Deck 14: Solutions and Their Behavior

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Question
What is the mole fraction of calcium chloride in 3.35 m CaCl2(aq)? The molar mass of CaCl2 is 111.0 g/mol and the molar mass of water is 18.02 g/mol.

A) 0.000866
B) 0.0569
C) 0.271
D) 37.2
E) 59.2
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Question
What is the definition of molality?

A) moles of solute per kg of solvent
B) grams of solute per kg of solution
C) grams of solute per liter of solution
D) moles of solute per liter of solvent
E) moles of solute per liter of solution
Question
A concentrated sodium hydroxide solution is 50.5% NaOH by mass and has a density of 1.53 g/mL at 25°C.What is the molarity of NaOH?

A) 19.3 M
B) 0.0612 M
C) 8.25 M
D) 12.1 M
E) 0.0825 M
Question
What is the mass percent of an aqueous sodium hydroxide solution in which the mole fraction of NaOH is 0.101?

A) 20.0%
B) 12.1%
C) 68.9%
D) 12.4%
E) 3.31%
Question
What is the mole fraction of urea,CO(NH2)2, in a solution prepared by dissolving 6.8 g of urea in 33.5 g of methanol,CH3OH?

A) 0.83
B) 0.17
C) 0.098
D) 0.90
E) 0.28
Question
Concentrated sodium hydroxide is 19.4 M and has a density of 1.54 g/mL.What is the molality of concentrated NaOH?

A) 12.6 m
B) 19.8 m
C) 25.4 m
D) 29.9 m
E) 50.4 m
Question
Calculate the molarity of a solution of magnesium chloride with a concentration of 30.3 mg/mL.

A) 0.159 M
B) 3.14 M
C) 0.636 M
D) 0.507 M
E) 0.318 M
Question
What is the mole fraction of urea,CH4N2O,in an aqueous solution that is 54% urea by mass?

A) 0.26
B) 0.74
C) 0.54
D) 0.37
E) 0.80
Question
If 27.9 g LiCl is dissolved in 175 g H2O,what is the weight percent of LiCl in the solution?

A) 0.376%
B) 6.78%
C) 13.8%
D) 15.9%
E) 19.0%
Question
What is the mass percent of an aqueous sodium hydroxide solution in which the molality of NaOH is 10.7 m?

A) 0.124%
B) 68.9%
C) 1.69%
D) 30.0%
E) 0.322%
Question
If the concentration of sodium carbonate in water is 12.8 ppm,what is the molarity of Na2CO3(aq)? The molar mass of Na2CO3 is 106.0 g/mol.Assume the density of the solution is 1.00 g/mL.

A) 8.28 ×\times 10-6 M
B) 1.21 ×\times 10-4 M
C) 1.36 ×\times 10-3 M
D) 0.136 M
E) 0.121 M
Question
A 12.0% sucrose solution by mass has a density of 1.05 g/cm3.What mass of sucrose is present in a 63.0-mL sample of this solution?

A) 7.94 g
B) 7.20 g
C) 0.126 g
D) 551 g
E) 7.56 g
Question
The volume of a 15.8% (by mass)solution is 146.4 mL.The density of the solution is 1.084 g/mL.What is the mass of solute in this solution?

A) 159 g
B) 25.1 g
C) 1004 g
D) 21.3 g
E) 134 g
Question
How many milliliters of 15.7 M H2SO4 are needed to prepare 600.0 mL of 0.10 M H2SO4?

A) 0.26 mL
B) 94 mL
C) 3.8 mL
D) 1.9 mL
E) 4.8 mL
Question
What mass of an aqueous 22.9% sodium chloride solution contains 99.5 g of water?

A) 129 g
B) 29.6 g
C) 0.500 g
D) 22.8 g
E) 99.5 g
Question
What volume of a 0.771 M solution of CaCl2 contains 1.28 g of solute?

A) 66.8 mL
B) 15.0 mL
C) 1.66 mL
D) 8.89 mL
E) 85.0 mL
Question
If 11.2 g of naphthalene,C10H8,is dissolved in 105.4 g of chloroform,CHCl3,what is the molality of the solution?

A) 0.0875 m
B) 12.7 m
C) 0.830 m
D) 0.0961 m
E) 0.0991 m
Question
What is the molality of ethanol,C2H5OH,in an aqueous solution that is 37.4% ethanol by mass?

A) 0.597 m
B) 0.0130 m
C) 13.0 m
D) 0.719 m
E) 93.0 m
Question
A concentrated hydrochloric acid solution has a density of 1.19 g/mL at 25°C and is 12.1 M.What is the percent by mass of HCl in the solution?

A) 37.1% HCl by mass
B) 1.02% HCl by mass
C) 0.980% HCl by mass
D) 2.80% HCl by mass
E) 30.6% HCl by mass
Question
What is the mass of H2SO4 in a 46.4-mL sample of concentrated sulfuric acid that has a density of 1.84 g/mL and consists of 98.3% H2SO4?

A) 45.6 g
B) 83.9 g
C) 3.90 g
D) 1.81 g
E) 24.8 g
Question
A 15 meter by 12 meter pool of water has a depth of 2.2 meters.What mass of silver ion is present in the reservoir if the concentration of silver ion is 0.14 ppm? (1 m3 = 1000 L; assume the density of the solution is 1.00 g/mL)

A) 5.5 ×\times 10-4 g
B) 5.5 ×\times 10-2 g
C) 0.55 g
D) 5.5 g
E) 55 g
Question
Which action(s)will decrease the equilibrium concentration of an inert gas (such as N2)in water?
1)decreasing the temperature of the water
2)increasing the volume of water
3)decreasing the pressure of the gas above the liquid

A) 1 only
B) 2 only
C) 3 only
D) 1 and 3
E) 1,2,and 3
Question
Which of the following compounds is  not \textbf{ not } miscible with water?

A) CH3NH2
B) CH3COOH
C) CCl4
D) CH3CN
E) HOCH2CH2OH
Question
The Henry's law constant for O2 in water at 25 \circ C is 1.3 ×\times 10-3 mol/kg.bar.What partial pressure of O2 (in atm)is necessary to achieve an equilibrium concentration of 2.9 ×\times 10-3 mol/kg O2? (1 atm = 0.9869 bar)

A) 0.44 atm
B) 0.45 atm
C) 2.1 atm
D) 2.3 atm
E) 3.8 atm
Question
The lattice enthalpy of KF is -808 kJ/mol and the enthalpy of solution of KF is -17.7 kJ/mol.Calculate the enthalpy of hydration of KF(s).

A) -790.3 kJ/mol
B) -35.4 kJ/mol
C) -825.7 kJ/mol
D) 790.3 kJ/mol
E) 825.7 kJ/mol
Question
The solubility of 1-hexanol in water is 0.60 g per 100 g of water at 25°C.What is the maximum amount of 1-hexanol that will dissolve in 5.3 g of water at 25°C?

A) 0.032 g
B) 0.11 g
C) 0.60 g
D) 3.2 g
E) 0.0011 g
Question
The standard enthalpy of formation of RbF(s)is -557.7kJ/mol and the standard enthalpy of formation of RbF(aq,1 m)is -583.8 kJ/mol.Determine the enthalpy of solution of RbF and indicate whether the solution temperature will increase or decrease when RbF is dissolved in water.

A) -26.1 kJ/mol; increase
B) 26.1 kJ/mol; increase
C) -26.1 kJ/mol; decrease
D) +1141.5 kJ/mol; increase
E) -1141.5 kJ/mol; decrease
Question
Two nonpolar solvents,such as hexane and carbon tetrachloride,may be miscible even though the enthalpy of mixing of these liquids might be small.A reason that mixing occurs is that mixtures have a greater dispersal of energy relative to pure solvents.The tendency toward greater dispersal of energy is a thermodynamic function called ____.

A) entropy
B) enthalpy
C) saturation
D) adhesion
E) cohesion
Question
Which of the following statements is INCORRECT?

A) The solubility of a gas in water decreases with increasing temperature.
B) The solubility of a gas in water is proportional to the partial pressure of the gas above the water.
C) The dissolution of a gas in water is usually an exothermic process.
D) The relationship between the solubility of a gas and its partial pressure is known as Henry's law.
E) The solubility of a gas in water is inversely proportional to the molar mass of the gas.
Question
According to the National Institute of Standards webbook,the Henry's Law constant for N2 gas is 0.00060 mol/kg.bar at 25 \circ C What is the Henry's law constant in units of mol/kg.atm? (1 bar = 0.9869 atm; 1 atm = 760 mmHg)

A)  <strong>According to the National Institute of Standards webbook,the Henry's Law constant for N<sub>2</sub> gas is 0.00060 mol/kg.bar at 25<sup> \circ </sup>C What is the Henry's law constant in units of mol/kg.atm? (1 bar = 0.9869 atm; 1 atm = 760 mmHg)</strong> A)   mol/kg.atm B)   mol/kg.atm C)   mol/kg.atm D)   mol/kg.atm E)   mol/kg.atm <div style=padding-top: 35px>  mol/kg.atm
B)  <strong>According to the National Institute of Standards webbook,the Henry's Law constant for N<sub>2</sub> gas is 0.00060 mol/kg.bar at 25<sup> \circ </sup>C What is the Henry's law constant in units of mol/kg.atm? (1 bar = 0.9869 atm; 1 atm = 760 mmHg)</strong> A)   mol/kg.atm B)   mol/kg.atm C)   mol/kg.atm D)   mol/kg.atm E)   mol/kg.atm <div style=padding-top: 35px>  mol/kg.atm
C)  <strong>According to the National Institute of Standards webbook,the Henry's Law constant for N<sub>2</sub> gas is 0.00060 mol/kg.bar at 25<sup> \circ </sup>C What is the Henry's law constant in units of mol/kg.atm? (1 bar = 0.9869 atm; 1 atm = 760 mmHg)</strong> A)   mol/kg.atm B)   mol/kg.atm C)   mol/kg.atm D)   mol/kg.atm E)   mol/kg.atm <div style=padding-top: 35px>  mol/kg.atm
D)  <strong>According to the National Institute of Standards webbook,the Henry's Law constant for N<sub>2</sub> gas is 0.00060 mol/kg.bar at 25<sup> \circ </sup>C What is the Henry's law constant in units of mol/kg.atm? (1 bar = 0.9869 atm; 1 atm = 760 mmHg)</strong> A)   mol/kg.atm B)   mol/kg.atm C)   mol/kg.atm D)   mol/kg.atm E)   mol/kg.atm <div style=padding-top: 35px>  mol/kg.atm
E)  <strong>According to the National Institute of Standards webbook,the Henry's Law constant for N<sub>2</sub> gas is 0.00060 mol/kg.bar at 25<sup> \circ </sup>C What is the Henry's law constant in units of mol/kg.atm? (1 bar = 0.9869 atm; 1 atm = 760 mmHg)</strong> A)   mol/kg.atm B)   mol/kg.atm C)   mol/kg.atm D)   mol/kg.atm E)   mol/kg.atm <div style=padding-top: 35px>  mol/kg.atm
Question
Which of the following liquids will be miscible with water in any proportion: ethanol (CH3CH2OH),carbon tetrachloride (CCl4),hexane (C6H14),and/or formic acid (HCO2H)?

A) ethanol and carbon tetrachloride
B) carbon tetrachloride and hexane
C) ethanol and formic acid
D) ethanol,carbon tetrachloride,and benzene
E) carbon tetrachloride,and formic acid
Question
What mass of Zn(NO3)2 must be diluted to a mass of 1.00 kg with H2O to prepare 97 ppm Zn2+(aq)?

A) 7.8 ×\times 10-6 g
B) 7.8 ×\times 10-3 g
C) 3.3 ×\times 10-2 g
D) 1.3 ×\times 10-1 g
E) 2.8 ×\times 10-1 g
Question
The Henry's law constant for N2 in water at 25 \circ C is 6.0 ×\times 10-4 mol/kg.bar.What is the equilibrium concentration of N2 in water when the partial pressure of N2 is 586 mm Hg? (760 mm Hg = 1 atm = 0.9869 bar)

A) 1.4 ×\times 10-9 M
B) 1.8 ×\times 10-5 M
C) 4.6 ×\times 10-4 M
D) 7.7 ×\times 10-4 M
E) 7.9 ×\times 10-4 M
Question
Which of the following statements concerning solubility is/are CORRECT?
1)Ionic compounds composed of Group 1A metal ions and halide ions,such as NaCl,are insoluble in nonpolar solvents.
2)The solubility of the halogens (Cl2,Br2,and I2)in polar solvents is greater than their solubility in nonpolar solvents.
3)The solubility of polar molecules,such as sugar,in polar solvents is generally greater than their solubility in nonpolar solvents.

A) 1 only
B) 2 only
C) 3 only
D) 1 and 3
E) 1,2,and 3
Question
Which of the following favor(s)the solubility of an ionic solid in a liquid solvent?

A) a small magnitude of the lattice energy of the solute
B) a large magnitude of the solvation energy of the ions
C) a large polarity of the solvent
D) all of the above
E) none of the above
Question
Which of the following statements is/are CORRECT?
1)Solubility is defined as the concentration of solute in equilibrium with undissolved solute in a saturated solution.
2)If two liquids mix to an appreciable extent to form a solution,they are miscible.
3)If two liquids mix completely in any proportion to form a solution,the resulting solution is supersaturated.

A) 1 only
B) 2 only
C) 3 only
D) 1 and 2
E) 2 and 3
Question
The change in energy accompanying the process below is the ____ of MX.
MX(s) \to M+(aq)+ X-(aq)

A) enthalpy of hydration
B) enthalpy of solution
C) lattice energy
D) enthalpy of formation
E) electron attachment enthalpy
Question
Which process is accompanied by the change in energy known as the lattice enthalpy of RbCl?

A) Rb+(g)+ Cl-(g) \to Rb+(aq)+ Cl-(aq)
B) RbCl(s) \to RbCl(aq,1 m)
C) Rb+(g)+ Cl-(g) \to RbCl(s)
D) Rb(s)+  <strong>Which process is accompanied by the change in energy known as the lattice enthalpy of RbCl?</strong> A) Rb<sup>+</sup>(g)+ Cl<sup>-</sup>(g) \to  Rb<sup>+</sup>(aq)+ Cl<sup>-</sup>(aq) B) RbCl(s) \to  RbCl(aq,1 m) C) Rb<sup>+</sup>(g)+ Cl<sup>-</sup>(g) \to  RbCl(s) D) Rb(s)+   Cl<sub>2</sub>(g) \to  RbCl(s) E) Rb(s)+   Cl<sub>2</sub>(g) \to RbCl(aq,1 m) <div style=padding-top: 35px>  Cl2(g) \to RbCl(s)
E) Rb(s)+  <strong>Which process is accompanied by the change in energy known as the lattice enthalpy of RbCl?</strong> A) Rb<sup>+</sup>(g)+ Cl<sup>-</sup>(g) \to  Rb<sup>+</sup>(aq)+ Cl<sup>-</sup>(aq) B) RbCl(s) \to  RbCl(aq,1 m) C) Rb<sup>+</sup>(g)+ Cl<sup>-</sup>(g) \to  RbCl(s) D) Rb(s)+   Cl<sub>2</sub>(g) \to  RbCl(s) E) Rb(s)+   Cl<sub>2</sub>(g) \to RbCl(aq,1 m) <div style=padding-top: 35px>  Cl2(g) \to RbCl(aq,1 m)
Question
What concentration of silver nitrate (in ppm)is present in 7.1 ×\times 10-7 M AgNO3(aq)? For very dilute aqueous solutions,you can assume the solution's density is 1.0 g/mL.The molar mass of AgNO3 is 169.9 g/mol.

A) 0.0071 ppm
B) 0.12 ppm
C) 0.71 ppm
D) 1.7 ppm
E) 8.3 ppm
Question
At a particular temperature the solubility of O2 in water is 0.590 g/L at an oxygen pressure of 15.2 atm.What is the Henry's law constant for O2?

A) 3.88 ×\times 10-2 L·atm/mol
B) 8.24 ×\times 102 L·atm/mol
C) 2.80 ×\times 10-1 L·atm/mol
D) 1.21 ×\times 10-3 L·atm/mol
E) None of the above.
Question
What is the freezing point of an aqueous 1.36 m NaCl solution? (Kfp for water is 1.858°C/m.)Assume no ion pairing occurs.

A) 5.1°C
B) 2.5°C
C) -5.1°C
D) 0.0°C
E) -2.5°C
Question
The vapor pressure of pure water at 15 \circ C is 12.8 mm Hg.What is the equilibrium vapor pressure of water above a mixture of 72.0 g ethanol (CH3CH2OH,molar mass = 46.07 g/mol)and 22.0 g water?

A) 2.84 mm Hg
B) 5.61 mm Hg
C) 7.19 mm Hg
D) 10.0 mm Hg
E) 12.8 mm Hg
Question
What mass of ethylene glycol,when mixed with 225 g H2O,will reduce the equilibrium vapor pressure of H2O from 1.00 atm to 0.800 atm at 100 \circ C? The molar masses of water and ethylene glycol are 18.02 g/mol and 62.07 g/mol,respectively.Assume ideal behavior for the solution.

A) 15.6 g
B) 49.9 g
C) 194 g
D) 969 g
E) 3.10 ×\times 103 g
Question
Assuming ideal behavior,which of the following aqueous solutions would be expected to exhibit the  smallest\underline{\text{ smallest}} freezing-point lowering?

A) 0.1 m KCl
B) 0.05 m CH3COOH
C) 0.05 m Al2(SO4)3
D) 0.1 m CaCl2
E) 0.25 m C6H12O6
Question
A solution consisting of 0.228 mol of methylbenzene,C6H5CH3,in 255 g of nitrobenzene,C6H5NO2,freezes at -0.3°C.Pure nitrobenzene freezes at 6.0°C.What is the freezing-point depression constant of nitrobenzene?

A) 1.1°C/m
B) 27°C/m
C) 14.0°C/m
D) 3.5°C/m
E) 7.0°C/m
Question
What is the equilibrium partial pressure of water vapor above a mixture of 37.5 g H2O and 62.5 g HOCH2CH2OH at 55 \circ C.The partial pressure of pure water at 55.0 \circ C is 118.0 mm Hg.Assume ideal behavior for the solution.

A) 3.54 mm Hg
B) 31.7 mm Hg
C) 38.5 mm Hg
D) 79.5 mm Hg
E) 175 mm Hg
Question
If the solubility of O2 at 0.360 bar and 25 \circ C is 15.0 g/100 g H2O,what is the solubility of O2 at a pressure of 1.72 bar and 25 \circ C?

A) 71.7 g/100 g H2O
B) 24.2 g/100 g H2O
C) 0.319 g/100 g H2O
D) 0.0140 g/100 g H2O
E) 3.14 g/100 g H2O
Question
For the following gas-liquid equilibrium for an aqueous system at a constant partial pressure of O2,
O2(g) \leftrightarrows O2(aq)
What is the effect on the equilibrium composition of the liquid when the  temperature \underline{\text{ temperature }} of the liquid is decreased?

A) The amount of O2 dissolved in the liquid decreases.
B) The amount of O2 dissolved in the liquid increases.
C) The amount of O2 dissolved in the liquid does not change.
D) Not enough information is provided to answer the question.
E) Either A or B could occur.
Question
Henry's Law constant is 0.034 mol/kg.bar and 0.0013 mol/kg.bar for CO2 and O2 respectively at 25 \circ C.What pressure of O2 is required to achieve the same solubility as 0.218 bar of CO2?

A) 5.7 bar
B) 0.0083 bar
C)  <strong>Henry's Law constant is 0.034 mol/kg.bar and 0.0013 mol/kg.bar for CO<sub>2</sub> and O<sub>2</sub> respectively at 25<sup> \circ </sup>C.What pressure of O<sub>2</sub> is required to achieve the same solubility as 0.218 bar of CO<sub>2</sub>?</strong> A) 5.7 bar B) 0.0083 bar C)   bar D)   bar E) 0.18 bar <div style=padding-top: 35px>  bar
D)  <strong>Henry's Law constant is 0.034 mol/kg.bar and 0.0013 mol/kg.bar for CO<sub>2</sub> and O<sub>2</sub> respectively at 25<sup> \circ </sup>C.What pressure of O<sub>2</sub> is required to achieve the same solubility as 0.218 bar of CO<sub>2</sub>?</strong> A) 5.7 bar B) 0.0083 bar C)   bar D)   bar E) 0.18 bar <div style=padding-top: 35px>  bar
E) 0.18 bar
Question
Assuming ideal behavior,which of the following aqueous solutions should have the highest boiling point?

A) 1.00 m LiBr
B) 0.75 m K2SO4
C) 0.50 m Ca(NO3)2
D) 0.75 m NaCl
E) 1.25 m C6H12O6
Question
What is the freezing point of a 0.24 m solution of glucose,C6H12O6,in water? (Kfp for water is 1.858°C/m.)

A) 0.22°C
B) 0.45°C
C) -0.45°C
D) -0.22°C
E) -0.89°C
Question
If a 25.0-g sample of a nonelectrolyte is dissolved in 145.0 g of water,the resulting solution will freeze at -0.89°C.What is the molar mass of the nonelectrolyte? (Kfp for water is 1.858°C/m.)

A) 76 g/mol
B) 0.36 g/mol
C) 990 g/mol
D) 290 g/mol
E) 360 g/mol
Question
What is the boiling-point  change \underline{\text{ change }} for a solution containing 0.432 mol of naphthalene (a nonvolatile,nonionizing compound)in 250.g of liquid benzene? (Kbp = 2.53°C/m for benzene)

A) 4.37 °C
B) 5.86 °C
C) 0.273 °C
D) 1.46 °C
E) 1.093 °C
Question
The vapor pressure of water at 90°C is 0.692 atm.What is the vapor pressure (in atm)of a solution made by dissolving 1.28 mole(s)of CsF(s)in 1.00 kg of water? Assume that Raoult's law applies.

A) 0.661 atm
B) 0.676 atm
C) 0.692 atm
D) 0.724 atm
E) none of these
Question
What partial pressure of oxygen gas is required in order for 0.00392 g of the gas to dissolve in 23.7 mL of pure water? The Henry's law constant for oxygen gas is 1.3 ×\times 10-3 M atm-1.

A) 2.2 ×\times 10-7 atm
B) 4.0 ×\times 100 atm
C) 1.6 ×\times 10-7 atm
D) 2.5 ×\times 10-1 atm
E) 4.2 ×\times 10-2 atm
Question
What mass of Na2SO4 must be dissolved in 100.0 grams of water to lower the freezing point by 2.50 \circ C? The freezing point depression constant,Kfp,of water is -1.86 \circ C/m.Assume the van't Hoff factor for Na2SO4 is 2.85.

A) 3.77 g
B) 6.36 g
C) 6.70 g
D) 11.3 g
E) 19.1 g
Question
What is the vapor pressure at 20°C of an ideal solution prepared by the addition of 4.60 g of the nonvolatile solute urea,CO(NH2)2,to 50.2 g of methanol,CH3OH? The vapor pressure of pure methanol at 20°C is 89.0 mmHg.

A) 4.15 mmHg
B) 76.0 mmHg
C) 81.5 mmHg
D) 84.9 mmHg
E) 13.0 mmHg
Question
Ideally,colligative properties depend only on the

A) relative numbers of solute and solvent particles in a solution.
B) molar masses of the solute particles in a solution.
C) density of a solution.
D) hydrated radii of the molecules or ions dissolved in a solution.
E) partial pressure of the gases above the surface of a solution.
Question
For the following gas-aqueous liquid equilibrium for a closed system at a constant temperature,
O2(g) \leftrightarrows O2(aq)
What is the effect on the equilibrium composition of the liquid when the  partial pressure \underline{\text{ partial pressure }} of O2 gas above the liquid is decreased?

A) The amount of O2 dissolved in the liquid decreases.
B) The amount of O2 dissolved in the liquid increases.
C) The amount of O2 dissolved in the liquid does not change.
D) Not enough information is provided to answer the question.
E) Either A or B is possible.
Question
What is the freezing point of a solution containing 2.80 grams benzene (molar mass = 78.11 g/mol)dissolved in 43.0 grams paradichlorobenzene (molar mass = 147.0 g/mol)? The freezing point of pure paradichlorobenzene is 53.0 \circ C and the freezing point depression constant,Kfp,is -7.10 \circ C/m.

A) 46.7 \circ C
B) 47.1 \circ C
C) 58.9 \circ C
D) 52.6 \circ C
E) 58 .9 \circ C
Question
Which of the following solutions would have the highest osmotic pressure?

A) 0.3 M C6H12O6,glucose
B) 0.2 M MgBr2,magnesium bromide
C) 0.2 M KCl,potassium chloride
D) 0.3 M CH3COOH,acetic acid
E) 0.3 M C12H22O11,sucrose
Question
All of the following are colloidal dispersions EXCEPT ____.

A) marshmallow
B) white wine
C) milk
D) whipped cream
E) cheese
Question
A surfactant used for cleaning is called a(n)________.
Question
Because ________ particles are relatively large (say,1000 nm in diameter)they scatter visible light,making the mixtures containing these particles appear cloudy.This scattering is known as the Tyndall effect.
Question
At 37°C,what is the osmotic pressure of a 0.59% NaCl by weight aqueous solution? Assume the density of the solution is 1.0 g/mL.Assume no ion pairing.(R = 0.0821 L · atm/K·mol)

A) 0.26 atm
B) 2.6 atm
C) 3.0 ×\times 102 atm
D) 5.1 atm
E) 0.61 atm
Question
________ are colloidal dispersions of one liquid in another liquid.
Question
What type of colloid is formed when a solid is dispersed in a liquid?

A) foam
B) aerosol
C) sol
D) emulsion
E) gel
Question
Aqueous colloidal solutions can be classified as ________ (water-fearing),or hydrophilic (water-loving).
Question
If one of the factors determining the equilibrium of a system is changed,the system adjusts to counteract that change.This is known as ________ principle.
Question
The osmotic pressure of blood is 7.65 atm at 37 \circ C.What mass of glucose (C6H12O6,molar mass = 180.2 g/mol)is needed to prepare 2.25 L of solution for intravenous injection? The osmotic pressure of the glucose solution must equal the osmotic pressure of blood.(R = 0.08206 L.atm/mol.K)

A) 0.676 g
B) 0.698 g
C) 5.67 g
D) 122 g
E) 1.02 ×\times 103 g
Question
For a dilute solution of NH4NO3,the van't Hoff factor (i)would be approximately ___.

A) 1
B) 2
C) 3
D) 4
E) 5
Question
A 2.3-g sample of a small protein having a molecular weight of 62,000 g/mol is dissolved in 38.8 mL of water at 28°C.What is the osmotic pressure of the solution? (R = 0.0821 L · atm/K·mol; 1 atm = 760 mmHg)

A) 18 mmHg
B) 1100 mmHg
C) 1.7 mmHg
D) 32,000 mmHg
E) 0.024 mmHg
Question
A 0.20 M solution of MgSO4 has an observed osmotic pressure of 7.7 atm at 25°C.Determine the observed van't Hoff factor for this experiment.

A) 2.0
B) 1.6
C) 0.31
D) 19
E) 1.8
Question
Colloids are described by all of the following  except: \textbf{ except: }

A) The particles in a colloid are so small that settling is negligible.
B) The mixture appears cloudy.
C) Only combinations of liquids and gases can form colloids.
D) Colloids are not suspensions or homogeneous mixtures.
E) Mayonnaise,whipped cream and fog are all examples of colloids.
Question
Which of the following statements concerning osmosis is/are CORRECT?
1)Osmosis involves the movement of ions through a semipermeable membrane until the charges on both sides of the membrane are equal.
2)Solvents move from regions of low solute concentration to regions of higher solute concentration.
3)Osmotic pressure is a colligative property.

A) 1 only
B) 2 only
C) 3 only
D) 2 and 3
E) 1,2,and 3
Question
Which of the following solutions has the lowest osmotic pressure?

A) 0.10 M Al(NO3)3
B) 0.20 M NH3
C) 0.15 M Ba(NO2)2
D) 0.10 M CaCl2
E) 0.15 M NaCl
Question
A solution is prepared by dissolving 5.88 g of an unknown nonelectrolyte in enough water to make 0.355 L of solution.The osmotic pressure of the solution is 1.21 atm at 27 \circ C.What is the molar mass of the solute? (R = 0.08206 L.atm/mol.K)

A) 0.00297 g/mol
B) 30.3 g/mol
C) 42.5 g/mol
D) 175 g/mol
E) 337 g/mol
Question
The following equation is known as ________ law: The following equation is known as ________ law:   .<div style=padding-top: 35px>
.
Question
Which of the following statements about soaps and detergents is  false? \underline{\text{ false? }}

A) The polar end is attracted to grease and oil.
B) They have a polar and a nonpolar end.
C) They are emulsifiers for grease and oil.
D) Phosphate detergents can produce pollution problems.
E) They can be described as surfactants.
Question
What concentration unit is used in the calculation of osmotic pressure for a dilute solution?

A) molality
B) weight percent
C) mass fraction
D) mole fraction
E) molarity
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Deck 14: Solutions and Their Behavior
1
What is the mole fraction of calcium chloride in 3.35 m CaCl2(aq)? The molar mass of CaCl2 is 111.0 g/mol and the molar mass of water is 18.02 g/mol.

A) 0.000866
B) 0.0569
C) 0.271
D) 37.2
E) 59.2
0.0569
2
What is the definition of molality?

A) moles of solute per kg of solvent
B) grams of solute per kg of solution
C) grams of solute per liter of solution
D) moles of solute per liter of solvent
E) moles of solute per liter of solution
moles of solute per kg of solvent
3
A concentrated sodium hydroxide solution is 50.5% NaOH by mass and has a density of 1.53 g/mL at 25°C.What is the molarity of NaOH?

A) 19.3 M
B) 0.0612 M
C) 8.25 M
D) 12.1 M
E) 0.0825 M
19.3 M
4
What is the mass percent of an aqueous sodium hydroxide solution in which the mole fraction of NaOH is 0.101?

A) 20.0%
B) 12.1%
C) 68.9%
D) 12.4%
E) 3.31%
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5
What is the mole fraction of urea,CO(NH2)2, in a solution prepared by dissolving 6.8 g of urea in 33.5 g of methanol,CH3OH?

A) 0.83
B) 0.17
C) 0.098
D) 0.90
E) 0.28
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6
Concentrated sodium hydroxide is 19.4 M and has a density of 1.54 g/mL.What is the molality of concentrated NaOH?

A) 12.6 m
B) 19.8 m
C) 25.4 m
D) 29.9 m
E) 50.4 m
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7
Calculate the molarity of a solution of magnesium chloride with a concentration of 30.3 mg/mL.

A) 0.159 M
B) 3.14 M
C) 0.636 M
D) 0.507 M
E) 0.318 M
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8
What is the mole fraction of urea,CH4N2O,in an aqueous solution that is 54% urea by mass?

A) 0.26
B) 0.74
C) 0.54
D) 0.37
E) 0.80
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9
If 27.9 g LiCl is dissolved in 175 g H2O,what is the weight percent of LiCl in the solution?

A) 0.376%
B) 6.78%
C) 13.8%
D) 15.9%
E) 19.0%
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10
What is the mass percent of an aqueous sodium hydroxide solution in which the molality of NaOH is 10.7 m?

A) 0.124%
B) 68.9%
C) 1.69%
D) 30.0%
E) 0.322%
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11
If the concentration of sodium carbonate in water is 12.8 ppm,what is the molarity of Na2CO3(aq)? The molar mass of Na2CO3 is 106.0 g/mol.Assume the density of the solution is 1.00 g/mL.

A) 8.28 ×\times 10-6 M
B) 1.21 ×\times 10-4 M
C) 1.36 ×\times 10-3 M
D) 0.136 M
E) 0.121 M
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12
A 12.0% sucrose solution by mass has a density of 1.05 g/cm3.What mass of sucrose is present in a 63.0-mL sample of this solution?

A) 7.94 g
B) 7.20 g
C) 0.126 g
D) 551 g
E) 7.56 g
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13
The volume of a 15.8% (by mass)solution is 146.4 mL.The density of the solution is 1.084 g/mL.What is the mass of solute in this solution?

A) 159 g
B) 25.1 g
C) 1004 g
D) 21.3 g
E) 134 g
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14
How many milliliters of 15.7 M H2SO4 are needed to prepare 600.0 mL of 0.10 M H2SO4?

A) 0.26 mL
B) 94 mL
C) 3.8 mL
D) 1.9 mL
E) 4.8 mL
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15
What mass of an aqueous 22.9% sodium chloride solution contains 99.5 g of water?

A) 129 g
B) 29.6 g
C) 0.500 g
D) 22.8 g
E) 99.5 g
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16
What volume of a 0.771 M solution of CaCl2 contains 1.28 g of solute?

A) 66.8 mL
B) 15.0 mL
C) 1.66 mL
D) 8.89 mL
E) 85.0 mL
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17
If 11.2 g of naphthalene,C10H8,is dissolved in 105.4 g of chloroform,CHCl3,what is the molality of the solution?

A) 0.0875 m
B) 12.7 m
C) 0.830 m
D) 0.0961 m
E) 0.0991 m
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18
What is the molality of ethanol,C2H5OH,in an aqueous solution that is 37.4% ethanol by mass?

A) 0.597 m
B) 0.0130 m
C) 13.0 m
D) 0.719 m
E) 93.0 m
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19
A concentrated hydrochloric acid solution has a density of 1.19 g/mL at 25°C and is 12.1 M.What is the percent by mass of HCl in the solution?

A) 37.1% HCl by mass
B) 1.02% HCl by mass
C) 0.980% HCl by mass
D) 2.80% HCl by mass
E) 30.6% HCl by mass
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20
What is the mass of H2SO4 in a 46.4-mL sample of concentrated sulfuric acid that has a density of 1.84 g/mL and consists of 98.3% H2SO4?

A) 45.6 g
B) 83.9 g
C) 3.90 g
D) 1.81 g
E) 24.8 g
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21
A 15 meter by 12 meter pool of water has a depth of 2.2 meters.What mass of silver ion is present in the reservoir if the concentration of silver ion is 0.14 ppm? (1 m3 = 1000 L; assume the density of the solution is 1.00 g/mL)

A) 5.5 ×\times 10-4 g
B) 5.5 ×\times 10-2 g
C) 0.55 g
D) 5.5 g
E) 55 g
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22
Which action(s)will decrease the equilibrium concentration of an inert gas (such as N2)in water?
1)decreasing the temperature of the water
2)increasing the volume of water
3)decreasing the pressure of the gas above the liquid

A) 1 only
B) 2 only
C) 3 only
D) 1 and 3
E) 1,2,and 3
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23
Which of the following compounds is  not \textbf{ not } miscible with water?

A) CH3NH2
B) CH3COOH
C) CCl4
D) CH3CN
E) HOCH2CH2OH
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24
The Henry's law constant for O2 in water at 25 \circ C is 1.3 ×\times 10-3 mol/kg.bar.What partial pressure of O2 (in atm)is necessary to achieve an equilibrium concentration of 2.9 ×\times 10-3 mol/kg O2? (1 atm = 0.9869 bar)

A) 0.44 atm
B) 0.45 atm
C) 2.1 atm
D) 2.3 atm
E) 3.8 atm
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25
The lattice enthalpy of KF is -808 kJ/mol and the enthalpy of solution of KF is -17.7 kJ/mol.Calculate the enthalpy of hydration of KF(s).

A) -790.3 kJ/mol
B) -35.4 kJ/mol
C) -825.7 kJ/mol
D) 790.3 kJ/mol
E) 825.7 kJ/mol
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26
The solubility of 1-hexanol in water is 0.60 g per 100 g of water at 25°C.What is the maximum amount of 1-hexanol that will dissolve in 5.3 g of water at 25°C?

A) 0.032 g
B) 0.11 g
C) 0.60 g
D) 3.2 g
E) 0.0011 g
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27
The standard enthalpy of formation of RbF(s)is -557.7kJ/mol and the standard enthalpy of formation of RbF(aq,1 m)is -583.8 kJ/mol.Determine the enthalpy of solution of RbF and indicate whether the solution temperature will increase or decrease when RbF is dissolved in water.

A) -26.1 kJ/mol; increase
B) 26.1 kJ/mol; increase
C) -26.1 kJ/mol; decrease
D) +1141.5 kJ/mol; increase
E) -1141.5 kJ/mol; decrease
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28
Two nonpolar solvents,such as hexane and carbon tetrachloride,may be miscible even though the enthalpy of mixing of these liquids might be small.A reason that mixing occurs is that mixtures have a greater dispersal of energy relative to pure solvents.The tendency toward greater dispersal of energy is a thermodynamic function called ____.

A) entropy
B) enthalpy
C) saturation
D) adhesion
E) cohesion
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29
Which of the following statements is INCORRECT?

A) The solubility of a gas in water decreases with increasing temperature.
B) The solubility of a gas in water is proportional to the partial pressure of the gas above the water.
C) The dissolution of a gas in water is usually an exothermic process.
D) The relationship between the solubility of a gas and its partial pressure is known as Henry's law.
E) The solubility of a gas in water is inversely proportional to the molar mass of the gas.
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30
According to the National Institute of Standards webbook,the Henry's Law constant for N2 gas is 0.00060 mol/kg.bar at 25 \circ C What is the Henry's law constant in units of mol/kg.atm? (1 bar = 0.9869 atm; 1 atm = 760 mmHg)

A)  <strong>According to the National Institute of Standards webbook,the Henry's Law constant for N<sub>2</sub> gas is 0.00060 mol/kg.bar at 25<sup> \circ </sup>C What is the Henry's law constant in units of mol/kg.atm? (1 bar = 0.9869 atm; 1 atm = 760 mmHg)</strong> A)   mol/kg.atm B)   mol/kg.atm C)   mol/kg.atm D)   mol/kg.atm E)   mol/kg.atm  mol/kg.atm
B)  <strong>According to the National Institute of Standards webbook,the Henry's Law constant for N<sub>2</sub> gas is 0.00060 mol/kg.bar at 25<sup> \circ </sup>C What is the Henry's law constant in units of mol/kg.atm? (1 bar = 0.9869 atm; 1 atm = 760 mmHg)</strong> A)   mol/kg.atm B)   mol/kg.atm C)   mol/kg.atm D)   mol/kg.atm E)   mol/kg.atm  mol/kg.atm
C)  <strong>According to the National Institute of Standards webbook,the Henry's Law constant for N<sub>2</sub> gas is 0.00060 mol/kg.bar at 25<sup> \circ </sup>C What is the Henry's law constant in units of mol/kg.atm? (1 bar = 0.9869 atm; 1 atm = 760 mmHg)</strong> A)   mol/kg.atm B)   mol/kg.atm C)   mol/kg.atm D)   mol/kg.atm E)   mol/kg.atm  mol/kg.atm
D)  <strong>According to the National Institute of Standards webbook,the Henry's Law constant for N<sub>2</sub> gas is 0.00060 mol/kg.bar at 25<sup> \circ </sup>C What is the Henry's law constant in units of mol/kg.atm? (1 bar = 0.9869 atm; 1 atm = 760 mmHg)</strong> A)   mol/kg.atm B)   mol/kg.atm C)   mol/kg.atm D)   mol/kg.atm E)   mol/kg.atm  mol/kg.atm
E)  <strong>According to the National Institute of Standards webbook,the Henry's Law constant for N<sub>2</sub> gas is 0.00060 mol/kg.bar at 25<sup> \circ </sup>C What is the Henry's law constant in units of mol/kg.atm? (1 bar = 0.9869 atm; 1 atm = 760 mmHg)</strong> A)   mol/kg.atm B)   mol/kg.atm C)   mol/kg.atm D)   mol/kg.atm E)   mol/kg.atm  mol/kg.atm
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31
Which of the following liquids will be miscible with water in any proportion: ethanol (CH3CH2OH),carbon tetrachloride (CCl4),hexane (C6H14),and/or formic acid (HCO2H)?

A) ethanol and carbon tetrachloride
B) carbon tetrachloride and hexane
C) ethanol and formic acid
D) ethanol,carbon tetrachloride,and benzene
E) carbon tetrachloride,and formic acid
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32
What mass of Zn(NO3)2 must be diluted to a mass of 1.00 kg with H2O to prepare 97 ppm Zn2+(aq)?

A) 7.8 ×\times 10-6 g
B) 7.8 ×\times 10-3 g
C) 3.3 ×\times 10-2 g
D) 1.3 ×\times 10-1 g
E) 2.8 ×\times 10-1 g
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33
The Henry's law constant for N2 in water at 25 \circ C is 6.0 ×\times 10-4 mol/kg.bar.What is the equilibrium concentration of N2 in water when the partial pressure of N2 is 586 mm Hg? (760 mm Hg = 1 atm = 0.9869 bar)

A) 1.4 ×\times 10-9 M
B) 1.8 ×\times 10-5 M
C) 4.6 ×\times 10-4 M
D) 7.7 ×\times 10-4 M
E) 7.9 ×\times 10-4 M
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34
Which of the following statements concerning solubility is/are CORRECT?
1)Ionic compounds composed of Group 1A metal ions and halide ions,such as NaCl,are insoluble in nonpolar solvents.
2)The solubility of the halogens (Cl2,Br2,and I2)in polar solvents is greater than their solubility in nonpolar solvents.
3)The solubility of polar molecules,such as sugar,in polar solvents is generally greater than their solubility in nonpolar solvents.

A) 1 only
B) 2 only
C) 3 only
D) 1 and 3
E) 1,2,and 3
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35
Which of the following favor(s)the solubility of an ionic solid in a liquid solvent?

A) a small magnitude of the lattice energy of the solute
B) a large magnitude of the solvation energy of the ions
C) a large polarity of the solvent
D) all of the above
E) none of the above
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36
Which of the following statements is/are CORRECT?
1)Solubility is defined as the concentration of solute in equilibrium with undissolved solute in a saturated solution.
2)If two liquids mix to an appreciable extent to form a solution,they are miscible.
3)If two liquids mix completely in any proportion to form a solution,the resulting solution is supersaturated.

A) 1 only
B) 2 only
C) 3 only
D) 1 and 2
E) 2 and 3
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37
The change in energy accompanying the process below is the ____ of MX.
MX(s) \to M+(aq)+ X-(aq)

A) enthalpy of hydration
B) enthalpy of solution
C) lattice energy
D) enthalpy of formation
E) electron attachment enthalpy
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38
Which process is accompanied by the change in energy known as the lattice enthalpy of RbCl?

A) Rb+(g)+ Cl-(g) \to Rb+(aq)+ Cl-(aq)
B) RbCl(s) \to RbCl(aq,1 m)
C) Rb+(g)+ Cl-(g) \to RbCl(s)
D) Rb(s)+  <strong>Which process is accompanied by the change in energy known as the lattice enthalpy of RbCl?</strong> A) Rb<sup>+</sup>(g)+ Cl<sup>-</sup>(g) \to  Rb<sup>+</sup>(aq)+ Cl<sup>-</sup>(aq) B) RbCl(s) \to  RbCl(aq,1 m) C) Rb<sup>+</sup>(g)+ Cl<sup>-</sup>(g) \to  RbCl(s) D) Rb(s)+   Cl<sub>2</sub>(g) \to  RbCl(s) E) Rb(s)+   Cl<sub>2</sub>(g) \to RbCl(aq,1 m)  Cl2(g) \to RbCl(s)
E) Rb(s)+  <strong>Which process is accompanied by the change in energy known as the lattice enthalpy of RbCl?</strong> A) Rb<sup>+</sup>(g)+ Cl<sup>-</sup>(g) \to  Rb<sup>+</sup>(aq)+ Cl<sup>-</sup>(aq) B) RbCl(s) \to  RbCl(aq,1 m) C) Rb<sup>+</sup>(g)+ Cl<sup>-</sup>(g) \to  RbCl(s) D) Rb(s)+   Cl<sub>2</sub>(g) \to  RbCl(s) E) Rb(s)+   Cl<sub>2</sub>(g) \to RbCl(aq,1 m)  Cl2(g) \to RbCl(aq,1 m)
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39
What concentration of silver nitrate (in ppm)is present in 7.1 ×\times 10-7 M AgNO3(aq)? For very dilute aqueous solutions,you can assume the solution's density is 1.0 g/mL.The molar mass of AgNO3 is 169.9 g/mol.

A) 0.0071 ppm
B) 0.12 ppm
C) 0.71 ppm
D) 1.7 ppm
E) 8.3 ppm
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40
At a particular temperature the solubility of O2 in water is 0.590 g/L at an oxygen pressure of 15.2 atm.What is the Henry's law constant for O2?

A) 3.88 ×\times 10-2 L·atm/mol
B) 8.24 ×\times 102 L·atm/mol
C) 2.80 ×\times 10-1 L·atm/mol
D) 1.21 ×\times 10-3 L·atm/mol
E) None of the above.
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41
What is the freezing point of an aqueous 1.36 m NaCl solution? (Kfp for water is 1.858°C/m.)Assume no ion pairing occurs.

A) 5.1°C
B) 2.5°C
C) -5.1°C
D) 0.0°C
E) -2.5°C
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42
The vapor pressure of pure water at 15 \circ C is 12.8 mm Hg.What is the equilibrium vapor pressure of water above a mixture of 72.0 g ethanol (CH3CH2OH,molar mass = 46.07 g/mol)and 22.0 g water?

A) 2.84 mm Hg
B) 5.61 mm Hg
C) 7.19 mm Hg
D) 10.0 mm Hg
E) 12.8 mm Hg
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43
What mass of ethylene glycol,when mixed with 225 g H2O,will reduce the equilibrium vapor pressure of H2O from 1.00 atm to 0.800 atm at 100 \circ C? The molar masses of water and ethylene glycol are 18.02 g/mol and 62.07 g/mol,respectively.Assume ideal behavior for the solution.

A) 15.6 g
B) 49.9 g
C) 194 g
D) 969 g
E) 3.10 ×\times 103 g
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44
Assuming ideal behavior,which of the following aqueous solutions would be expected to exhibit the  smallest\underline{\text{ smallest}} freezing-point lowering?

A) 0.1 m KCl
B) 0.05 m CH3COOH
C) 0.05 m Al2(SO4)3
D) 0.1 m CaCl2
E) 0.25 m C6H12O6
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45
A solution consisting of 0.228 mol of methylbenzene,C6H5CH3,in 255 g of nitrobenzene,C6H5NO2,freezes at -0.3°C.Pure nitrobenzene freezes at 6.0°C.What is the freezing-point depression constant of nitrobenzene?

A) 1.1°C/m
B) 27°C/m
C) 14.0°C/m
D) 3.5°C/m
E) 7.0°C/m
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46
What is the equilibrium partial pressure of water vapor above a mixture of 37.5 g H2O and 62.5 g HOCH2CH2OH at 55 \circ C.The partial pressure of pure water at 55.0 \circ C is 118.0 mm Hg.Assume ideal behavior for the solution.

A) 3.54 mm Hg
B) 31.7 mm Hg
C) 38.5 mm Hg
D) 79.5 mm Hg
E) 175 mm Hg
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47
If the solubility of O2 at 0.360 bar and 25 \circ C is 15.0 g/100 g H2O,what is the solubility of O2 at a pressure of 1.72 bar and 25 \circ C?

A) 71.7 g/100 g H2O
B) 24.2 g/100 g H2O
C) 0.319 g/100 g H2O
D) 0.0140 g/100 g H2O
E) 3.14 g/100 g H2O
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48
For the following gas-liquid equilibrium for an aqueous system at a constant partial pressure of O2,
O2(g) \leftrightarrows O2(aq)
What is the effect on the equilibrium composition of the liquid when the  temperature \underline{\text{ temperature }} of the liquid is decreased?

A) The amount of O2 dissolved in the liquid decreases.
B) The amount of O2 dissolved in the liquid increases.
C) The amount of O2 dissolved in the liquid does not change.
D) Not enough information is provided to answer the question.
E) Either A or B could occur.
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49
Henry's Law constant is 0.034 mol/kg.bar and 0.0013 mol/kg.bar for CO2 and O2 respectively at 25 \circ C.What pressure of O2 is required to achieve the same solubility as 0.218 bar of CO2?

A) 5.7 bar
B) 0.0083 bar
C)  <strong>Henry's Law constant is 0.034 mol/kg.bar and 0.0013 mol/kg.bar for CO<sub>2</sub> and O<sub>2</sub> respectively at 25<sup> \circ </sup>C.What pressure of O<sub>2</sub> is required to achieve the same solubility as 0.218 bar of CO<sub>2</sub>?</strong> A) 5.7 bar B) 0.0083 bar C)   bar D)   bar E) 0.18 bar  bar
D)  <strong>Henry's Law constant is 0.034 mol/kg.bar and 0.0013 mol/kg.bar for CO<sub>2</sub> and O<sub>2</sub> respectively at 25<sup> \circ </sup>C.What pressure of O<sub>2</sub> is required to achieve the same solubility as 0.218 bar of CO<sub>2</sub>?</strong> A) 5.7 bar B) 0.0083 bar C)   bar D)   bar E) 0.18 bar  bar
E) 0.18 bar
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50
Assuming ideal behavior,which of the following aqueous solutions should have the highest boiling point?

A) 1.00 m LiBr
B) 0.75 m K2SO4
C) 0.50 m Ca(NO3)2
D) 0.75 m NaCl
E) 1.25 m C6H12O6
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51
What is the freezing point of a 0.24 m solution of glucose,C6H12O6,in water? (Kfp for water is 1.858°C/m.)

A) 0.22°C
B) 0.45°C
C) -0.45°C
D) -0.22°C
E) -0.89°C
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52
If a 25.0-g sample of a nonelectrolyte is dissolved in 145.0 g of water,the resulting solution will freeze at -0.89°C.What is the molar mass of the nonelectrolyte? (Kfp for water is 1.858°C/m.)

A) 76 g/mol
B) 0.36 g/mol
C) 990 g/mol
D) 290 g/mol
E) 360 g/mol
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53
What is the boiling-point  change \underline{\text{ change }} for a solution containing 0.432 mol of naphthalene (a nonvolatile,nonionizing compound)in 250.g of liquid benzene? (Kbp = 2.53°C/m for benzene)

A) 4.37 °C
B) 5.86 °C
C) 0.273 °C
D) 1.46 °C
E) 1.093 °C
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54
The vapor pressure of water at 90°C is 0.692 atm.What is the vapor pressure (in atm)of a solution made by dissolving 1.28 mole(s)of CsF(s)in 1.00 kg of water? Assume that Raoult's law applies.

A) 0.661 atm
B) 0.676 atm
C) 0.692 atm
D) 0.724 atm
E) none of these
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55
What partial pressure of oxygen gas is required in order for 0.00392 g of the gas to dissolve in 23.7 mL of pure water? The Henry's law constant for oxygen gas is 1.3 ×\times 10-3 M atm-1.

A) 2.2 ×\times 10-7 atm
B) 4.0 ×\times 100 atm
C) 1.6 ×\times 10-7 atm
D) 2.5 ×\times 10-1 atm
E) 4.2 ×\times 10-2 atm
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56
What mass of Na2SO4 must be dissolved in 100.0 grams of water to lower the freezing point by 2.50 \circ C? The freezing point depression constant,Kfp,of water is -1.86 \circ C/m.Assume the van't Hoff factor for Na2SO4 is 2.85.

A) 3.77 g
B) 6.36 g
C) 6.70 g
D) 11.3 g
E) 19.1 g
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57
What is the vapor pressure at 20°C of an ideal solution prepared by the addition of 4.60 g of the nonvolatile solute urea,CO(NH2)2,to 50.2 g of methanol,CH3OH? The vapor pressure of pure methanol at 20°C is 89.0 mmHg.

A) 4.15 mmHg
B) 76.0 mmHg
C) 81.5 mmHg
D) 84.9 mmHg
E) 13.0 mmHg
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58
Ideally,colligative properties depend only on the

A) relative numbers of solute and solvent particles in a solution.
B) molar masses of the solute particles in a solution.
C) density of a solution.
D) hydrated radii of the molecules or ions dissolved in a solution.
E) partial pressure of the gases above the surface of a solution.
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59
For the following gas-aqueous liquid equilibrium for a closed system at a constant temperature,
O2(g) \leftrightarrows O2(aq)
What is the effect on the equilibrium composition of the liquid when the  partial pressure \underline{\text{ partial pressure }} of O2 gas above the liquid is decreased?

A) The amount of O2 dissolved in the liquid decreases.
B) The amount of O2 dissolved in the liquid increases.
C) The amount of O2 dissolved in the liquid does not change.
D) Not enough information is provided to answer the question.
E) Either A or B is possible.
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60
What is the freezing point of a solution containing 2.80 grams benzene (molar mass = 78.11 g/mol)dissolved in 43.0 grams paradichlorobenzene (molar mass = 147.0 g/mol)? The freezing point of pure paradichlorobenzene is 53.0 \circ C and the freezing point depression constant,Kfp,is -7.10 \circ C/m.

A) 46.7 \circ C
B) 47.1 \circ C
C) 58.9 \circ C
D) 52.6 \circ C
E) 58 .9 \circ C
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61
Which of the following solutions would have the highest osmotic pressure?

A) 0.3 M C6H12O6,glucose
B) 0.2 M MgBr2,magnesium bromide
C) 0.2 M KCl,potassium chloride
D) 0.3 M CH3COOH,acetic acid
E) 0.3 M C12H22O11,sucrose
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62
All of the following are colloidal dispersions EXCEPT ____.

A) marshmallow
B) white wine
C) milk
D) whipped cream
E) cheese
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63
A surfactant used for cleaning is called a(n)________.
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64
Because ________ particles are relatively large (say,1000 nm in diameter)they scatter visible light,making the mixtures containing these particles appear cloudy.This scattering is known as the Tyndall effect.
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65
At 37°C,what is the osmotic pressure of a 0.59% NaCl by weight aqueous solution? Assume the density of the solution is 1.0 g/mL.Assume no ion pairing.(R = 0.0821 L · atm/K·mol)

A) 0.26 atm
B) 2.6 atm
C) 3.0 ×\times 102 atm
D) 5.1 atm
E) 0.61 atm
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66
________ are colloidal dispersions of one liquid in another liquid.
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67
What type of colloid is formed when a solid is dispersed in a liquid?

A) foam
B) aerosol
C) sol
D) emulsion
E) gel
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68
Aqueous colloidal solutions can be classified as ________ (water-fearing),or hydrophilic (water-loving).
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69
If one of the factors determining the equilibrium of a system is changed,the system adjusts to counteract that change.This is known as ________ principle.
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70
The osmotic pressure of blood is 7.65 atm at 37 \circ C.What mass of glucose (C6H12O6,molar mass = 180.2 g/mol)is needed to prepare 2.25 L of solution for intravenous injection? The osmotic pressure of the glucose solution must equal the osmotic pressure of blood.(R = 0.08206 L.atm/mol.K)

A) 0.676 g
B) 0.698 g
C) 5.67 g
D) 122 g
E) 1.02 ×\times 103 g
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71
For a dilute solution of NH4NO3,the van't Hoff factor (i)would be approximately ___.

A) 1
B) 2
C) 3
D) 4
E) 5
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72
A 2.3-g sample of a small protein having a molecular weight of 62,000 g/mol is dissolved in 38.8 mL of water at 28°C.What is the osmotic pressure of the solution? (R = 0.0821 L · atm/K·mol; 1 atm = 760 mmHg)

A) 18 mmHg
B) 1100 mmHg
C) 1.7 mmHg
D) 32,000 mmHg
E) 0.024 mmHg
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73
A 0.20 M solution of MgSO4 has an observed osmotic pressure of 7.7 atm at 25°C.Determine the observed van't Hoff factor for this experiment.

A) 2.0
B) 1.6
C) 0.31
D) 19
E) 1.8
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74
Colloids are described by all of the following  except: \textbf{ except: }

A) The particles in a colloid are so small that settling is negligible.
B) The mixture appears cloudy.
C) Only combinations of liquids and gases can form colloids.
D) Colloids are not suspensions or homogeneous mixtures.
E) Mayonnaise,whipped cream and fog are all examples of colloids.
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75
Which of the following statements concerning osmosis is/are CORRECT?
1)Osmosis involves the movement of ions through a semipermeable membrane until the charges on both sides of the membrane are equal.
2)Solvents move from regions of low solute concentration to regions of higher solute concentration.
3)Osmotic pressure is a colligative property.

A) 1 only
B) 2 only
C) 3 only
D) 2 and 3
E) 1,2,and 3
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76
Which of the following solutions has the lowest osmotic pressure?

A) 0.10 M Al(NO3)3
B) 0.20 M NH3
C) 0.15 M Ba(NO2)2
D) 0.10 M CaCl2
E) 0.15 M NaCl
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77
A solution is prepared by dissolving 5.88 g of an unknown nonelectrolyte in enough water to make 0.355 L of solution.The osmotic pressure of the solution is 1.21 atm at 27 \circ C.What is the molar mass of the solute? (R = 0.08206 L.atm/mol.K)

A) 0.00297 g/mol
B) 30.3 g/mol
C) 42.5 g/mol
D) 175 g/mol
E) 337 g/mol
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78
The following equation is known as ________ law: The following equation is known as ________ law:   .
.
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79
Which of the following statements about soaps and detergents is  false? \underline{\text{ false? }}

A) The polar end is attracted to grease and oil.
B) They have a polar and a nonpolar end.
C) They are emulsifiers for grease and oil.
D) Phosphate detergents can produce pollution problems.
E) They can be described as surfactants.
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80
What concentration unit is used in the calculation of osmotic pressure for a dilute solution?

A) molality
B) weight percent
C) mass fraction
D) mole fraction
E) molarity
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