br
2
(g)
2NOBr(g)
Find the concentration of NOBr when the system reaches equilibrium.
Question 67
Short Answer
Consider the chemical reaction 2NH
3
(g)
N
2
(g)+ 3H
2
(g).The equilibrium is to be established in a 1.0 L container at 1,000 K, where K
c
= 4.0 * 10
-2
. Initially, 1,220 moles of NH
3
(g)are present.Calculate K
p
for the reaction.
Question 68
Short Answer
Consider the reaction N
2
(g)+ 3H
2
(g)
2NH
3
(g). If nitrogen is removed from the system at equilibrium, what will happen to the hydrogen (H
2
)concentration?
Question 69
Essay
What conditions are used in the Haber process to enhance the yield of ammonia? Explain why each condition affects the yield in terms of the Le Châtelier principle.
Question 70
Short Answer
Consider the chemical reaction 2NH
3
(g)
N
2
(g)+ 3H
2
(g).The equilibrium is to be established in a 1.0 L container at 1,000 K, where K
c
= 4.0 * 10
-2
. Initially, 1,220 moles of NH
3
(g)are present.Estimate the equilibrium concentration of H
2
(g).
Question 71
Short Answer
Calcium carbonate decomposes at high temperatures to give calcium oxide and carbon dioxide. CaCO
3
(s)
CaO(s)+ CO
2
(g) K
P
for this reaction is 1.16 at 800°C.A 5.00 L vessel containing 10.0 g of CaCO
3
(s)was evacuated to remove the air, sealed, and then heated to 800°C.Ignoring the volume occupied by the solid, what will be the mass of the solid in the vessel once equilibrium is reached?
Question 72
Short Answer
Consider the reaction N
2
(g)+ 3H
2
(g)
2NH
3
(g). If we use a catalyst, which way will the reaction shift?
Question 73
Short Answer
Consider the equilibrium equation C(s)+ H
2
O(g)+ 2296 J
CO(g)+ H
2
(g).If additional gaseous water is added to this reaction mixture, what will happen to the temperature of the mixture?
Question 74
Essay
The dissociation of solid silver chloride in water to produce silver ions and chloride ions has an equilibrium constant of 1.8 * 10
-18
.Based on the magnitude of the equilibrium constant, is silver chloride very soluble in water? Why?