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Suppose a New Metallic Element X Is Discovered,and Its Reactions

Question 118

Multiple Choice

Suppose a new metallic element X is discovered,and its reactions with oxygen gas and chlorine gas at 298 K are studied. Trial
Reaction
ΔHºrxn (kJ/mol)
1
4X(s) + 3O2(g) → 2X2O3(s)
-600
2
2X(s) + 3Cl2(g) → 2XCl3(s)
-800
3
4XCl3(s) + 3O2(g) →X2O3(s) +6Cl2(g)
-200
However,it is later discovered that one of the samples was contaminated,and the ΔHºrxn value from this trial is not reliable.Which trial had the contaminated sample,and what should the correct value of ΔHºrxn be for this trial?


A) Trial 1 had the contaminated sample; its ΔHºrxn value should be -900 kJ/mol.
B) Trial 2 had the contaminated sample; its ΔHºrxn value should be +100 kJ/mol.
C) Trial 3 had the contaminated sample; its ΔHºrxn value should be -1000 kJ/mol.
D) Trial 3 had the contaminated sample; its ΔHºrxn value should be +1000 kJ/mol.
E) Not enough information is provided; all three trials must be redone.

Correct Answer:

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