Deck 15: Acids and Bases
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Deck 15: Acids and Bases
1
The OH- concentration in a 7.5 * 10-3 M Ca(OH)2 solution is
A) 7.5 * 10-3 M.
B) 1.5 * 10-2 M.
C) 1.3 * 10-12 M.
D) 1.0 * 10-7 M.
E) 1.0 * 10-14 M.
A) 7.5 * 10-3 M.
B) 1.5 * 10-2 M.
C) 1.3 * 10-12 M.
D) 1.0 * 10-7 M.
E) 1.0 * 10-14 M.
1.5 * 10-2 M.
2
Which of the following is not a conjugate acid-base pair
A) H3PO4 and H2PO4-
B) H2PO4- and HPO42-
C) H3PO4 and HPO42-
D) HPO42- and PO43-
E) H2O and H3O+
A) H3PO4 and H2PO4-
B) H2PO4- and HPO42-
C) H3PO4 and HPO42-
D) HPO42- and PO43-
E) H2O and H3O+
H3PO4 and HPO42-
3
The hydronium ion and the hydroxide ion, in that order, are:
A) H3O+, OH+
B) OH-, H3O-
C) OH-, H+
D) H3O+, OH-
E) H3O-, OH-
A) H3O+, OH+
B) OH-, H3O-
C) OH-, H+
D) H3O+, OH-
E) H3O-, OH-
H3O+, OH-
4
Identify the conjugate base of HSO4-.
A) OH-
B) H2SO4
C) H2O
D) H2SO3
E) SO42-
A) OH-
B) H2SO4
C) H2O
D) H2SO3
E) SO42-
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5
What is the H+ ion concentration in a 4.8 * 10-2 M KOH solution
A) 4.8 * 10-2 M
B) 1.0 * 10-7 M
C) 4.8 * 10-11 M
D) 4.8 * 10-12 M
E) 2.1 * 10-13 M
A) 4.8 * 10-2 M
B) 1.0 * 10-7 M
C) 4.8 * 10-11 M
D) 4.8 * 10-12 M
E) 2.1 * 10-13 M
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6
In the reaction: 2H2O(l) H3O+(aq) + OH- (aq) the conjugate acid-base pairs are
A) pair 1: H2O and H2O; pair 2: H3O+ and OH-
B) pair 1: H3O+ and OH-; pair 2: H3O+ and H2O
C) pair 1: H3O+ and OH-; pair 2: OH- and H2O
D) pair 1: H2O and OH-; pair 2: H2O and H3O+
E) pair 1: H3O+ and HO-: pair 2: OH- and H3O+
A) pair 1: H2O and H2O; pair 2: H3O+ and OH-
B) pair 1: H3O+ and OH-; pair 2: H3O+ and H2O
C) pair 1: H3O+ and OH-; pair 2: OH- and H2O
D) pair 1: H2O and OH-; pair 2: H2O and H3O+
E) pair 1: H3O+ and HO-: pair 2: OH- and H3O+
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7
The OH- concentration in a 1.0 * 10-3 M Ba(OH)2 solution is
A) 0.50 * 10-3 M.
B) 1.0 * 10-3 M.
C) 2.0 * 10-3 M.
D) 1.0 * 10-2 M.
E) 0.020 M.
A) 0.50 * 10-3 M.
B) 1.0 * 10-3 M.
C) 2.0 * 10-3 M.
D) 1.0 * 10-2 M.
E) 0.020 M.
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8
Which of the following does not fit the definition of a Brønsted Base
A) CO32-
B) NH3
C) H2O
D) NH4+
E) HCO3-
A) CO32-
B) NH3
C) H2O
D) NH4+
E) HCO3-
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9
The OH- concentration in a 2.5 * 10-3 M Ba(OH)2 solution is
A) 4.0 * 10-12 M.
B) 2.5 * 10-3 M.
C) 5.0 * 10-3 M.
D) 1.2 * 10-2 M.
E) 0.025 M.
A) 4.0 * 10-12 M.
B) 2.5 * 10-3 M.
C) 5.0 * 10-3 M.
D) 1.2 * 10-2 M.
E) 0.025 M.
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10
Which of the following does not fit the definition of a Brønsted Acid
A) H3PO4
B) H2PO4-
C) H2O
D) NH4+
E) CO2
A) H3PO4
B) H2PO4-
C) H2O
D) NH4+
E) CO2
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11
Identify the conjugate acid of HCO3-.
A) H2O
B) CO32-
C) H2CO3
D) CO2
E) H3O+
A) H2O
B) CO32-
C) H2CO3
D) CO2
E) H3O+
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12
In the reaction: CH3COOH(aq) + NH2- (aq) CH3COO- (aq) + NH3(aq), the conjugate acid-base pairs are:
A) pair 1: CH3COOH and CH3COO- ; pair 2: NH2- and NH3
B) pair 1: CH3COOH and NH3; pair 2: NH2- and CH3COO-
C) pair 1: CH3COOH and NH2- ; pair 2: NH3 and CH3OO-
D) pair 1: CH3COOH and CH3COO- ; pair 2: NH4+ and NH3
E) pair 1: CH3COOH and CH3COO- ; pair 2: NH2- and NH3+
A) pair 1: CH3COOH and CH3COO- ; pair 2: NH2- and NH3
B) pair 1: CH3COOH and NH3; pair 2: NH2- and CH3COO-
C) pair 1: CH3COOH and NH2- ; pair 2: NH3 and CH3OO-
D) pair 1: CH3COOH and CH3COO- ; pair 2: NH4+ and NH3
E) pair 1: CH3COOH and CH3COO- ; pair 2: NH2- and NH3+
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13
Which of the following is not a conjugate acid-base pair
A) H2O and OH-
B) H2O and H3O+
C) H3O+ and OH-
D) HO2- and H2O2
E) O22- and HO2-
A) H2O and OH-
B) H2O and H3O+
C) H3O+ and OH-
D) HO2- and H2O2
E) O22- and HO2-
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14
What is the concentration of H+ in a 2.5 M HCl solution
A) 0
B) 1.3 M
C) 2.5 M
D) 5.0 M
E) 10. M
A) 0
B) 1.3 M
C) 2.5 M
D) 5.0 M
E) 10. M
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15
In the reaction HSO4-(aq) + OH-(aq) SO42-(aq) + H2O(l), the conjugate acid-base pairs are
A. and and
B. and and .
C. and and .
D. and and
E. and and
A) A
B) B
C) C
D) D
E) E
A. and and
B. and and .
C. and and .
D. and and
E. and and
A) A
B) B
C) C
D) D
E) E
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16
Identify the conjugate base of HCO3-.
A) H2CO3
B) CO32-
C) OH-
D) CO2
E) CO
A) H2CO3
B) CO32-
C) OH-
D) CO2
E) CO
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17
Identify the conjugate base of HPO42-.
A) H2O
B) H2PO4-
C) H3PO4
D) PO43-
E) OH-
A) H2O
B) H2PO4-
C) H3PO4
D) PO43-
E) OH-
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18
Identify the conjugate acid of SO42-.
A) H2SO4
B) HSO4-
C) H2SO3
D) H3O+
E) SO32-
A) H2SO4
B) HSO4-
C) H2SO3
D) H3O+
E) SO32-
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19
Which one of these statements about strong acids is true
A) All strong acids have H atoms bonded to electronegative oxygen atoms.
B) Strong acids are 100% ionized in water.
C) The conjugate base of a strong acid is itself a strong base.
D) Strong acids are very concentrated acids.
E) Strong acids produce solutions with a higher pH than weak acids.
A) All strong acids have H atoms bonded to electronegative oxygen atoms.
B) Strong acids are 100% ionized in water.
C) The conjugate base of a strong acid is itself a strong base.
D) Strong acids are very concentrated acids.
E) Strong acids produce solutions with a higher pH than weak acids.
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20
Identify the conjugate acid of CO32-.
A) H2CO3
B) HCO3-
C) H2O
D) H3O+
E) CO2
A) H2CO3
B) HCO3-
C) H2O
D) H3O+
E) CO2
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21
Calculate the H+ ion concentration in lemon juice having a pH of 2.40.
A) 4.0 * 10-2 M
B) 250 M
C) 0.38 M
D) 4.0 * 10-3 M
E) 12 M
A) 4.0 * 10-2 M
B) 250 M
C) 0.38 M
D) 4.0 * 10-3 M
E) 12 M
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22
Which of the following solutions is acidic
A) [OH-] = 1.0 x 10-7 M
B) [OH-] > 1.0 x 10-7 M
C) [OH-] = 1.0 x 10-10 M
D) [H3O+] = 1.0 x 10-10 M
E) [H3O+] < 1.0 x 10-7 M
A) [OH-] = 1.0 x 10-7 M
B) [OH-] > 1.0 x 10-7 M
C) [OH-] = 1.0 x 10-10 M
D) [H3O+] = 1.0 x 10-10 M
E) [H3O+] < 1.0 x 10-7 M
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23
Calculate the pH of a 0.14 M HNO2 solution that is 5.7% ionized.
A) 0.85
B) 1.70
C) 2.10
D) 11.90
E) 13.10
A) 0.85
B) 1.70
C) 2.10
D) 11.90
E) 13.10
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24
What is the pH of 10.0 mL of 0.0020 M HCl
A) 0.70
B) 2.70
C) 3.70
D) 5.70
E) 10.0
A) 0.70
B) 2.70
C) 3.70
D) 5.70
E) 10.0
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25
Determine the pH of a KOH solution made by mixing 0.251 g KOH with enough water to make 1.0 * 102 mL of solution.
A) 1.35
B) 2.35
C) 7.00
D) 11.65
E) 12.65
A) 1.35
B) 2.35
C) 7.00
D) 11.65
E) 12.65
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26
A 0.10 M NH3 solution is 1.3% ionized. Calculate the H+ ion concentration.NH3 + H2O NH4+ + OH-
A) 1.3 * 10-3 M
B) 7.7 * 10-2 M
C) 7.7 * 10-12 M
D) 0.13 M
E) 0.10 M
A) 1.3 * 10-3 M
B) 7.7 * 10-2 M
C) 7.7 * 10-12 M
D) 0.13 M
E) 0.10 M
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27
What is the OH- ion concentration in a 5.2 * 10-4 M HNO3 solution
A) 1.9 * 10-11 M
B) 1.0 * 10-7 M
C) 5.2 * 10-4 M
D) 0
E) 1.0 * 10-4 M
A) 1.9 * 10-11 M
B) 1.0 * 10-7 M
C) 5.2 * 10-4 M
D) 0
E) 1.0 * 10-4 M
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28
What is the pH of a 0.0055 M HA (weak acid) solution that is 8.2% ionized
A) 2.26
B) 3.35
C) 4.52
D) 8.21
E) 10.65
A) 2.26
B) 3.35
C) 4.52
D) 8.21
E) 10.65
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29
Calculate the pH of a 6.7 * 10-2 M NaOH solution.
A) 12.83
B) 2.17
C) 11.82
D) 6.71
E) 1.17
A) 12.83
B) 2.17
C) 11.82
D) 6.71
E) 1.17
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30
Calculate the pH of a carbonated beverage in which the hydrogen ion concentration is 3.4 * 10-4 M.
A) 2.34
B) 3.47
C) 6.01
D) 7.99
E) 10.53
A) 2.34
B) 3.47
C) 6.01
D) 7.99
E) 10.53
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31
Which of the following solutions is basic
A) [H3O+] = 1.0 x 10-10 M
B) [OH-] = 1.0 x 10-10 M
C) [H3O+] > 1.0 x 10-7 M
D) [OH-] < 1.0 x 10-10 M
E) [OH-] = 1.0 x 10-7 M
A) [H3O+] = 1.0 x 10-10 M
B) [OH-] = 1.0 x 10-10 M
C) [H3O+] > 1.0 x 10-7 M
D) [OH-] < 1.0 x 10-10 M
E) [OH-] = 1.0 x 10-7 M
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32
Calculate the pH of a 3.5 * 10-3 M HNO3 solution.
A) -2.46
B) 0.54
C) 2.46
D) 3.00
E) 3.46
A) -2.46
B) 0.54
C) 2.46
D) 3.00
E) 3.46
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33
Which of the following solutions is basic
A) [OH-] = 1.0 x 10-14 M
B) [OH-] = 1.0 x 10-7 M
C) [H3O+] = 1.0 x 10-14 M
D) [H3O+] > 1.0 x 10-7 M
E) [OH-] < 1.0 x 10-7 M
A) [OH-] = 1.0 x 10-14 M
B) [OH-] = 1.0 x 10-7 M
C) [H3O+] = 1.0 x 10-14 M
D) [H3O+] > 1.0 x 10-7 M
E) [OH-] < 1.0 x 10-7 M
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34
Calculate the pH of a 0.10 M HCN solution that is 0.0070% ionized.
A) 1.00
B) 0.00070
C) 3.15
D) 5.15
E) 7.00
A) 1.00
B) 0.00070
C) 3.15
D) 5.15
E) 7.00
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35
A 0.14 M HNO2 solution is 5.7% ionized. Calculate the H+ ion concentration.
A) 8.0 * 10-3 M
B) 0.057 M
C) 0.13 M
D) 0.14 M
E) 0.80 M
A) 8.0 * 10-3 M
B) 0.057 M
C) 0.13 M
D) 0.14 M
E) 0.80 M
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36
Calculate the H+ ion concentration in a 8.8 * 10-4 M Ca(OH)2 solution.
A) 8.8 * 10-4 M
B) 1.8 * 10-3 M
C) 2.2 * 10-11 M
D) 1.1 * 10-11 M
E) 5.7 * 10-12 M
A) 8.8 * 10-4 M
B) 1.8 * 10-3 M
C) 2.2 * 10-11 M
D) 1.1 * 10-11 M
E) 5.7 * 10-12 M
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37
Which of the following solutions is acidic
A) [H3O+] = 7.0 x 10-7 M
B) [H3O+] = 1.5 x 10-10 M
C) [H3O+] < 7.0 x 10-7 M
D) [H3O+] > 7.0 x 10-7 M
E) [H3O+] = 1.0 x 10-14 M
A) [H3O+] = 7.0 x 10-7 M
B) [H3O+] = 1.5 x 10-10 M
C) [H3O+] < 7.0 x 10-7 M
D) [H3O+] > 7.0 x 10-7 M
E) [H3O+] = 1.0 x 10-14 M
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38
A 0.10 M HF solution is 8.4% ionized. Calculate the H+ ion concentration.
A) 0.84 M
B) 0.12 M
C) 0.10 M
D) 0.084 M
E) 8.4 * 10-3 M
A) 0.84 M
B) 0.12 M
C) 0.10 M
D) 0.084 M
E) 8.4 * 10-3 M
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39
Consider the weak acid CH3COOH (acetic acid). If a 0.048 M CH3COOH solution is 5.2% ionized, determine the [H3O+] concentration at equilibrium.
A) 0.25 M
B) 9.2 * 10-3 M
C) 0.048 M
D) 0.052 M
E) 2.5 * 10-3 M
A) 0.25 M
B) 9.2 * 10-3 M
C) 0.048 M
D) 0.052 M
E) 2.5 * 10-3 M
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40
Calculate the pH of 2.6 *10-2 M KOH.
A) 12.41
B) 15.59
C) 2.06
D) 7.00
E) 1.59
A) 12.41
B) 15.59
C) 2.06
D) 7.00
E) 1.59
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41
The pH of tomato juice is about 4.5. Calculate the concentration of hydrogen ions in this juice.
A) 3 * 10-10 M
B) 3 * 10-5 M
C) 5 * 10-4 M
D) 4 M
E) 3 * 1010 M
A) 3 * 10-10 M
B) 3 * 10-5 M
C) 5 * 10-4 M
D) 4 M
E) 3 * 1010 M
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42
Calculate the hydrogen ion concentration in a solution having a pH of 4.60.
A) 4.0 * 10-3 M
B) 4.0 * 10-9 M
C) 4.0 * 10-10 M
D) 2.5 * 10-5 M
E) 2.5 * 10-4 M
A) 4.0 * 10-3 M
B) 4.0 * 10-9 M
C) 4.0 * 10-10 M
D) 2.5 * 10-5 M
E) 2.5 * 10-4 M
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43
The pOH of a solution is 10.40. Calculate the hydrogen ion concentration in the solution.
A) 4.0 * 10-11 M
B) 3.6 M
C) 4.0 * 10-10 M
D) 2.5 * 10-4 M
E) 1.8 * 10-4 M
A) 4.0 * 10-11 M
B) 3.6 M
C) 4.0 * 10-10 M
D) 2.5 * 10-4 M
E) 1.8 * 10-4 M
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44
If the pH of an acid rain storm is approximately 3.0, how many times greater is the [H+] in the rain than in a cup of coffee having a pH of 5.0
A) 1000
B) 100
C) 20
D) 1.7
E) 0.60
A) 1000
B) 100
C) 20
D) 1.7
E) 0.60
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45
A 5.5 L sample of a 0.25 M HNO3 solution is mixed with 1.2 L of a 0.34 M HCl solution. What is the pH of the mixture
A) 0.23
B) 0.57
C) 1.07
D) 0.50
E) 0.84
A) 0.23
B) 0.57
C) 1.07
D) 0.50
E) 0.84
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46
What is the pH of a solution prepared by mixing 10.0 mL of a strong acid solution with pH = 2.0 and 10.0 mL of a strong acid solution with pH = 6.0
A) 2.0
B) 2.3
C) 4.0
D) 6.0
E) 8.0
A) 2.0
B) 2.3
C) 4.0
D) 6.0
E) 8.0
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47
Diet cola drinks have a pH of about 3.0, while milk has a pH of about 7.0. How many times greater is the H3O+ concentration in diet cola than in milk
A) 2.3 times higher in diet cola than in milk
B) 400 times higher in diet cola than in milk
C) 0.43 times higher in diet cola than in milk
D) 1,000 times higher in diet cola than in milk
E) 10,000 times higher in diet cola than in milk
A) 2.3 times higher in diet cola than in milk
B) 400 times higher in diet cola than in milk
C) 0.43 times higher in diet cola than in milk
D) 1,000 times higher in diet cola than in milk
E) 10,000 times higher in diet cola than in milk
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48
The pH of a Ba(OH)2 solution is 10.00. What is the H+ ion concentration of this solution
A) 4.0 * 10-11 M
B) 1.6 * 10-10 M
C) 1.3 * 10-5 M
D) 1.0 * 10-10 M
E) 10. M
A) 4.0 * 10-11 M
B) 1.6 * 10-10 M
C) 1.3 * 10-5 M
D) 1.0 * 10-10 M
E) 10. M
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49
What is the pH of a 0.014 M Ca(OH)2 solution
A) 1.85
B) 1.55
C) 12.15
D) 12.45
E) 15.85
A) 1.85
B) 1.55
C) 12.15
D) 12.45
E) 15.85
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50
A 1.5 L sample of a 0.44 M HBr solution is mixed with 2.2 L of a 0.080 M HClO4 solution. What is the pH of the mixture
A) 0.28
B) 0.36
C) 1.45
D) 0.73
E) 0.65
A) 0.28
B) 0.36
C) 1.45
D) 0.73
E) 0.65
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51
What is the pH of a 0.001 M Ca(OH)2 solution
A) 3.0
B) 11.0
C) 2.7
D) 17.0
E) 11.3
A) 3.0
B) 11.0
C) 2.7
D) 17.0
E) 11.3
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52
The pOH of a solution is 9.60. Calculate the hydrogen ion concentration in this solution.
A) 2.5 * 10-10 M
B) 6.0 * 10-9 M
C) 4.0 * 10-5 M
D) 2.4 * 10-4 M
E) 1.0 * 10-14 M
A) 2.5 * 10-10 M
B) 6.0 * 10-9 M
C) 4.0 * 10-5 M
D) 2.4 * 10-4 M
E) 1.0 * 10-14 M
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53
A 2.1 L sample of a 0.23 M NaOH solution is mixed with 1.9 L of a 0.021 M KOH solution. What is the pH of the mixture
A) 13.40
B) 13.12
C) 11.68
D) 12.84
E) 13.04
A) 13.40
B) 13.12
C) 11.68
D) 12.84
E) 13.04
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54
The pH of coffee is approximately 5.0. How many times greater is the [H+] in coffee than in neutral water
A) 200
B) 100
C) 5.0
D) 1.4
E) 0.01
A) 200
B) 100
C) 5.0
D) 1.4
E) 0.01
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55
Calculate the hydrogen ion concentration in a solution of iced tea with lemon having a pH of 2.87.
A) 2.9 * 10-2 M
B) 5.7 * 10-2 M
C) 1.3 * 10-3 M
D) 2.9 * 10-3 M
E) 5.7 * 10-4 M
A) 2.9 * 10-2 M
B) 5.7 * 10-2 M
C) 1.3 * 10-3 M
D) 2.9 * 10-3 M
E) 5.7 * 10-4 M
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56
Calculate the pOH for a solution with [H3O+] = 2.5 x 10-5 M
A) 4.60
B) 9.40
C) 4.0 x 10-10
D) 2.50
E) 11.50
A) 4.60
B) 9.40
C) 4.0 x 10-10
D) 2.50
E) 11.50
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57
Calculate the pH of a 1.6 M KOH solution.
A) 1.60
B) -0.20
C) 0.20
D) 14.20
E) 13.80
A) 1.60
B) -0.20
C) 0.20
D) 14.20
E) 13.80
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58
A 5.2 L sample of a 1.1 M KOH solution is mixed with 2.3 L of a 0.20 M Sc(OH)3 solution. What is the pH of the mixture
A) 13.67
B) 13.89
C) 14.11
D) 14.23
E) 13.98
A) 13.67
B) 13.89
C) 14.11
D) 14.23
E) 13.98
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59
Calculate the hydrogen ion concentration in a solution of fruit juice having a pH of 4.25.
A) 1.0 * 10-14 M
B) 5.6 * 10-5 M
C) 4.0 * 10-25 M
D) 2.5 * 10-4 M
E) 5.6 * 10-4 M
A) 1.0 * 10-14 M
B) 5.6 * 10-5 M
C) 4.0 * 10-25 M
D) 2.5 * 10-4 M
E) 5.6 * 10-4 M
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60
The pH of coffee is approximately 5.0. How many times greater is the [H3O+] in coffee than in tap water having a pH of 8.0
A) 0.62
B) 1.6
C) 30
D) 1,000
E) 1.0 * 104
A) 0.62
B) 1.6
C) 30
D) 1,000
E) 1.0 * 104
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61
Which one of these net ionic equations represents the reaction of a strong acid with a weak base
A)H+(aq) + OH-(aq) H2O(aq)
B)H+(aq) + CH3NH2(aq) CH3NH3+(aq)
C)OH-(aq) + HCN(aq) H2O(aq) + CN-(aq)
D)HCN(aq) + CH3NH2(aq) CH3NH3+ (aq)+ CN-(aq)
A)H+(aq) + OH-(aq) H2O(aq)
B)H+(aq) + CH3NH2(aq) CH3NH3+(aq)
C)OH-(aq) + HCN(aq) H2O(aq) + CN-(aq)
D)HCN(aq) + CH3NH2(aq) CH3NH3+ (aq)+ CN-(aq)
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62
The equilibrium expression for the ionization of a weak monoprotic acid, HA, in water is:
A) Ka = [HA]/[OH-][H3O+]
B) Ka = [OH-][H3O+]/[HA]
C) Ka = [H3O+][HA]/[A-]
D) Ka = [H3O+][A-]/[HA]
E) Ka = [HA]/[H3O+][A-]
A) Ka = [HA]/[OH-][H3O+]
B) Ka = [OH-][H3O+]/[HA]
C) Ka = [H3O+][HA]/[A-]
D) Ka = [H3O+][A-]/[HA]
E) Ka = [HA]/[H3O+][A-]
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63
Given the following Ka values, which anion is the strongest base
A) F-
B) HCOO-
C) CN-
D) NO2-
E) CH3COO-
A) F-
B) HCOO-
C) CN-
D) NO2-
E) CH3COO-
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64
Arrange the acids HOCl, HClO3, and HClO2 in order of increasing acid strength.
A) HOCl < HClO3 < HClO2
B) HOCl < HClO2 < HClO3
C) HClO2 < HOCl < HClO3
D) HClO3 < HOCl < HClO2
E) HClO3 < HClO2 < HOCl
A) HOCl < HClO3 < HClO2
B) HOCl < HClO2 < HClO3
C) HClO2 < HOCl < HClO3
D) HClO3 < HOCl < HClO2
E) HClO3 < HClO2 < HOCl
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65
Which one of these equations represents the reaction of a weak acid with a weak base
A)H+(aq) + OH-(aq) H2O(aq)
B)H+(aq) + CH3NH2(aq) CH3NH3+(aq)
C)OH-(aq) + HCN(aq) H2O(aq) + CN-(aq)
D)HCN(aq) + CH3NH2(aq) CH3NH3+(aq) + CN-(aq)
A)H+(aq) + OH-(aq) H2O(aq)
B)H+(aq) + CH3NH2(aq) CH3NH3+(aq)
C)OH-(aq) + HCN(aq) H2O(aq) + CN-(aq)
D)HCN(aq) + CH3NH2(aq) CH3NH3+(aq) + CN-(aq)
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66
Arrange the acids HBr, H2Se, and H3As in order of increasing acid strength.
A) HBr < H2Se < H3As
B) HBr < H3As < H2Se
C) H2Se < H3As < HBr
D) H3As < H2Se < HBr
E) H3As < HBr < H2Se
A) HBr < H2Se < H3As
B) HBr < H3As < H2Se
C) H2Se < H3As < HBr
D) H3As < H2Se < HBr
E) H3As < HBr < H2Se
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67
Which one of the following equations represents the ionization of a weak base in water
A) NH3(aq) + H2O(l) NH2+(aq) + H3O+(aq)
B) NH3(aq) + H2O(l) NH4+(aq) + OH-(aq)
C) NH3(aq) + H2O(l) NH4- (aq) + OH+(aq)
D) NH3(aq) + OH-(aq) NH2- (aq) + H2O(l)
E) NH3(aq) + H3O+(aq) NH (aq) + H O(l)
A) NH3(aq) + H2O(l) NH2+(aq) + H3O+(aq)
B) NH3(aq) + H2O(l) NH4+(aq) + OH-(aq)
C) NH3(aq) + H2O(l) NH4- (aq) + OH+(aq)
D) NH3(aq) + OH-(aq) NH2- (aq) + H2O(l)
E) NH3(aq) + H3O+(aq) NH (aq) + H O(l)
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68
Arrange the acids HOBr, HBrO3, and HBrO2 in order of increasing acid strength.
A) HOBr < HBrO3 < HBrO2
B) HOBr < HBrO2 < HBrO3
C) HBrO2 < HOBr < HBrO3
D) HBrO3 < HOBr < HBrO2
E) HBrO3 < HBrO2 < HOBr
A) HOBr < HBrO3 < HBrO2
B) HOBr < HBrO2 < HBrO3
C) HBrO2 < HOBr < HBrO3
D) HBrO3 < HOBr < HBrO2
E) HBrO3 < HBrO2 < HOBr
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69
Given the following Ka values, which anion is the strongest base
A) HCO3-
B) CO32-
C) HC2O4-
D) C2O42-
E) HPO42-
A) HCO3-
B) CO32-
C) HC2O4-
D) C2O42-
E) HPO42-
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70
Arrange the acids H2Se, H2Te, and H2S in order of increasing acid strength.
A) H2S < H2Se < H2Te
B) H2S < H2Te < H2Se
C) H2Te < H2S < H2Se
D) H2Se < H2S < H2Te
E) H2Se < H2Te < H2S
A) H2S < H2Se < H2Te
B) H2S < H2Te < H2Se
C) H2Te < H2S < H2Se
D) H2Se < H2S < H2Te
E) H2Se < H2Te < H2S
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71
Calculate the pOH for a solution with [H3O+] = 3.1 x 10-9 M.
A) 3.10
B) 10.90
C) 8.51
D) 5.49
E) 3.2 x 10-6
A) 3.10
B) 10.90
C) 8.51
D) 5.49
E) 3.2 x 10-6
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72
Which one of the following equations represents the ionization of a weak monoprotic acid in water
A) HNO2(aq) + OH- (aq) H2O(l) + NO2-(aq)
B) HNO2(aq) + NH3(aq) NH4NO2(aq)
C) HNO2(aq) + H2O(l) H3O+(aq) + NO2-(aq)
D) HNO3(aq) + OH-(aq) H2O(l) + NO3-(aq)
E) NO2- (aq) + H2O(aq) HNO (aq) + OH (aq)
A) HNO2(aq) + OH- (aq) H2O(l) + NO2-(aq)
B) HNO2(aq) + NH3(aq) NH4NO2(aq)
C) HNO2(aq) + H2O(l) H3O+(aq) + NO2-(aq)
D) HNO3(aq) + OH-(aq) H2O(l) + NO3-(aq)
E) NO2- (aq) + H2O(aq) HNO (aq) + OH (aq)
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73
When comparing acid strength of binary acids HX, as X varies within a particular group of the periodic table, which one of these factors dominates in affecting the acid strength
A) bond strength
B) electron withdrawing effects
C) percent ionic character of the H-X bond
D) solubility
E) Le Châtelier's principle
A) bond strength
B) electron withdrawing effects
C) percent ionic character of the H-X bond
D) solubility
E) Le Châtelier's principle
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74
Given the following Kb values, which cation is the strongest acid
A) NH4+
B) C2H5NH3+
C) C5H6N+
D) [C8H11N4O2]+
E) [NH2NH3CO]+
A) NH4+
B) C2H5NH3+
C) C5H6N+
D) [C8H11N4O2]+
E) [NH2NH3CO]+
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75
Which solution will have the lowest pH
A) 0.25 M HClO
B) 0.25 M HClO2
C) 0.25 M HClO3
D) 0.25 M HClO4
E) 0.25 M NaClO4
A) 0.25 M HClO
B) 0.25 M HClO2
C) 0.25 M HClO3
D) 0.25 M HClO4
E) 0.25 M NaClO4
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76
Which one of the following equations represents the ionization of a weak monoprotic acid in water
A) HCN(aq) + H2O(l) H3O+(aq) + CN-(aq)
B) HCN(aq) + OH-(aq) H2O(l) + CN+(aq)
C) CN- (aq) + H2O(aq) HCN(aq) + OH-(aq)
D) HCN(aq) + OH- (aq) H2O(l) + CN-(aq)
E) HCN(aq) + NH3(aq) NH CN(aq)
A) HCN(aq) + H2O(l) H3O+(aq) + CN-(aq)
B) HCN(aq) + OH-(aq) H2O(l) + CN+(aq)
C) CN- (aq) + H2O(aq) HCN(aq) + OH-(aq)
D) HCN(aq) + OH- (aq) H2O(l) + CN-(aq)
E) HCN(aq) + NH3(aq) NH CN(aq)
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77
Which one of the following statements is true for a 0.1 M solution of a weak acid HA
A) The concentration of H+ is slightly greater than the concentration of A-.
B) The pH equals 1.0.
C) The concentration of H+ is exactly equal to the concentration of A-.
D) The pH is less than 1.0.
E) The concentration of H+ is slightly less than the concentration of A-.
A) The concentration of H+ is slightly greater than the concentration of A-.
B) The pH equals 1.0.
C) The concentration of H+ is exactly equal to the concentration of A-.
D) The pH is less than 1.0.
E) The concentration of H+ is slightly less than the concentration of A-.
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78
Which one of these net ionic equations represents the reaction of a strong acid with a strong base
A)H+(aq) + OH-(aq) H2O(aq)
B)H+(aq) + CH3NH2(aq) CH3NH3+(aq)
C)OH-(aq) + HCN(aq) H2O(aq) + CN-(aq)
D)HCN(aq) + CH3NH2(aq) CH3NH3+(aq) + CN-(aq)
A)H+(aq) + OH-(aq) H2O(aq)
B)H+(aq) + CH3NH2(aq) CH3NH3+(aq)
C)OH-(aq) + HCN(aq) H2O(aq) + CN-(aq)
D)HCN(aq) + CH3NH2(aq) CH3NH3+(aq) + CN-(aq)
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79
Which one of these equations represents the reaction of a weak acid with a strong base
A)H+(aq) + OH-(aq) H2O(aq)
B)H+(aq) + CH3NH2(aq) CH3NH3+(aq)
C)OH-(aq) + HCN(aq) H2O(aq) + CN-(aq)
D)HCN(aq) + CH3NH2(aq) CH3NH3+(aq) + CN-(aq)
A)H+(aq) + OH-(aq) H2O(aq)
B)H+(aq) + CH3NH2(aq) CH3NH3+(aq)
C)OH-(aq) + HCN(aq) H2O(aq) + CN-(aq)
D)HCN(aq) + CH3NH2(aq) CH3NH3+(aq) + CN-(aq)
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80
Which solution will have the lowest pH
A) 0.10 M HCN
B) 0.10 M HNO3
C) 0.10 M NaCl
D) 0.10 M H2CO3
E) 0.10 M NaOH
A) 0.10 M HCN
B) 0.10 M HNO3
C) 0.10 M NaCl
D) 0.10 M H2CO3
E) 0.10 M NaOH
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