Deck 17: Acid-Base Equilibria and Solubility Equilibria
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Question
Unlock Deck
Sign up to unlock the cards in this deck!
Unlock Deck
Unlock Deck
1/129
Play
Full screen (f)
Deck 17: Acid-Base Equilibria and Solubility Equilibria
1
What is the pH of a solution prepared by mixing 500.mL of 0.10 M NaOCl and 500.mL of 0.20 M HOCl?
[Ka(HOCl)= 3.2 × 10-8]
A)4.10
B)7.00
C)7.19
D)7.49
E)7.80
[Ka(HOCl)= 3.2 × 10-8]
A)4.10
B)7.00
C)7.19
D)7.49
E)7.80
7.19
2
Calculate the pH of a buffer solution that contains 0.25 M benzoic acid (C6H5CO2H)and 0.15 M sodium benzoate (C6H5COONa).(Ka = 6.5 × 10-5 for benzoic acid)
A)3.97
B)4.83
C)4.19
D)3.40
E)4.41
A)3.97
B)4.83
C)4.19
D)3.40
E)4.41
3.97
3
You have 500.0 mL of a buffer solution containing 0.30 M acetic acid (CH3COOH)and 0.20 M sodium acetate (CH3COONa).What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution?
[Ka(CH3COOH)= 1.8 × 10-5]
A)4.65
B)4.71
C)4.56
D)4.84
E)5.07
[Ka(CH3COOH)= 1.8 × 10-5]
A)4.65
B)4.71
C)4.56
D)4.84
E)5.07
4.71
4
Which pair of substances could form a buffered aqueous solution?
A)HCl,NaCl
B)HNO3,NaNO3
C)H3PO4,Na H2PO4
D)H SO4,CH3COOH
E)NH3,NaOH
A)HCl,NaCl
B)HNO3,NaNO3
C)H3PO4,Na H2PO4
D)H SO4,CH3COOH
E)NH3,NaOH
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
5
What is the pH of a buffer solution prepared by dissolving 0.20 mole of cyanic acid (HCNO)and 0.80 mole of sodium cyanate (NaCNO)in enough water to make 1.0 liter of solution? [Ka(HCNO)= 2.0 × 10-4]
A)0.97
B)3.10
C)4.40
D)3.70
E)4.30
A)0.97
B)3.10
C)4.40
D)3.70
E)4.30
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
6
What is the name is used to describe the situation when a compound containing an ion in common with a dissolved substance is added to a solution at equilibrium which shifts the equilibrium?
A)Shift ion
B)Shift reagent
C)Equilibrium ion
D)Common ion effect
E)Ion adduct
A)Shift ion
B)Shift reagent
C)Equilibrium ion
D)Common ion effect
E)Ion adduct
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
7
Calculate the pH of a buffer solution prepared by dissolving 0.20 mole of sodium cyanate (NaCNO)and 1.0 mole of cyanic acid (HCNO)in enough water to make 1.0 liter of solution. [Ka(HCNO)= 2.0 × 10-4]
A)0.00
B)3.00
C)3.70
D)4.40
E)5.00
A)0.00
B)3.00
C)3.70
D)4.40
E)5.00
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
8
What is the effect on the equilibrium when sodium formate is added to a solution of formic acid? HCOOH(aq)
H+(aq)+ HCOO-(aq)
A)There is no change in the equilibrium.
B)The equilibrium shifts to the right.
C)More information is needed to answer the question.
D)The equilibrium shifts to the left.
E)The pH decreases.

A)There is no change in the equilibrium.
B)The equilibrium shifts to the right.
C)More information is needed to answer the question.
D)The equilibrium shifts to the left.
E)The pH decreases.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
9
Which pair of substances is capable of forming a buffer in aqueous solution?
A)H3PO4,Na3PO3
B)HNO3,NaNO3
C)HCl,NaCl
D)H2CO3,NaNO2
E)CH3COOH,CH3COONa
A)H3PO4,Na3PO3
B)HNO3,NaNO3
C)HCl,NaCl
D)H2CO3,NaNO2
E)CH3COOH,CH3COONa
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
10
Which may be used to prepare a buffer having a pH of 8.8? Ka = 7 × 10-3 for H3PO4; 8 × 10-8 for H2PO4-; 5 × 10-13 for HP O42-
A)NaH2PO4 only
B)NaH2PO4 and Na2HPO4
C)Na3PO4 and Na2HPO4
D)NaHPO4 and H3PO4
E)H3PO4 and Na3PO4
A)NaH2PO4 only
B)NaH2PO4 and Na2HPO4
C)Na3PO4 and Na2HPO4
D)NaHPO4 and H3PO4
E)H3PO4 and Na3PO4
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
11
What is the pH of a solution that is 0.410 M in HOCl and 0.050 M in NaOCl? [Ka(HOCl)= 3.2 × 10-8]
A)0.39
B)3.94
C)6.58
D)7.49
E)8.40
A)0.39
B)3.94
C)6.58
D)7.49
E)8.40
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
12
What molar ratio of CH3COOH to CH3COONa should be used in order to prepare an acetic acid / sodium acetate buffer solution with a pH of 4.00 ± 0.02? [Ka(CH3COOH)= 1.8 × 10-5]
A)0.18
B)0.84
C)1.2
D)5.6
E)0.10
A)0.18
B)0.84
C)1.2
D)5.6
E)0.10
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
13
You have 500.0 mL of a buffer solution containing 0.20 M acetic acid (CH3COOH)and 0.30 M sodium acetate (CH3COONa).What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution? [Ka(CH3COOH)= 1.8 × 10-5]
A)4.41
B)4.74
C)4.56
D)4.92
E)5.07
A)4.41
B)4.74
C)4.56
D)4.92
E)5.07
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
14
Which of the following acids is the best acid to prepare a buffer with the highest pH?
A)C5H5O5COOH,Ka = 4.0 × 10-6
B)HOC6H4OCOOH,Ka = 1.0 × 10-3
C)HBrO,Ka = 2.3 × 10-9
D)C6H4(COOH)2,Ka = 2.9 × 10-4
E)CH3COOH,Ka = 1.8 × 10-5
A)C5H5O5COOH,Ka = 4.0 × 10-6
B)HOC6H4OCOOH,Ka = 1.0 × 10-3
C)HBrO,Ka = 2.3 × 10-9
D)C6H4(COOH)2,Ka = 2.9 × 10-4
E)CH3COOH,Ka = 1.8 × 10-5
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
15
When the concentration of the conjugate base of a weak acid is less than the concentration of the weak acid in a buffer solution,the pH of the solution is
A)less than the pKa.
B)greater than the pKa.
C)always acidic.
D)always basic.
E)equal to the pKa.
A)less than the pKa.
B)greater than the pKa.
C)always acidic.
D)always basic.
E)equal to the pKa.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
16
What happens to the solution if sodium acetate is added to a solution of acetic acid? CH3COOH(aq)
H+ (aq)+ CH3COO- (aq)
A)The equilibrium shifts to the right.
B)There is an increase in percent ionization of acetic acid.
C)Less of hydrogen ion is consumed.
D)There is an increased concentration of acetate ions.
E)Less of the acetate ion is consumed.

A)The equilibrium shifts to the right.
B)There is an increase in percent ionization of acetic acid.
C)Less of hydrogen ion is consumed.
D)There is an increased concentration of acetate ions.
E)Less of the acetate ion is consumed.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
17
Which pair of substances cannot form a buffered aqueous solution?
A)HCN and KCN
B)NH3 and (NH4)2SO4
C)HNO3 and NaNO3
D)HF and NaF
E)HNO2 and NaNO2
A)HCN and KCN
B)NH3 and (NH4)2SO4
C)HNO3 and NaNO3
D)HF and NaF
E)HNO2 and NaNO2
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
18
What is the effect on equilibrium when sodium acetate is added to a solution of acetic acid? CH3COOH(aq)
H+(aq)+ CH3COO-(aq)
A)There is no change in the equilibrium.
B)The equilibrium shifts to the right.
C)More information is needed to answer the question.
D)The equilibrium shifts to the left.
E)The pH decreases.

A)There is no change in the equilibrium.
B)The equilibrium shifts to the right.
C)More information is needed to answer the question.
D)The equilibrium shifts to the left.
E)The pH decreases.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
19
Which results in a buffered solution?
A)A solution containing a strong acid and its conjugate base
B)A solution containing a strong base and its conjugate acid
C)A solution containing a catalyst
D)A solution containing two organic liquids
E)A solution containing a weak acid and its conjugate base
A)A solution containing a strong acid and its conjugate base
B)A solution containing a strong base and its conjugate acid
C)A solution containing a catalyst
D)A solution containing two organic liquids
E)A solution containing a weak acid and its conjugate base
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
20
What is the Henderson-Hasselbach equation?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
21
What is the pH of a solution that consists of 0.50 M H2C6H6O6 (ascorbic acid)and 0.75 M NaHC6H6O6 (sodium ascorbate)?
[Ka (H2C6H6O6)= 6.8 × 10-5]
A)3.76
B)3.99
C)4.34
D)4.57
E)5.66
[Ka (H2C6H6O6)= 6.8 × 10-5]
A)3.76
B)3.99
C)4.34
D)4.57
E)5.66
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
22
Which of the following is correct for the equivalence point in an acid-base titration?
A)The pH is at its highest value for any reaction.
B)The amounts of acid and base combined are in a stoichiometric ratio at the equivalence point in an acid-base titration.
C)The pH is 7.0.
D)The pH is equal to the pKa of the weak acid.
E)The pH is equal to the pKb of the weak base.
A)The pH is at its highest value for any reaction.
B)The amounts of acid and base combined are in a stoichiometric ratio at the equivalence point in an acid-base titration.
C)The pH is 7.0.
D)The pH is equal to the pKa of the weak acid.
E)The pH is equal to the pKb of the weak base.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
23
A 50.00-mL solution of 0.10 M HNO2 is titrated with a 0.10 M KOH solution.After 25.00 mL of the KOH solution is added,what is the pH in the titration flask?
[Ka(HNO2)= 4.5 × 10-4]
A)2.17
B)3.35
C)2.41
D)1.48
E)7.00
[Ka(HNO2)= 4.5 × 10-4]
A)2.17
B)3.35
C)2.41
D)1.48
E)7.00
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
24
A buffer is prepared by adding 1.00 L of 1.0 M HCl to 750 mL of 1.5 M NaHCOO.What is the pH of this buffer? [Ka (HCOOH)= 1.7 × 10-4]
A)2.87
B)3.72
C)3.82
D)3.95
E)4.66
A)2.87
B)3.72
C)3.82
D)3.95
E)4.66
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
25
A buffer is prepared by adding 150 mL of 1.0 M NaOH to 250 mL of 1.0 M NaH2PO4.How many moles of HCl must be added to this buffer solution to change the pH by 0.18 units?
A)0.025 mol HCl
B)0.063 mol HCl
C)0.082 mol HCl
D)0.50 mol HCl
E)1.0 mol HCl
A)0.025 mol HCl
B)0.063 mol HCl
C)0.082 mol HCl
D)0.50 mol HCl
E)1.0 mol HCl
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
26
A buffer is prepared by adding 300.0 mL of 2.0 M NaOH to 500.0 mL of 2.0 M CH3COOH.What is the pH of this buffer? [Ka(CH3COOH)= 1.8 × 10-5]
A)4.57
B)4.52
C)4.87
D)4.92
E)4.97
A)4.57
B)4.52
C)4.87
D)4.92
E)4.97
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
27
Which best describes the pH at the equivalence point of a titration of a weak acid with a strong base?
A)Less than zero
B)Between 0 and 7
C)Close to 7.0
D)Between 7 and 14
E)Greater than 14
A)Less than zero
B)Between 0 and 7
C)Close to 7.0
D)Between 7 and 14
E)Greater than 14
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
28
What is the [H3O+] in a solution that consists of 1.5 M NH3 and 2.5 M NH4Cl? Kb = 1.8 × 10-5
A)1.1 × 10-5 M
B)3.0 × 10-6 M
C)3.3 × 10-9 M
D)5.6 × 10-10 M
E)9.3 × 10-10 M
A)1.1 × 10-5 M
B)3.0 × 10-6 M
C)3.3 × 10-9 M
D)5.6 × 10-10 M
E)9.3 × 10-10 M
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
29
What is the pH at the equivalence point in the titration of 100 mL of 0.10 M HCl with 0.10 M NaOH?
A)1.0
B)6.0
C)7.0
D)8.0
E)13.0
A)1.0
B)6.0
C)7.0
D)8.0
E)13.0
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
30
A 20.0-mL sample of 0.25 M HNO3 is titrated with 0.15 M NaOH.What is the pH of the solution after 30.0 mL of NaOH have been added to the acid?
A)2.00
B)1.60
C)1.05
D)1.00
E)0.00
A)2.00
B)1.60
C)1.05
D)1.00
E)0.00
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
31
An acetic acid buffer containing 0.50 M CH3COOH and 0.50 M CH3COONa has a pH of 4.74.What will the pH be after 0.0020 mol of HCl has been added to 100.0 mL of the buffer?
A)4.77
B)4.71
C)4.68
D)4.62
E)1.70.
A)4.77
B)4.71
C)4.68
D)4.62
E)1.70.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
32
What is the pH of a buffer that consists of 0.20 M Na H2PO4 and 0.40 M Na2HPO4? [Ka(Na H2PO4)= 6.2 × 10-8]
A)6.51
B)6.91
C)7.51
D)7.90
E)8.13
A)6.51
B)6.91
C)7.51
D)7.90
E)8.13
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
33
Which is the best acid to prepare a buffer with the lowest pH?
A)C5H5O5COOH,Ka = 4.0 × 10-6
B)HOC6H4OCOOH,Ka = 1.0 × 10-3
C)HBrO,Ka = 2.3 × 10-9
D)C6H4(COOH)2,Ka = 2.9 × 10-4
E)CH3COOH,Ka = 1.8 × 10-5
A)C5H5O5COOH,Ka = 4.0 × 10-6
B)HOC6H4OCOOH,Ka = 1.0 × 10-3
C)HBrO,Ka = 2.3 × 10-9
D)C6H4(COOH)2,Ka = 2.9 × 10-4
E)CH3COOH,Ka = 1.8 × 10-5
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
34
A 50.0-mL sample of 0.50 M HCl is titrated with 0.50 M NaOH.What is the pH of the solution after 28.0 mL of NaOH have been added to the acid?
A)0.85
B)2.96
C)2.85
D)1.49
E)3.81
A)0.85
B)2.96
C)2.85
D)1.49
E)3.81
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
35
A 20.00-mL sample of 0.3000 M HBr is titrated with 0.15 M NaOH.What is the pH of the solution after 40.3 mL of NaOH have been added to the acid?
A)1.00
B)3.13
C)10.87
D)11.05
E)13.14
A)1.00
B)3.13
C)10.87
D)11.05
E)13.14
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
36
What is the pH of a buffer that consists of 0.45 M CH3COOH and 0.35 M CH3COONa? [Ka(CH3COOH)= 1.8 × 10-5]
A)3.43
B)4.64
C)4.85
D)4.74
E)6.06
A)3.43
B)4.64
C)4.85
D)4.74
E)6.06
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
37
What is the [H3O+] in a buffer that consists of 0.30 M HCOOH and 0.20 M HCOONa? [Ka(HCOOH)= 1.7 × 10-4]
A)1.1 × 10-4 M
B)2.6 × 10-4 M
C)4.3 × 10-4 M
D)6.7 × 10-5 M
E)1.7 × 10-4 M
A)1.1 × 10-4 M
B)2.6 × 10-4 M
C)4.3 × 10-4 M
D)6.7 × 10-5 M
E)1.7 × 10-4 M
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
38
Which best describes the pH at the equivalence point of a titration of a weak base with a strong acid?
A)Less than zero
B)Between 0 and 7
C)Close to 7.0
D)Between 7 and 14
E)Greater than 14
A)Less than zero
B)Between 0 and 7
C)Close to 7.0
D)Between 7 and 14
E)Greater than 14
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
39
Which is the best choice for preparing a buffer with a pH of 3.5?
A)C5H5O5COOH,Ka = 4.0 × 10-6
B)HOC6H4OCOOH,Ka = 1.0 × 10-3
C)HBrO,Ka = 2.3 × 10-9
D)C6H4(COOH)2,Ka = 2.9 × 10-4
E)CH3COOH,Ka = 1.8 ×10-5
A)C5H5O5COOH,Ka = 4.0 × 10-6
B)HOC6H4OCOOH,Ka = 1.0 × 10-3
C)HBrO,Ka = 2.3 × 10-9
D)C6H4(COOH)2,Ka = 2.9 × 10-4
E)CH3COOH,Ka = 1.8 ×10-5
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
40
Which of the following is an exact or approximate value of the pH at the equivalence point of a titration of a strong acid with a strong base?
A)14.0
B)7.0
C)3.5
D)1.0
E)0.0
A)14.0
B)7.0
C)3.5
D)1.0
E)0.0
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
41
Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak diprotic acid H2A (0.10 M)with a strong base of the same concentration?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
42
When a strong acid is titrated with a strong base,the pH at the equivalence point
A)is greater than 7.0.
B)is equal to 7.0.
C)is between 3.5 and 7.0.
D)is equal to the p Ka of the acid.
E)is equal to 3.5.
A)is greater than 7.0.
B)is equal to 7.0.
C)is between 3.5 and 7.0.
D)is equal to the p Ka of the acid.
E)is equal to 3.5.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
43
A 35.0-mL sample of 0.20 M LiOH is titrated with 0.25 M HCl.What is the pH of the solution after 23.0 mL of HCl have been added to the base?
A)1.26
B)1.67
C)12.33
D)12.74
E)13.03
A)1.26
B)1.67
C)12.33
D)12.74
E)13.03
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
44
When a weak acid is titrated with a strong base,the pH at the equivalence point
A)is greater than 7.0.
B)is equal to 7.0.
C)is less than 7.0.
D)is equal to the pKa of the acid.
E)is equal to the pKb of the conjugate base.
A)is greater than 7.0.
B)is equal to 7.0.
C)is less than 7.0.
D)is equal to the pKa of the acid.
E)is equal to the pKb of the conjugate base.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
45
For PbCl2 (Ksp = 2.4 × 10-4),will a precipitate of PbCl2 form when 0.10 L of 3.0 × 10-2M Pb(NO3)2 is added to 400 mL of 9.0 × 10-2M NaCl?
A)Yes,because Q > Ksp.
B)No,because Q < Ksp.
C)No,because Q = Ksp.
D)Yes,because Q < Ksp.
A)Yes,because Q > Ksp.
B)No,because Q < Ksp.
C)No,because Q = Ksp.
D)Yes,because Q < Ksp.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
46
When a weak acid is titrated with a weak base,the pH at the equivalence point
A)is greater than 7.0.
B)is equal to 7.0.
C)is less than 7.0.
D)is determined by the magnitudes of Ka and Kb.
E)depends on the pKa of the indicator.
A)is greater than 7.0.
B)is equal to 7.0.
C)is less than 7.0.
D)is determined by the magnitudes of Ka and Kb.
E)depends on the pKa of the indicator.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
47
Methyl red is a common acid-base indicator.It has a Ka equal to 6.3 × 10-6.Its un-ionized form is red and its anionic form is yellow.What color would a methyl red solution have at pH = 7.8?
A)green
B)red
C)blue
D)yellow
E)violet
A)green
B)red
C)blue
D)yellow
E)violet
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
48
40.0 ml of an acetic acid of unknown concentration is titrated with 0.100 M NaOH.After 20.0 mL of the base solution has been added,the pH in the titration flask is 5.10.What was the concentration of the original acetic acid solution? (Ka(CH3COOH)= 1.8 × 10-5)
A)0.11 M
B)0.022 M
C)0.072 M
D)0.050 M
E)0.015 M
A)0.11 M
B)0.022 M
C)0.072 M
D)0.050 M
E)0.015 M
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
49
Calculate the pH at the equivalence point for the titration of 50.0 mL of 0.20 M NH3 with 0.20 M HCl. [Kb(NH3)= 1.8 × 10-5]
A)2.87
B)4.98
C)5.13
D)7.00
E)11.13
A)2.87
B)4.98
C)5.13
D)7.00
E)11.13
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
50
A 25.0-mL sample of 0.10 M C2H5NH2 (ethylamine)is titrated with 0.15 M HCl.What is the pH of the solution after 9.00 mL of acid have been added to the amine? [Kb(C2H5NH2)= 6.5 × 10-4]
A)11.08
B)10.74
C)10.81
D)10.55
E)10.49
A)11.08
B)10.74
C)10.81
D)10.55
E)10.49
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
51
A 20.0-mL sample of 0.30 M HClO was titrated with 0.30 M NaOH.The following data were collected during the titration.Determine to Ka for HClO. mL NaOH added
5)00
10)00
15)00
20)00
PH
6)98
7)46
7)93
10)31
A)1.1 × 10-7
B)3.5 × 10-8
C)1.2 × 10-8
D)4.9 × 10-11
E)None of the answers is correct.
5)00
10)00
15)00
20)00
PH
6)98
7)46
7)93
10)31
A)1.1 × 10-7
B)3.5 × 10-8
C)1.2 × 10-8
D)4.9 × 10-11
E)None of the answers is correct.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
52
A 10.0-mL sample of 0.75 M CH3CH2COOH is titrated with 0.30 M NaOH.What is the pH of the solution after 22.0 mL of NaOH have been added to the acid? [Ka(CH3CH2COOH)= 1.3 × 10-5]
A)5.75
B)4.94
C)4.83
D)4.02
E)3.95
A)5.75
B)4.94
C)4.83
D)4.02
E)3.95
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
53
Calculate the pH of the solution resulting from the addition of 10.0 mL of 0.10 M NaOH to 50.0 mL of 0.10 M HCN (Ka = 4.9 × 10-10)solution.
A)5.15
B)8.71
C)5.85
D)9.91
E)13.0
A)5.15
B)8.71
C)5.85
D)9.91
E)13.0
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
54
A 25.0-mL sample of 1.00 M NH3 is titrated with 0.15 M HCl.What is the pH of the solution after 15.00 mL of acid have been added to the ammonia solution? [Kb(NH3)= 1.8 × 10-5]
A)10.26
B)9.30
C)9.21
D)8.30
E)8.21
A)10.26
B)9.30
C)9.21
D)8.30
E)8.21
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
55
Which is included in the Ksp expression? I.Concentration of cation
II)Concentration of anion
III)Concentration of solid
A)I only
B)II only
C)III only
D)I and II
E)I,II and III
II)Concentration of anion
III)Concentration of solid
A)I only
B)II only
C)III only
D)I and II
E)I,II and III
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
56
Which of the following is correct?
A)Solubility is the concentration of unsaturated ions in solution.
B)Ksp is the same as the solubility.
C)Ksp is an equilibrium constant and solubility is the concentration of a saturated solution.
D)Ksp is the solubility product constant for a precipitate.
E)Solubility = Kw × Ksp.
A)Solubility is the concentration of unsaturated ions in solution.
B)Ksp is the same as the solubility.
C)Ksp is an equilibrium constant and solubility is the concentration of a saturated solution.
D)Ksp is the solubility product constant for a precipitate.
E)Solubility = Kw × Ksp.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
57
When a strong acid is titrated with a weak base,the pH at the equivalence point
A)is greater than 7.0.
B)is equal to 7.0.
C)is less than 7.0.
D)is equal to the pKa of the conjugate acid.
E)is equal to the pKb of the base.
A)is greater than 7.0.
B)is equal to 7.0.
C)is less than 7.0.
D)is equal to the pKa of the conjugate acid.
E)is equal to the pKb of the base.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
58
The indicator propyl red has Ka = 3.3 × 10-6.What would be the approximate pH range over which it would change color?
A)3.5 - 5.5
B)4.5 - 6.5
C)5.5 - 7.5
D)6.5 - 8.5
E)7.5 - 9.5
A)3.5 - 5.5
B)4.5 - 6.5
C)5.5 - 7.5
D)6.5 - 8.5
E)7.5 - 9.5
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
59
Which indicator would be the best to use if 0.050 M benzoic acid (Ka = 6.6 × 10-5)is titrated with 0.050 M NaOH?
A)bromphenol blue,pH range: 3.0 - 4.5
B)bromcresol green,pH range: 3.8 - 5.4
C)alizarin,pH range: 5.7 - 7.2
D)phenol red,pH range: 6.9 - 8.5
A)bromphenol blue,pH range: 3.0 - 4.5
B)bromcresol green,pH range: 3.8 - 5.4
C)alizarin,pH range: 5.7 - 7.2
D)phenol red,pH range: 6.9 - 8.5
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
60
The solubility of lead(II)iodide is 0.064 g/100 mL at 20°C.What is the solubility product for lead(II)iodide?
A)1.1 × 10-8
B)2.7 × 10-9
C)1.1 × 10-11
D)2.7 × 10-12
E)1.1 × 10-3
A)1.1 × 10-8
B)2.7 × 10-9
C)1.1 × 10-11
D)2.7 × 10-12
E)1.1 × 10-3
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
61
Suppose 0.015 mol of KOH is added to 1.00 L of 0.0010 M Ca(NO3)2.Which statement is correct? [Ksp(Ca(OH)2)= 6.5 × 10-6]
A)Calcium hydroxide precipitates until the solution is saturated.
B)The solution is unsaturated and no precipitate forms.
C)The concentration of calcium ions is reduced by the addition of the hydroxide ions.
D)Potassium nitrate precipitates until the solution is saturated.
E)The presence of KOH will raise the solubility of Ca(NO3)2.
A)Calcium hydroxide precipitates until the solution is saturated.
B)The solution is unsaturated and no precipitate forms.
C)The concentration of calcium ions is reduced by the addition of the hydroxide ions.
D)Potassium nitrate precipitates until the solution is saturated.
E)The presence of KOH will raise the solubility of Ca(NO3)2.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
62
The molar solubility of magnesium carbonate is 1.8 × 10-4 mol/L.What is Ksp for this compound?
A)1.8 × 10-4
B)3.6 × 10-4
C)1.3 × 10-7
D)3.2 × 10-8
E)2.8 × 10-14
A)1.8 × 10-4
B)3.6 × 10-4
C)1.3 × 10-7
D)3.2 × 10-8
E)2.8 × 10-14
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
63
mL of 0.150 M KI? [Ksp(PbI2)=1.4 × 10-8]
A)2.2 × 10-2 M
B)1.5 × 10-7 M
C)6.2 × 10-7 M
D)9.3 × 10-8 M
E)1.4 × 10-8 M
A)2.2 × 10-2 M
B)1.5 × 10-7 M
C)6.2 × 10-7 M
D)9.3 × 10-8 M
E)1.4 × 10-8 M
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
64
The solubility of lead(II)chloride is 0.45 g/100 mL of solution.What is the Ksp of PbCl2?
A)4.9 × 10-2
B)1.7 × 10-5
C)8.5 × 10-6
D)4.2 × 10-6
E)2.6 × 10-4
A)4.9 × 10-2
B)1.7 × 10-5
C)8.5 × 10-6
D)4.2 × 10-6
E)2.6 × 10-4
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
65
Calculate the solubility of silver oxalate,Ag2C2 O4,in pure water. [Ksp(Ag2C2O4)= 1.0 × 10-11]
A)1.4 × 10-4 M
B)8.2 × 10-5 M
C)5.4 × 10-5 M
D)3.2 × 10-6 M
E)2.5 × 10-12 M
A)1.4 × 10-4 M
B)8.2 × 10-5 M
C)5.4 × 10-5 M
D)3.2 × 10-6 M
E)2.5 × 10-12 M
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
66
Does a precipitate of magnesium fluoride form if 300.0 mL of 1.1 × 10-3 M MgCl2 are added to 500.0 mL of 1.2 × 10-3 M NaF?
[Ksp (MgF2)= 6.9 × 10-9]
A)Yes,because Q > Ksp.
B)No,because Q < Ksp.
C)No,because Q = Ksp.
D)Yes,because Q < Ksp.
E)No,because Q > Ksp.
[Ksp (MgF2)= 6.9 × 10-9]
A)Yes,because Q > Ksp.
B)No,because Q < Ksp.
C)No,because Q = Ksp.
D)Yes,because Q < Ksp.
E)No,because Q > Ksp.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
67
The solubility of magnesium phosphate is 2.27 × 10-3 g/1.0 L of solution.What is the Ksp for Mg3(P O4)2?
A)7.46 × 10-11
B)2.68 × 10-9
C)5.19 × 10-24
D)4.80 × 10-26
E)1.20 × 10-26
A)7.46 × 10-11
B)2.68 × 10-9
C)5.19 × 10-24
D)4.80 × 10-26
E)1.20 × 10-26
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
68
Will a precipitate (ppt)form when 300.0 mL of 5.0 × 10-5M AgNO3 are added to 200.0 mL of 2.5 × 10-7M NaBr? Answer yes or no,and identify the precipitate if there is one.
A)Yes,the ppt is AgNO3(s).
B)Yes,the ppt is AgBr(s).
C)Yes,the ppt is NaBr(s).
D)Yes,the ppt is NaNO3(s).
E)No,a precipitate will not form.
A)Yes,the ppt is AgNO3(s).
B)Yes,the ppt is AgBr(s).
C)Yes,the ppt is NaBr(s).
D)Yes,the ppt is NaNO3(s).
E)No,a precipitate will not form.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
69
Calculate the solubility of zinc hydroxide,Zn(OH)2,in 1.00 M NaOH.Ksp = 3.0 × 10-16 for Zn(OH)2,Kf = 3.0 × 1015 for Zn(OH)42-
A)0.60 M
B)0.52 M
C)0.37 M
D)0.32 M
E)0.24 M
A)0.60 M
B)0.52 M
C)0.37 M
D)0.32 M
E)0.24 M
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
70
Calculate the minimum concentration of Cr3+ that must be added to 0.095 M NaF in order to initiate a precipitate of chromium(III)fluoride.[Ksp(CrF3)= 6.6 × 10-11]
A)0.023 M
B)0.032 M
C)7.7 × 10-8 M
D)2.9 × 10-9 M
E)6.9 × 10-10 M
A)0.023 M
B)0.032 M
C)7.7 × 10-8 M
D)2.9 × 10-9 M
E)6.9 × 10-10 M
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
71
Which compound has the lowest solubility in pure water?
A)Ag2C2O4,Ksp = 1.0 × 10-11
B)PbCl2,Ksp = 1.7 × 10-5
C)FePO4,Ksp = 1.3 × 10-22
D)Ca3(PO4)2,Ksp = 1.2 × 10-26
E)MgF2,Ksp = 6.9 × 10-9
A)Ag2C2O4,Ksp = 1.0 × 10-11
B)PbCl2,Ksp = 1.7 × 10-5
C)FePO4,Ksp = 1.3 × 10-22
D)Ca3(PO4)2,Ksp = 1.2 × 10-26
E)MgF2,Ksp = 6.9 × 10-9
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
72
Consider the dissolution of MnS in water.[Ksp(MnS)=3.0 × 10-14] MnS(s)+ H2O(l)
Mn2+(aq)+ HS-(aq)+ OH-(aq)
How is the solubility of manganese(II)sulfide affected by the addition of aqueous potassium hydroxide to the system?
A)The solubility will be unchanged.
B)The solubility will decrease.
C)The solubility will increase.
D)The amount of KOH added must be known before its effect can be predicted.
E)The pKa of H2S is needed before a reliable prediction can be made.
![<strong>Consider the dissolution of MnS in water.[K<sub>sp</sub>(MnS)=3.0 × 10<sup>-14</sup>] MnS(s)+ H<sub>2</sub>O(l) Mn<sup>2+</sup>(aq)+ HS<sup>-</sup>(aq)+ OH<sup>-</sup>(aq) How is the solubility of manganese(II)sulfide affected by the addition of aqueous potassium hydroxide to the system?</strong> A)The solubility will be unchanged. B)The solubility will decrease. C)The solubility will increase. D)The amount of KOH added must be known before its effect can be predicted. E)The pK<sub>a</sub> of H<sub>2</sub>S is needed before a reliable prediction can be made.](https://d2lvgg3v3hfg70.cloudfront.net/TB6485/11eab46b_9c97_1a65_a889_c74f69c2273e_TB6485_11.jpg)
How is the solubility of manganese(II)sulfide affected by the addition of aqueous potassium hydroxide to the system?
A)The solubility will be unchanged.
B)The solubility will decrease.
C)The solubility will increase.
D)The amount of KOH added must be known before its effect can be predicted.
E)The pKa of H2S is needed before a reliable prediction can be made.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
73
Write the ion product expression for calcium phosphate,Ca3(P O4)2.
A)![<strong>Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(P O<sub>4</sub>)<sub>2</sub>.</strong> A) B) C) D) E)(3 × [Ca<sup>2+</sup>])(2 × [P O<sub>4</sub><sup>3-</sup> ]](https://d2lvgg3v3hfg70.cloudfront.net/TB6485/11eab46b_9c95_e1e1_a889_4712d3a6a45a_TB6485_11.jpg)
B)![<strong>Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(P O<sub>4</sub>)<sub>2</sub>.</strong> A) B) C) D) E)(3 × [Ca<sup>2+</sup>])(2 × [P O<sub>4</sub><sup>3-</sup> ]](https://d2lvgg3v3hfg70.cloudfront.net/TB6485/11eab46b_9c96_08f2_a889_b5f839c32262_TB6485_11.jpg)
C)![<strong>Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(P O<sub>4</sub>)<sub>2</sub>.</strong> A) B) C) D) E)(3 × [Ca<sup>2+</sup>])(2 × [P O<sub>4</sub><sup>3-</sup> ]](https://d2lvgg3v3hfg70.cloudfront.net/TB6485/11eab46b_9c96_08f3_a889_33c6df9cc56c_TB6485_11.jpg)
D)![<strong>Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(P O<sub>4</sub>)<sub>2</sub>.</strong> A) B) C) D) E)(3 × [Ca<sup>2+</sup>])(2 × [P O<sub>4</sub><sup>3-</sup> ]](https://d2lvgg3v3hfg70.cloudfront.net/TB6485/11eab46b_9c96_3004_a889_adbdbd5fb73c_TB6485_11.jpg)
E)(3 × [Ca2+])(2 × [P O43- ]
A)
![<strong>Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(P O<sub>4</sub>)<sub>2</sub>.</strong> A) B) C) D) E)(3 × [Ca<sup>2+</sup>])(2 × [P O<sub>4</sub><sup>3-</sup> ]](https://d2lvgg3v3hfg70.cloudfront.net/TB6485/11eab46b_9c95_e1e1_a889_4712d3a6a45a_TB6485_11.jpg)
B)
![<strong>Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(P O<sub>4</sub>)<sub>2</sub>.</strong> A) B) C) D) E)(3 × [Ca<sup>2+</sup>])(2 × [P O<sub>4</sub><sup>3-</sup> ]](https://d2lvgg3v3hfg70.cloudfront.net/TB6485/11eab46b_9c96_08f2_a889_b5f839c32262_TB6485_11.jpg)
C)
![<strong>Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(P O<sub>4</sub>)<sub>2</sub>.</strong> A) B) C) D) E)(3 × [Ca<sup>2+</sup>])(2 × [P O<sub>4</sub><sup>3-</sup> ]](https://d2lvgg3v3hfg70.cloudfront.net/TB6485/11eab46b_9c96_08f3_a889_33c6df9cc56c_TB6485_11.jpg)
D)
![<strong>Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(P O<sub>4</sub>)<sub>2</sub>.</strong> A) B) C) D) E)(3 × [Ca<sup>2+</sup>])(2 × [P O<sub>4</sub><sup>3-</sup> ]](https://d2lvgg3v3hfg70.cloudfront.net/TB6485/11eab46b_9c96_3004_a889_adbdbd5fb73c_TB6485_11.jpg)
E)(3 × [Ca2+])(2 × [P O43- ]
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
74
Will a precipitate (ppt)form when 20.0 mL of 1.1 × 10-3 M Ba(NO3)2 are added to 80.0 mL of 8.4 ×10-4M Na2CO3?
A)Yes,the ppt is Ba(NO3)2.
B)Yes,the ppt is NaNO3.
C)Yes,the ppt is BaCO3.
D)Yes,the ppt is Na2CO3.
E)No,a precipitate will not form.
A)Yes,the ppt is Ba(NO3)2.
B)Yes,the ppt is NaNO3.
C)Yes,the ppt is BaCO3.
D)Yes,the ppt is Na2CO3.
E)No,a precipitate will not form.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
75
The molar solubility of tin(II)iodide is 1.28 × 10-2 mol/L.What is Ksp for this compound?
A)8.39 × 10-6
B)1.28 × 10-2
C)4.20 × 10-6
D)1.64 × 10-4
E)2.10 × 10-6
A)8.39 × 10-6
B)1.28 × 10-2
C)4.20 × 10-6
D)1.64 × 10-4
E)2.10 × 10-6
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
76
If 50.0 mL of 1.2 × 10-3 M Pb(NO3)2 are added to 50.0 mL of 2.0 × 10-4 M Na2S,what takes place?
A)A precipitate of PbS forms.
B)A precipitate of NaNO3 forms.
C)A precipitate of Na2S forms.
D)A precipitate of Pb(NO3)2 forms.
E)No precipitate forms.
A)A precipitate of PbS forms.
B)A precipitate of NaNO3 forms.
C)A precipitate of Na2S forms.
D)A precipitate of Pb(NO3)2 forms.
E)No precipitate forms.
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
77
Which compound has the highest solubility in pure water?
A)Ag2C2O4,Ksp = 1.0 × 10-11
B)PbCl2,Ksp = 1.7 × 10-5
C)CaSO4,Ksp = 2.4 × 10-5
D)Ca3(PO4)2,Ksp = 1.2 × 10-26
E)MgF2,Ksp = 6.9 × 10-9
A)Ag2C2O4,Ksp = 1.0 × 10-11
B)PbCl2,Ksp = 1.7 × 10-5
C)CaSO4,Ksp = 2.4 × 10-5
D)Ca3(PO4)2,Ksp = 1.2 × 10-26
E)MgF2,Ksp = 6.9 × 10-9
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
78
The molar solubility of manganese(II)carbonate is 4.2 × 10-6 M.What is Ksp for this compound?
A)4.2 × 10-6
B)8.4 × 10-6
C)3.0 × 10-16
D)1.8 × 10-11
E)2.0 × 10-3
A)4.2 × 10-6
B)8.4 × 10-6
C)3.0 × 10-16
D)1.8 × 10-11
E)2.0 × 10-3
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
79
Calculate the minimum concentration of Mg2+ that must be added to 0.10 M NaF in order to initiate a precipitate of magnesium fluoride.[Ksp(MgF2)= 6.9 × 10-9] rev: 08_14_2014_QC_52437
A)1.4 × 107 M
B)6.9 × 10-9 M
C)6.9 × 10-8 M
D)1.7 × 10-7 M
E)6.9 × 10-7 M
A)1.4 × 107 M
B)6.9 × 10-9 M
C)6.9 × 10-8 M
D)1.7 × 10-7 M
E)6.9 × 10-7 M
Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck
80
What is the ion product expression for magnesium fluoride,MgF2?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

Unlock Deck
Unlock for access to all 129 flashcards in this deck.
Unlock Deck
k this deck