What is the composition of the precipitate formed when H2S gas is bubbled through 1.0 litre of a solution of 0.010 M Zn2+,0.010 M Pb2+,and 0.010 M Mn2+,buffered at pH 2.0,until 0.10 mol of H2S has been added?
(Ksp values are: ZnS: 1.6 × 10-23;MnS: 7.0 × 10-16;PbS: 7.0 × 10-29.For H2S,Ka1 = 1.0 × 10-7;Ka2 = 1.3 × 10-13 ) .
A) only ZnS
B) only MnS
C) only PbS
D) only MnS and PbS
E) only ZnS and PbS
Correct Answer:
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