Which of the statements below are true for the titration of Fe2+ with standard Ce4+?
I The indicator electrode potential before the addition of Ce4+ solution is calculated using the Fe3+ half-reaction after calculating the equilibrium concentrations of Fe3+ and Fe2+ in solution.
II Before the equivalence point,the indicator electrode potential is calculated using the Fe3+ half-reaction because only [Fe3+] and [Fe2+] are known.
III At the equivalence point,the indicator potential is the average of Eo for Fe3+ and Ce4+.
IV After the equivalence point,the indicator electrode potential is calculated using the Ce4+ half-reaction because only [Ce4+] and [Ce2+] are known.
A) II and IV
B) II,III,and IV
C) I,III,and IV
D) I,II,and IV
E) I,II,III,and IV
Correct Answer:
Verified
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