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The Standard Reduction Potentials (E0') for the Following Half Reactions

Question 14

Multiple Choice

The standard reduction potentials (E0') for the following half reactions are given.
Fumarate + 2H+ + 2e− → succinate E0' = + 0.031 V
FAD + 2H+ + 2e− → FADH2 E0' = −0.219 V
If you mixed succinate, fumarate, FAD, and FADH2 together, all at 1-M concentrations and in the presence of succinate dehydrogenase, which of the following would happen initially?


A) fumarate and succinate would become oxidized; FAD and FADH2 would become reduced
B) fumarate would become reduced, FADH2 would become oxidized
C) no reaction would occur because all reactants and products are already at their standard concentrations
D) succinate would become oxidized, FAD would become reduced
E) succinate would become oxidized, FADH2 would be unchanged because it is a cofactor

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