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Suppose You Are Studying Coordination Compounds of Co(II)with the Ligand

Question 44

Multiple Choice

Suppose you are studying coordination compounds of Co(II) with the ligand pyridine (py,C5H5N,molar mass = 79.10) .You isolate a crystalline compound,and since the only available anions are Cl- and NO3-,you hypothesize the empirical formula of the coordination compound must be Cow(py) x(Cl) y(NO3) z.
-You analyze for pyridine (Kb is approximately 10-9) by dissolving 0.1000 g of complex in 10 mL of H2O and titrating with a 0.01 M HCl solution.Which of the following indicators should be used to detect the endpoint? (Assume that the initial concentration of pyridine is approximately 0.01 M. )


A) bromophenol blue,pH range of color change = 3.0-4.6
B) methyl red,pH range of color change = 4.8-6.0
C) bromothymol blue,pH range of color change = 6.0-7.6
D) thymol blue,pH range of color change = 8.0 -9.6
E) alizarin yellow,pH range of color change = 10.1-12.0

Correct Answer:

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