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What Is the Composition of the Precipitate Formed When H2S

Question 70

Multiple Choice

What is the composition of the precipitate formed when H2S gas is bubbled through 1.0 litre of a solution of 0.010 M Zn2+,0.010 M Pb2+,and 0.010 M Mn2+,buffered at pH 2.0,until 0.10 mol of H2S has been added?
(Ksp values are: ZnS: 1.6 × 10-23;MnS: 7.0 × 10-16;PbS: 7.0 × 10-29.For H2S,Ka1 = 1.0 × 10-7;Ka2 = 1.3 × 10-13 ) .


A) only ZnS
B) only MnS
C) only PbS
D) only MnS and PbS
E) only ZnS and PbS

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