A $ \pi $-bonding ligand always gives a larger ligand field splitting energy than a $\sigma $-bonding ligand.

Question

Quizplus · Accepted Answer

A $\sigma$-bonding ligand typically gives a larger ligand field splitting energy than a $\pi$-bonding ligand because $\sigma$-bonding involves head-on overlap between the ligand and metal orbitals, leading to stronger bonding interactions compared to the side-on overlap in $\pi$-bonding.

A π \pi π -Bonding Ligand Always Gives a Larger Ligand Field Splitting Energy

A $\pi$ -Bonding Ligand Always Gives a Larger Ligand Field Splitting Energy