A 0.535 g sample of pyrolusite ore (impure MnO2) is treated with 1.42 g oxalic acid (H2C2O4 ∙ 2H2O) in an acidic medium. Following this reaction, the excess oxalic acid is titrated with 0.1000 M KMnO4, 36.6 mL being required. What is the % MnO2 in the ore? The reactions are: H2C2O4 + MnO2 + 2 H+ → Mn2+ + 2 H2O + 2 CO2
5 H2C2O4 + 2 MnO4- + 6 H+ → 2 Mn2+ + 8 H2O + 10 CO2
A) 34.4%
B) 61.1%
C) 2.33%
D) 1.22%
E) 38.9%
Correct Answer:
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