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General Chemistry
Quiz 6: Thermochemistry
Path 4
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Question 101
Multiple Choice
What is the standard enthalpy of formation of liquid diethylamine,(CH
3
CH
2
)
2
NH? N
2
O
5
(g) + 8CH
4
(g) → 2(CH
3
CH
2
)
2
NH(l) + 5H
2
O(l) ; ΔH° = -1103 kJ Substance ΔH°
f
(kJ/mol) N
2
O
5
(g) +11) 3 CH
4
(g) -74) 9 H
2
O(l) -285.8
Question 102
Multiple Choice
What is the standard enthalpy of formation of liquid n-butanol,CH
3
CH
2
CH
2
CH
2
OH? CH
3
CH
2
CH
2
CH
2
OH(l) + 6O
2
(g) → 4CO
2
(g) + 5H
2
O(l) ; ΔH° = -2675 kJ Substance ΔH°
f
(kJ/mol) CO
2
(g) -393.5 H
2
O(l) -285.8
Question 103
Multiple Choice
Which of the following is not a fuel-oxidizer mixture used in rockets?
Question 104
Multiple Choice
What is the standard enthalpy of formation of liquid butyraldehyde,CH
3
CH
2
CH
2
CHO(l) ? CH
3
CH
2
CH
2
CHO(l) +
O
2
(g) → 4H
2
O(l) + 4CO
2
(g) ; ΔH° = -2471.8 kJ Substance ΔH°
f
(kJ/mol) CO
2
(g) -393.5 H
2
O(l) -285.8
Question 105
Multiple Choice
A 70.4-L sample of a gaseous hydrocarbon,measured at 1.00 atm pressure and 25.0°C,is burned in excess oxygen,liberating 4.06 × 10
3
kJ of heat at constant pressure.What is the identity of the hydrocarbon? (R = 0.0821 L ∙ atm/(K ∙ mol) ) Substance ΔH°
f
(kJ/mol) CO
2
(g) -393.5 H
2
O(l) -285.8
Question 106
Multiple Choice
The standard enthalpies of formation of various iodine species are as follows: Substance ΔH°
f
(kJ/mol) I(g) +107 I
2
(g) +21 HI(g) +26 What additional information is needed to calculate the standard enthalpy change of the following reaction? H
2
(g) + I
2
(g) → 2HI(g)
Question 107
Multiple Choice
At 25°C,the standard enthalpy of combustion of gaseous propane (C
3
H
8
) is -2219.0 kJ per mole of propane,and the standard enthalpy of combustion of gaseous propylene (C
3
H
6
) is -2058.3 kJ per mole of propylene.What is the standard enthalpy change for the following reaction at 25°C? C
3
H
6
(g) + H
2
(g) → C
3
H
8
(g) Substance ΔH°
f
(kJ/mol) CO
2
(g) -393.5 H
2
O(l) -285.8
Question 108
Multiple Choice
What is the standard enthalpy of formation of CaCO
3
(s) ? CaO(s) + CO
2
(g) → CaCO
3
(s) ; ΔH° = -179.4 kJ Substance ΔH°
f
(kJ/mol) CaO(s) -634.9 CO
2
(g) -393.5
Question 109
Multiple Choice
At 25°C,when 1.00 g of sulfur is burned at constant pressure in excess oxygen to give SO
2
(g) ,9.28 kJ of heat is liberated.What is the enthalpy of formation of SO
2
(g) ?
Question 110
Multiple Choice
What is the standard enthalpy change for the combustion of gaseous propylene,C
3
H
6
? C
3
H
6
(g) +
O
2
(g) → 3CO
2
(g) + 3H
2
O(l) Substance ΔH°
f
(kJ/mol) C
3
H
6
(g) +20) 4 CO
2
(g) -393.5 H
2
O(l) -285.8
Question 111
Multiple Choice
Calculate the change in enthalpy when 52.0 g of solid chromium at 25°C and 1 atm pressure is oxidized.(ΔH°
f
for Cr
2
O
3
(s) is -1135 kJ/mol.) 4Cr(s) + 3O
2
(g) → 2Cr
2
O
3
(s)