Deck 15: Principles of Chemical Equilibrium
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Deck 15: Principles of Chemical Equilibrium
1
In an equilibrium process,the concentrations of products and of reactants are equal.
False
2
Changes in temperature cause change in the equilibrium position.
True
3
For which of the following reactions does Kp = Kc?
A)3 Fe(s)+ 4 H2O(g)⇌ Fe3O4(s)+ 4 H2(g)
B)C(s)+ H2O(g)⇌ CO(g)+ H2(g)
C)2 SO2(g)+ O2(g)⇌ 2 SO3(g)
D)H2(g)+ I2(s)⇌ 2 HI(g)
A)3 Fe(s)+ 4 H2O(g)⇌ Fe3O4(s)+ 4 H2(g)
B)C(s)+ H2O(g)⇌ CO(g)+ H2(g)
C)2 SO2(g)+ O2(g)⇌ 2 SO3(g)
D)H2(g)+ I2(s)⇌ 2 HI(g)
3 Fe(s)+ 4 H2O(g)⇌ Fe3O4(s)+ 4 H2(g)
4
What is the value for Kc for the reaction below if the equilibrium concentrations are [N2] = 0.025 M,[H2] = 0.0013 M and [NH3] = 0.028 M for the following reaction?
N2(g)+ 3 H2(g)⇌ 2 NH3(g)
A)8.6 × 102
B)1.4 × 107
C)1.2 × 10-3
D)7.1 × 10-8
E)7.4 × 105
N2(g)+ 3 H2(g)⇌ 2 NH3(g)
A)8.6 × 102
B)1.4 × 107
C)1.2 × 10-3
D)7.1 × 10-8
E)7.4 × 105
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5
The concentration of a pure solid is left out of a equilibrium constant expression but a pure liquid is included.
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6
What is the value for Kc if [CO] = 0.025 M,[H2] = 0.013 M and [CH3OH] = 0.0028 M for the following reaction?
CH3OH(g)⇌ CO(g)+ 2 H2(g)
A)1.5 × 10-3
B)0.12
C)6.6 × 102
D)8.6
E)9.1 × 10-7
CH3OH(g)⇌ CO(g)+ 2 H2(g)
A)1.5 × 10-3
B)0.12
C)6.6 × 102
D)8.6
E)9.1 × 10-7
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7
Both products and reactants will be present in an equilibrium reaction unless K is very small or very large.
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8
Which of the following substances present in the chemical reaction would be excluded from the equilibrium constant expression?
A)Na+(aq)
B)H2O(g)
C)Cl-(aq)
D)H2O(l)(reactant and solvent)
E)CO(g)
A)Na+(aq)
B)H2O(g)
C)Cl-(aq)
D)H2O(l)(reactant and solvent)
E)CO(g)
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9
The value of the equilibrium constant for a given reaction depends on the initial concentrations of reactants.
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10
In a system in equilibrium,two opposing reactions occur at equal rates.
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11
Choose the INCORRECT statement.
A)A certain amount of energy,called the activation energy,must be available if a reaction is to take place.
B)A reversible chemical reaction is one in which equilibrium is never established due to the constant decomposition of the products.
C)When the rate of the reverse reaction equals the rate of the forward reaction,equilibrium has been established.
D)Changes in temperature will change the value of an equilibrium constant.
E)Chemical equilibrium is a dynamic equilibrium.
A)A certain amount of energy,called the activation energy,must be available if a reaction is to take place.
B)A reversible chemical reaction is one in which equilibrium is never established due to the constant decomposition of the products.
C)When the rate of the reverse reaction equals the rate of the forward reaction,equilibrium has been established.
D)Changes in temperature will change the value of an equilibrium constant.
E)Chemical equilibrium is a dynamic equilibrium.
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12
Given that the equilibrium concentrations of [N2] = 0.035 M,[C2H2] = 0.057 M,and [HCN] = 6.8 × 10-4 M,find the value of the equilibrium constant expression for the reaction:
N2(g)+ C2H2(g)⇌ 2 HCN
A)3.4 × 10-1
B)2.9
C)4300
D)2.3 × 10-4
E)6.8 × 10-1
N2(g)+ C2H2(g)⇌ 2 HCN
A)3.4 × 10-1
B)2.9
C)4300
D)2.3 × 10-4
E)6.8 × 10-1
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13
For a solute (X)aq,in an ideal aqueous solution,its activity equals its concentration.
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14
Given the following:
I.N2O(g)+ 1/2 O2(g)⇌ 2 NO(g)Kc = 1.7 × 10-13
II.N2(g)+ O2(g)⇌ 2 NO(g)Kc = 4.1 × 10-31
Find the value of the equilibrium constant for the following equilibrium reaction:
N2(g)+ 1/2 O2(g)⇌ N2O(g)
A)7.0 × 10-44
B)4.2 × 1017
C)2.4 × 10-18
D)1.6 × 10-9
E)2.6 × 10-22
I.N2O(g)+ 1/2 O2(g)⇌ 2 NO(g)Kc = 1.7 × 10-13
II.N2(g)+ O2(g)⇌ 2 NO(g)Kc = 4.1 × 10-31
Find the value of the equilibrium constant for the following equilibrium reaction:
N2(g)+ 1/2 O2(g)⇌ N2O(g)
A)7.0 × 10-44
B)4.2 × 1017
C)2.4 × 10-18
D)1.6 × 10-9
E)2.6 × 10-22
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15
Large value for equilibrium constant K means the reaction will be less complete at the equilibrium point.
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16
One method to aid in working out equilibrium problems is the ICE table.
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17
For the following chemical equilibrium,Kp = 4.6 × 10-14 at 25 °C,find the value of Kc for this reaction at 25 °C.
2 Cl2(g)+ 2 H2O(g)⇌ 4 HCl(g)+ O2(g)
A)Kc = 1.9 × 10-15
B)Kc = 2.2 × 10-14
C)Kc = 1.1 × 10-12
D)Kc = 9.4 × 10-14
E)Kc = 4.6 × 10-14
2 Cl2(g)+ 2 H2O(g)⇌ 4 HCl(g)+ O2(g)
A)Kc = 1.9 × 10-15
B)Kc = 2.2 × 10-14
C)Kc = 1.1 × 10-12
D)Kc = 9.4 × 10-14
E)Kc = 4.6 × 10-14
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18
Reaction quotient Q will always be equal to the reaction's equilibrium constant K.
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19
Equilibrium reactions are noted by a single straight arrow for a yield sign.
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20
For the reaction: H2(g)+ I2(g)⇌ 2 HI(g),Kc = 92.0
When equilibrium concentrations of HI and I2 are [HI] = 0.115 M and [I2] = 0.250 M,the equilibrium concentration of [H2] is:
A)5.00 × 10-3 M
B)5.75 × 10-4 M
C)1.74 × 103 M
D)0.135 M
E)9.56 M
When equilibrium concentrations of HI and I2 are [HI] = 0.115 M and [I2] = 0.250 M,the equilibrium concentration of [H2] is:
A)5.00 × 10-3 M
B)5.75 × 10-4 M
C)1.74 × 103 M
D)0.135 M
E)9.56 M
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21
Choose the correct statement about the equilibrium:
N2(g)+ 3 H2(g)⇌ 2 NH3(g),Kp = 1 × 10-4
A)The rate constant for the forward reaction is greater than that of the reverse reaction.
B)Since the reaction has a high activation energy,a catalyst is not needed.
C)The equilibrium constant is given by Kp = [N2][H2]3/[NH3]2.
D)Conducting the reaction under high pressures will increase the yield of ammonia.
E)The Kp is independent of temperature.
N2(g)+ 3 H2(g)⇌ 2 NH3(g),Kp = 1 × 10-4
A)The rate constant for the forward reaction is greater than that of the reverse reaction.
B)Since the reaction has a high activation energy,a catalyst is not needed.
C)The equilibrium constant is given by Kp = [N2][H2]3/[NH3]2.
D)Conducting the reaction under high pressures will increase the yield of ammonia.
E)The Kp is independent of temperature.
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22
For the reaction: CH4(g)+ 2 H2O(g)⇌ CO2(g)+ 4 H2(g),ΔrH° = +190 kJ,when catalyst is added:
A)the reaction shifts to the right
B)the reaction shifts to the left
C)the ΔH° increases
D)the temperature increases
E)there is no change,catalyst changes reaction rate only
A)the reaction shifts to the right
B)the reaction shifts to the left
C)the ΔH° increases
D)the temperature increases
E)there is no change,catalyst changes reaction rate only
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23
For the reaction: CH4(g)+ 2 H2O(g)⇌ CO2(g)+ 4 H2(g),ΔH° = +190 kJ,when H2(g)is added:
A)the reaction shifts to the right
B)the reaction shifts to the left
C)the ΔrH° increases
D)the temperature increases
E)there is no change in equilibrium position
A)the reaction shifts to the right
B)the reaction shifts to the left
C)the ΔrH° increases
D)the temperature increases
E)there is no change in equilibrium position
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24
For the reaction: CH4(g)+ 2 H2O(g)⇌ CO2(g)+ 4 H2(g),ΔrH° = +190 kJ,when CH4 is added:
A)the reaction shifts to the right
B)the reaction shifts to the left
C)the ΔrH° increases
D)the temperature increases
E)there is no change in equilibrium position
A)the reaction shifts to the right
B)the reaction shifts to the left
C)the ΔrH° increases
D)the temperature increases
E)there is no change in equilibrium position
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25
For the reaction: 3 Fe(s)+ 4 H2O(g)⇌ Fe3O4(s)+ 4 H2(g)what is the effect on equilibrium of increasing temperature of an exothermic reaction?
A)The reaction shifts to the right.
B)There is no change.
C)The reaction shifts to the left.
D)The Kp is decreased.
E)The Kp is doubled.
A)The reaction shifts to the right.
B)There is no change.
C)The reaction shifts to the left.
D)The Kp is decreased.
E)The Kp is doubled.
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26
For the reaction: 3 Fe(s)+ 4 H2O(g)⇌ Fe3O4(s)+ 4 H2(g)what is the effect of removing H2?
A)The reaction shifts to the right.
B)There is no change.
C)The reaction shifts to the left.
D)The Kp is decreased.
E)The Kp is doubled.
A)The reaction shifts to the right.
B)There is no change.
C)The reaction shifts to the left.
D)The Kp is decreased.
E)The Kp is doubled.
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27
Consider the reaction:
CH4(g)+ 4 Cl2(g)⇌ CCl4(l)+ 4 HCl(g),ΔrH° = -398 kJ/mol
The equilibrium is displaced to the right if:
A)the temperature is raised
B)the pressure is lowered
C)some carbon tetrachloride is removed
D)some hydrogen chloride is added
E)some chlorine gas is removed
CH4(g)+ 4 Cl2(g)⇌ CCl4(l)+ 4 HCl(g),ΔrH° = -398 kJ/mol
The equilibrium is displaced to the right if:
A)the temperature is raised
B)the pressure is lowered
C)some carbon tetrachloride is removed
D)some hydrogen chloride is added
E)some chlorine gas is removed
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28
In a reaction at equilibrium involving only gases,a change in pressure of the reaction mixture shifts the position of equilibrium only when:
A)heat is absorbed by the reaction proceeding to the right
B)the gases are impure
C)the collision rate increases
D)the reaction is exothermic as written
E)the moles of gas are not equal on the two sides of the equation
A)heat is absorbed by the reaction proceeding to the right
B)the gases are impure
C)the collision rate increases
D)the reaction is exothermic as written
E)the moles of gas are not equal on the two sides of the equation
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29
Choose the correct statement about a container in which the chemical equilibrium is established:
2 SO2(g)+ O2(g)⇌ 2 SO3(g)+ heat
A)A decrease in amount of O2 will decrease the amount of SO2 present.
B)A decrease in the volume will decrease the amount of SO2 present.
C)An increase in temperature will decrease the amount of SO2 present.
D)A decrease in the amount of SO3 present will increase the amount of SO2 present.
E)An increase in amount of O2 will increase the amount of SO2 present.
2 SO2(g)+ O2(g)⇌ 2 SO3(g)+ heat
A)A decrease in amount of O2 will decrease the amount of SO2 present.
B)A decrease in the volume will decrease the amount of SO2 present.
C)An increase in temperature will decrease the amount of SO2 present.
D)A decrease in the amount of SO3 present will increase the amount of SO2 present.
E)An increase in amount of O2 will increase the amount of SO2 present.
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30
For the reaction: CH4(g)+ 2 H2O(g)⇌ CO2(g)+ 4 H2(g),ΔrH° = +190 kJ,when the temperature is raised to 1200 K:
A)the reaction shifts to the right
B)the reaction shifts to the left
C)the ΔrH° increases
D)the temperature increases
E)there is no change in equilibrium position
A)the reaction shifts to the right
B)the reaction shifts to the left
C)the ΔrH° increases
D)the temperature increases
E)there is no change in equilibrium position
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31
For the reaction 2 SO2 (g)+ O2 (g)⇌ 2 SO3 (g),Kc = 2.8 × 102 at 1000 K.If a vessel is filled with these gases such that the initial concentrations are [SO2] = 0.025 M,[O2] = 0.035 M,and [SO3] = 0.046 M,in which direction will a reaction occur and why?
A)toward products because Qc = 53
B)toward reactants because Qc = 0.019
C)toward products because Qc = 97
D)toward reactants because Qc = 2.8 × 103
E)it is at equilibrium because Qc = 1
A)toward products because Qc = 53
B)toward reactants because Qc = 0.019
C)toward products because Qc = 97
D)toward reactants because Qc = 2.8 × 103
E)it is at equilibrium because Qc = 1
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32
According to Le Chatelier's Principle:
A)an increase in pressure always causes a change in the position of equilibrium for any reaction
B)the greatest yield of ammonia in the exothermic reaction N2 + 3 H2 ⇌ 2 NH3 is attained at a high temperature
C)the equilibrium constant is increased for the reaction A + B ⇌ C if the concentration of A is increased
D)an increase of temperature causes a decrease in the value of the equilibrium constant for an exothermic reaction
E)when an equilibrium system is stressed,the system reacts to offset the stress
A)an increase in pressure always causes a change in the position of equilibrium for any reaction
B)the greatest yield of ammonia in the exothermic reaction N2 + 3 H2 ⇌ 2 NH3 is attained at a high temperature
C)the equilibrium constant is increased for the reaction A + B ⇌ C if the concentration of A is increased
D)an increase of temperature causes a decrease in the value of the equilibrium constant for an exothermic reaction
E)when an equilibrium system is stressed,the system reacts to offset the stress
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33
For the reaction CO(g)+ 3 H2(g)⇌ H2O(g)+ CH4(g),Kc = 190 at 1000 K.If a vessel is filled with these gases such that the initial concentrations are [CO] = 0.036 M,[H2] = 0.045 M,[H2O] = 0.020,M and [CH4] = 0.031 M,in which direction will a reaction occur and why?
A)toward products because Qc = 0.38
B)toward reactants because Qc = 0.24
C)toward products because Qc = 4.1
D)toward reactants because Qc = 61
E)it is at equilibrium because Qc = 190
A)toward products because Qc = 0.38
B)toward reactants because Qc = 0.24
C)toward products because Qc = 4.1
D)toward reactants because Qc = 61
E)it is at equilibrium because Qc = 190
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34
Consider the following reaction.
C(s)+ H2O(g)⇌ CO(g)+ H2(g)
At equilibrium at a certain temperature,[H2O] = 0.12 M,and [CO] = [H2] = 1.2 M.If suddenly these concentrations are increased by 0.50 M,which of the following is true?
A)more products are formed
B)Kc = 4.66
C)more H2O(g)will be formed
D)Since Kc does not change,nothing happens.
C(s)+ H2O(g)⇌ CO(g)+ H2(g)
At equilibrium at a certain temperature,[H2O] = 0.12 M,and [CO] = [H2] = 1.2 M.If suddenly these concentrations are increased by 0.50 M,which of the following is true?
A)more products are formed
B)Kc = 4.66
C)more H2O(g)will be formed
D)Since Kc does not change,nothing happens.
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35
Which factor influences the value of the equilibrium constant for a reversible reaction?
A)addition of a catalyst
B)raising the temperature
C)removing product
D)removing reactant
E)increase in mixing rate
A)addition of a catalyst
B)raising the temperature
C)removing product
D)removing reactant
E)increase in mixing rate
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36
Consider the exothermic reaction:
4 HCl(aq)+ MnO2(s)⇌ Cl2(g)+ 2 H2O(l)+ MnCl2(aq)
The equilibrium is displaced to the left if:
A)catalyst is added
B)pressure is lowered
C)temperature is lowered
D)MnCl2(aq)is added
E)MnO2(s)is added
4 HCl(aq)+ MnO2(s)⇌ Cl2(g)+ 2 H2O(l)+ MnCl2(aq)
The equilibrium is displaced to the left if:
A)catalyst is added
B)pressure is lowered
C)temperature is lowered
D)MnCl2(aq)is added
E)MnO2(s)is added
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37
Which of the following keep the equilibrium position unchanged?
A)temperature decrease
B)concentration change
C)temperature
D)pressure change
E)homogeneous catalyst
A)temperature decrease
B)concentration change
C)temperature
D)pressure change
E)homogeneous catalyst
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38
Which of the following equilibrium constants-reaction types is INCORRECT?
A)1.4 × 1083 equilibrium reaction-goes to completion.
B)1.6 × 10-23 equilibrium reaction-does not occur.
C)1.8 × 10-5 equilibrium reaction-more reactants than products at equilibrium.
D)1.0 equilibrium reaction-equal amounts of products and reactants.
E)3.2 × 103 equilibrium reaction-more reactants than products at equilibrium.
A)1.4 × 1083 equilibrium reaction-goes to completion.
B)1.6 × 10-23 equilibrium reaction-does not occur.
C)1.8 × 10-5 equilibrium reaction-more reactants than products at equilibrium.
D)1.0 equilibrium reaction-equal amounts of products and reactants.
E)3.2 × 103 equilibrium reaction-more reactants than products at equilibrium.
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39
For the reaction PCl5 (g)⇌ PCl3 (g)+ Cl2 (g)Kc = 0.0454 at 261 °C.If a vessel is filled with these gases such that the initial concentrations are [PCl5] = 0.20 M,[PCl3] = 0.20 M,and [Cl2] = 2.5 M,in which direction will a reaction occur and why?
A)toward products because Qc = 0.56
B)toward reactants because Qc = 2.5
C)toward products because Qc = 2.8
D)toward reactants because Qc = 0.0454
E)it is at equilibrium because Qc = 1
A)toward products because Qc = 0.56
B)toward reactants because Qc = 2.5
C)toward products because Qc = 2.8
D)toward reactants because Qc = 0.0454
E)it is at equilibrium because Qc = 1
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40
For the reaction CO(g)+ 3 H2(g)⇌ H2O(g)+ CH4(g),Kc = 190 at 1000 K.If a vessel is filled with these gases such that the initial concentrations are [CO] = 0.025 M,[H2] = 0.045 M,[H2O] = 0.025,M and [CH4] = 0.046 M,in which direction will a reaction occur and why?
A)toward products because Qc = 0.17
B)toward reactants because Qc = 0.0029
C)toward products because Qc = 0.35
D)toward reactants because Qc = 505
E)it is at equilibrium because Qc = 1
A)toward products because Qc = 0.17
B)toward reactants because Qc = 0.0029
C)toward products because Qc = 0.35
D)toward reactants because Qc = 505
E)it is at equilibrium because Qc = 1
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41
What will happen to the equilibrium in the reaction 2 A(g)⇌ B(g)+ C(g),Kc = 1.25 at 300 K,if a catalyst is added?
A)The reaction is forced to the right.
B)The reaction is forced to the left.
C)No change,catalyst only changes the rate.
D)Kc is increased.
E)Kc is decreased.
A)The reaction is forced to the right.
B)The reaction is forced to the left.
C)No change,catalyst only changes the rate.
D)Kc is increased.
E)Kc is decreased.
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42
For the decomposition of SO3(g),Kc = [SO2]2[O2]/[SO3]2,at equilibrium,there are 0.090 mol SO2,0.110 mol O2,0.100 mol SO3 in a 25.0-L container.What is the value of Kc?
A)3.6 × 10-3
B)0.040
C)2.23
D)0.089
E)7.89
A)3.6 × 10-3
B)0.040
C)2.23
D)0.089
E)7.89
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43
Equilibrium constant K is constant except when one varies the:
A)concentrations of the reactants
B)temperature of the reaction
C)concentration of the products
D)partial pressures of the reactants
E)K always remains constant
A)concentrations of the reactants
B)temperature of the reaction
C)concentration of the products
D)partial pressures of the reactants
E)K always remains constant
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44
For the production of NO2,Kc = [NO2]2/[NO]2[O2].At equilibrium in a 2.50 L container,there are 3.00 mol NO,4.00 mol O2 and 22.0 mol NO2.The value of Kc is ________.
A)13.4
B)33.6
C)5.38
D)0.0116
E)3.75
A)13.4
B)33.6
C)5.38
D)0.0116
E)3.75
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45
Consider the following reaction at a certain temperature.
2 SO3(g)⇌ 2 SO2(g)+ O2(g)
When the initial concentration of SO3(g)is 0.128 M,the concentration of oxygen gas at equilibrium is found to be 0.0130 M.Calculate Kc for this reaction.
A)8.45 × 10-4
B)1.62 × 10-2
C)7.64 × 10-5
D)1.47 × 10-3
2 SO3(g)⇌ 2 SO2(g)+ O2(g)
When the initial concentration of SO3(g)is 0.128 M,the concentration of oxygen gas at equilibrium is found to be 0.0130 M.Calculate Kc for this reaction.
A)8.45 × 10-4
B)1.62 × 10-2
C)7.64 × 10-5
D)1.47 × 10-3
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46
For the following reaction
O2(g)⇌ 2 O(g)
What conditions favor production of oxygen atoms?
A)high temperature and low pressure
B)high temperature and high pressure
C)low temperature and low pressure
D)low temperature and high pressure
O2(g)⇌ 2 O(g)
What conditions favor production of oxygen atoms?
A)high temperature and low pressure
B)high temperature and high pressure
C)low temperature and low pressure
D)low temperature and high pressure
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47
For CO2(g)+ H2(g)⇌ CO(g)+ H2O(g),Kc = [CO][H2]/[CO2][H2],if there are 1.43 mols each of CO and H2O,0.572 mol H2 and 4.572 mols CO2,in a 4.0 L container at equilibrium,what is Kc?
A)0.547
B)0.782
C)1.28
D)0.137
E)2.34
A)0.547
B)0.782
C)1.28
D)0.137
E)2.34
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48
Consider the following equilibrium reaction: PCl3(g)+ Cl2(g)⇌ PCl5(g)Kc = 96.2 The equilibrium constant for the decomposition of PCl5(g)to PCl3(g)and Cl2(g)is ________.
A)-Kc
B)
C)
D)
E)
A)-Kc
B)

C)

D)

E)

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49
0.75 mol of N2 and 1.20 mol of H2 are placed in a 3.0 liter container.When the reaction
N2(g)+ 3 H2(g)⇌ 2 NH3(g)reaches equilibrium,[H2] = 0.100 M.Which of the following is true?
A)[NH3] = 0.150 M
B)[NH3] = 0.200 M
C)[N2] = 0.650 M
D)[N2] = 0.250 M
E)[NH3] = [H2] = 0.05 M
N2(g)+ 3 H2(g)⇌ 2 NH3(g)reaches equilibrium,[H2] = 0.100 M.Which of the following is true?
A)[NH3] = 0.150 M
B)[NH3] = 0.200 M
C)[N2] = 0.650 M
D)[N2] = 0.250 M
E)[NH3] = [H2] = 0.05 M
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50
For the reaction;N2(g)+ 3 H2(g)⇌ 2 NH3(g),the equilibrium amount of NH3 will be increased by:
I.increasing the pressure
II.adding H2
III.removing N2
IV.decreasing the pressure
A)I,III
B)III only
C)II,III
D)I,II
E)II,IV
I.increasing the pressure
II.adding H2
III.removing N2
IV.decreasing the pressure
A)I,III
B)III only
C)II,III
D)I,II
E)II,IV
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51
Consider the reaction:
2 SO2(g)+ O2(g)⇌ 2 SO3(g),ΔrH° = -196.6 kJ/mol
The equilibrium is displaced to the left if:
A)some sulfur trioxide is removed
B)the temperature is raised
C)some sulfur dioxide is added
D)the pressure is raised
E)the temperature is lowered
2 SO2(g)+ O2(g)⇌ 2 SO3(g),ΔrH° = -196.6 kJ/mol
The equilibrium is displaced to the left if:
A)some sulfur trioxide is removed
B)the temperature is raised
C)some sulfur dioxide is added
D)the pressure is raised
E)the temperature is lowered
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52
2.5 moles H2O and 100 g of C are placed in a 50-L container.At equilibrium for the reaction C(s)+ H2O(g)⇌ CO(g)+ H2(g),[H2] = 0.040 M.Which of the following is true?
A)[CO] = 0.020 M
B)[H2O] = 0.010 M
C)no carbon is left
D)[H2O] = 0.020 M
E)[C(s)] = 0.04 M
A)[CO] = 0.020 M
B)[H2O] = 0.010 M
C)no carbon is left
D)[H2O] = 0.020 M
E)[C(s)] = 0.04 M
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53
For the reaction: CH4(g)+ 2 H2O(g)⇌ CO2(g)+ 4 H2(g),ΔrH° = +190 kJ,add N2(g)at constant volume and:
A)the reaction reacts to the right
B)the reaction reacts to the left
C)the ΔH° increases
D)the temperature increases
E)there is no change
A)the reaction reacts to the right
B)the reaction reacts to the left
C)the ΔH° increases
D)the temperature increases
E)there is no change
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54
Consider the following gas phase reaction at 25 °C.
N2(g)+ C2H2(g)⇌ 2 HCN(g)
1.600 mol N2(g)and 1.750 mol C2H2(g)are placed in a 1.000 L vessel and the mixture is allowed to react.At equilibrium,there are 1.587 mol N2(g)in the mixture.What is Kc for this reaction at 25 °C?
A)9.8 × 10-4
B)9.4 × 10-3
C)2.5 × 10-4
D)4.7 × 10-3
E)6.7 × 10-5
N2(g)+ C2H2(g)⇌ 2 HCN(g)
1.600 mol N2(g)and 1.750 mol C2H2(g)are placed in a 1.000 L vessel and the mixture is allowed to react.At equilibrium,there are 1.587 mol N2(g)in the mixture.What is Kc for this reaction at 25 °C?
A)9.8 × 10-4
B)9.4 × 10-3
C)2.5 × 10-4
D)4.7 × 10-3
E)6.7 × 10-5
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55
In a reaction at equilibrium involving only gases,a pressure change will shift the reaction only when:
A)heat is absorbed by the reaction proceeding to the right
B)the number of molecules on one side is greater than the number on the other side of the balanced equation
C)the number of molecules increases during the chemical reaction
D)the gases are impure
E)the collision rate increases
A)heat is absorbed by the reaction proceeding to the right
B)the number of molecules on one side is greater than the number on the other side of the balanced equation
C)the number of molecules increases during the chemical reaction
D)the gases are impure
E)the collision rate increases
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56
Consider the following chemical reaction at equilibrium:
2 Cl2(g)+ 2 H2O(g)⇌ 4 HCl(g)+ O2(g)
This equilibrium can be shifted to the right by:
A)removing H2O(g)from the mixture
B)adding more O2(g)to the mixture
C)adding Ne(g)to the mixture
D)decreasing the volume of the mixture
E)increasing the volume of the mixture
2 Cl2(g)+ 2 H2O(g)⇌ 4 HCl(g)+ O2(g)
This equilibrium can be shifted to the right by:
A)removing H2O(g)from the mixture
B)adding more O2(g)to the mixture
C)adding Ne(g)to the mixture
D)decreasing the volume of the mixture
E)increasing the volume of the mixture
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57
For the reaction below
CO(g)+ 2 H2(g)⇌ CH3OH(g)
The equilibrium concentrations at 483 K are [CO] = 0.0753 M,[H2] = 0.151 M,and [CH3OH] = 0.0247 M.Calculate the value of Kc.
A)14.4
B)1.09
C)2.17
D)0.0694
E)0.917
CO(g)+ 2 H2(g)⇌ CH3OH(g)
The equilibrium concentrations at 483 K are [CO] = 0.0753 M,[H2] = 0.151 M,and [CH3OH] = 0.0247 M.Calculate the value of Kc.
A)14.4
B)1.09
C)2.17
D)0.0694
E)0.917
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58
Consider the following equation:
N2O4(g)⇌ 2 NO2(g),Kc = 5.8 × 10-3
If the initial concentration of N2O4(g)= 0.040 M and the initial concentration of NO2(g)is 0 M,what is the equilibrium concentration of N2O4(g)?
A)1.7 × 10-2 M
B)1.9 × 10-2 M
C)3.3 × 10-2 M
D)2.6 × 10-2 M
E)2.3 × 10-6 M
N2O4(g)⇌ 2 NO2(g),Kc = 5.8 × 10-3
If the initial concentration of N2O4(g)= 0.040 M and the initial concentration of NO2(g)is 0 M,what is the equilibrium concentration of N2O4(g)?
A)1.7 × 10-2 M
B)1.9 × 10-2 M
C)3.3 × 10-2 M
D)2.6 × 10-2 M
E)2.3 × 10-6 M
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59
What is the equilibrium constant expression for:
4 NH3(g)+ 5 O2(g)⇌ 4 NO(g)+ 6 H2O(g)
A)
B)
C)
D)
E)
4 NH3(g)+ 5 O2(g)⇌ 4 NO(g)+ 6 H2O(g)
A)

B)

C)

D)

E)

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60
Write the equilibrium constant expression for the following reaction:
N2(g)+ 3 H2(g)⇌ 2 NH3(g)
A)
B)
C)
D)
E)
N2(g)+ 3 H2(g)⇌ 2 NH3(g)
A)

B)

C)

D)

E)

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61
Write the equilibrium expression Kc for the reaction:
Sodium sulfite(aq)+ chloric acid (aq)⇌ sodium chlorate(aq)+ sulfur dioxide(g)+ water(l).
A)
B)
C)
D)
E)
Sodium sulfite(aq)+ chloric acid (aq)⇌ sodium chlorate(aq)+ sulfur dioxide(g)+ water(l).
A)

B)

C)

D)

E)

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62
For a reaction,the reaction quotient,Qc > Kc ,the reaction ________.
A)is at equilibrium
B)is exothermic
C)shifts to the right
D)shifts to the left
E)is endothermic
A)is at equilibrium
B)is exothermic
C)shifts to the right
D)shifts to the left
E)is endothermic
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63
For the reaction:
3 Fe(s)+ 4 H2O(g)⇌ Fe3O4(s)+ 4 H2(g)
Write the expression for Kp.
A)
B)
C)
D)
E)
3 Fe(s)+ 4 H2O(g)⇌ Fe3O4(s)+ 4 H2(g)
Write the expression for Kp.
A)

B)

C)

D)

E)

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64
For the reaction 2 NO2(g)⇌ N2O4(g)Kp equals ________.
A)Kc
B)RT/Kc
C)Kc(RT)
D)Kc/RT
E)Kc(RT)2
A)Kc
B)RT/Kc
C)Kc(RT)
D)Kc/RT
E)Kc(RT)2
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65
Two moles of NH3 are initially present for the reaction:
2 NH3(g)⇌ N2(g)+ 3 H2(g)
At equilibrium there is 1.00 mol NH3.How many moles of H2 are present at equilibrium?
A)3.00 moles
B)1.00 moles
C)1.50 moles
D)0.67 moles
E)0.75 moles
2 NH3(g)⇌ N2(g)+ 3 H2(g)
At equilibrium there is 1.00 mol NH3.How many moles of H2 are present at equilibrium?
A)3.00 moles
B)1.00 moles
C)1.50 moles
D)0.67 moles
E)0.75 moles
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66
For the reaction: 3 Fe(s)+ 4 H2O(g)⇌ Fe3O4(s)+ 4 H2(g)write the expression for Kc in terms of Kp.
A)Kc = Kp
B)Kc =
C)Kc = KpRT
D)Kc =
E)Kc =
A)Kc = Kp
B)Kc =

C)Kc = KpRT
D)Kc =

E)Kc =

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67
What is the relationship between Kp and Kc for the reaction below?
4 NH3(g)+ 7 O2(g)⇌ 2 N2O4(g)+ 6 H2O(g)
A)Kp = Kc(RT)-3
B)Kc = Kp(RT)-3
C)Kp = Kc(RT)3
D)Kp = Kc(RT)
E)Kp = Kc
4 NH3(g)+ 7 O2(g)⇌ 2 N2O4(g)+ 6 H2O(g)
A)Kp = Kc(RT)-3
B)Kc = Kp(RT)-3
C)Kp = Kc(RT)3
D)Kp = Kc(RT)
E)Kp = Kc
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68
For the reaction: 3 Fe(s)+ 4 H2O(g)⇌ Fe3O4(s)+ 4 H2(g)what is the effect of adding Fe(s)?
A)The reaction shifts to the right.
B)There is no change.
C)The reaction shifts to the left.
D)Kp is decreased.
E)Kp is doubled.
A)The reaction shifts to the right.
B)There is no change.
C)The reaction shifts to the left.
D)Kp is decreased.
E)Kp is doubled.
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69
For the reaction: 2 Cl2(g)+ 2 H2O(g)⇌ 4 HCl(g)+ O2(g),Kp = 6.4 × 10-6 at 500 K.If a fixed volume is filled with initial concentrations of these gases at 227 °C such that [Cl2] = 0.5 M,[H2O] = 0.40 M,[HCl] = 0.5 M,and [O2] = 0.015 M,in which direction will the reaction proceed?
A)The reaction proceeds to the right.
B)The reaction proceeds to the left.
C)The reaction is already at equilibrium.
D)The reaction volume must be specified to answer this question.
E)The value of Kp at 25 °C must be specified to answer this question.
A)The reaction proceeds to the right.
B)The reaction proceeds to the left.
C)The reaction is already at equilibrium.
D)The reaction volume must be specified to answer this question.
E)The value of Kp at 25 °C must be specified to answer this question.
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70
Find Kp for the following reaction at 25.0 °C.
SbCl5(g)⇌ SbCl3(g)+ Cl2(g)Kc = 2.51 × 10-2
A)0.614
B)1.03 × 10-3
C)5.15 × 10-2
D)9.74 × 102
E)39.8
SbCl5(g)⇌ SbCl3(g)+ Cl2(g)Kc = 2.51 × 10-2
A)0.614
B)1.03 × 10-3
C)5.15 × 10-2
D)9.74 × 102
E)39.8
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71
Write the equilibrium constant expression for the following reaction:
2 KI(aq)+ H2O2(aq)⇌ 2 KOH(aq)+ I2(aq)
A)Kc =![<strong>Write the equilibrium constant expression for the following reaction: 2 KI(aq)+ H<sub>2</sub>O<sub>2</sub>(aq)⇌ 2 KOH(aq)+ I<sub>2</sub>(aq)</strong> A)K<sub>c</sub> = B)K<sub>c</sub> = [I<sub>2</sub>] C)K<sub>c</sub> = [I<sub>2</sub>]<sup>2 </sup> D)K<sub>c</sub> = E)K<sub>c</sub> =](https://d2lvgg3v3hfg70.cloudfront.net/TB5343/11ea7a5e_3e64_d029_89bd_ebe997943745_TB5343_11.jpg)
B)Kc = [I2]
C)Kc = [I2]2
D)Kc =![<strong>Write the equilibrium constant expression for the following reaction: 2 KI(aq)+ H<sub>2</sub>O<sub>2</sub>(aq)⇌ 2 KOH(aq)+ I<sub>2</sub>(aq)</strong> A)K<sub>c</sub> = B)K<sub>c</sub> = [I<sub>2</sub>] C)K<sub>c</sub> = [I<sub>2</sub>]<sup>2 </sup> D)K<sub>c</sub> = E)K<sub>c</sub> =](https://d2lvgg3v3hfg70.cloudfront.net/TB5343/11ea7a5e_3e64_d02a_89bd_df7723acdc71_TB5343_11.jpg)
E)Kc =![<strong>Write the equilibrium constant expression for the following reaction: 2 KI(aq)+ H<sub>2</sub>O<sub>2</sub>(aq)⇌ 2 KOH(aq)+ I<sub>2</sub>(aq)</strong> A)K<sub>c</sub> = B)K<sub>c</sub> = [I<sub>2</sub>] C)K<sub>c</sub> = [I<sub>2</sub>]<sup>2 </sup> D)K<sub>c</sub> = E)K<sub>c</sub> =](https://d2lvgg3v3hfg70.cloudfront.net/TB5343/11ea7a5e_3e64_f73b_89bd_3bd290e30bf4_TB5343_11.jpg)
2 KI(aq)+ H2O2(aq)⇌ 2 KOH(aq)+ I2(aq)
A)Kc =
![<strong>Write the equilibrium constant expression for the following reaction: 2 KI(aq)+ H<sub>2</sub>O<sub>2</sub>(aq)⇌ 2 KOH(aq)+ I<sub>2</sub>(aq)</strong> A)K<sub>c</sub> = B)K<sub>c</sub> = [I<sub>2</sub>] C)K<sub>c</sub> = [I<sub>2</sub>]<sup>2 </sup> D)K<sub>c</sub> = E)K<sub>c</sub> =](https://d2lvgg3v3hfg70.cloudfront.net/TB5343/11ea7a5e_3e64_d029_89bd_ebe997943745_TB5343_11.jpg)
B)Kc = [I2]
C)Kc = [I2]2
D)Kc =
![<strong>Write the equilibrium constant expression for the following reaction: 2 KI(aq)+ H<sub>2</sub>O<sub>2</sub>(aq)⇌ 2 KOH(aq)+ I<sub>2</sub>(aq)</strong> A)K<sub>c</sub> = B)K<sub>c</sub> = [I<sub>2</sub>] C)K<sub>c</sub> = [I<sub>2</sub>]<sup>2 </sup> D)K<sub>c</sub> = E)K<sub>c</sub> =](https://d2lvgg3v3hfg70.cloudfront.net/TB5343/11ea7a5e_3e64_d02a_89bd_df7723acdc71_TB5343_11.jpg)
E)Kc =
![<strong>Write the equilibrium constant expression for the following reaction: 2 KI(aq)+ H<sub>2</sub>O<sub>2</sub>(aq)⇌ 2 KOH(aq)+ I<sub>2</sub>(aq)</strong> A)K<sub>c</sub> = B)K<sub>c</sub> = [I<sub>2</sub>] C)K<sub>c</sub> = [I<sub>2</sub>]<sup>2 </sup> D)K<sub>c</sub> = E)K<sub>c</sub> =](https://d2lvgg3v3hfg70.cloudfront.net/TB5343/11ea7a5e_3e64_f73b_89bd_3bd290e30bf4_TB5343_11.jpg)
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72
For the reaction: 2 SO2(g)+ O2(g)⇌ 2 SO3(g),Kc = 6.9 × 1024 at 25 °C.If a reaction vessel is filled with these gases,such that [SO2] = 6.0 M,[O2] = 6.0 M and [SO3] = 6.0 M,in which direction will the reaction proceed?
A)The reaction proceeds to the right.
B)The reaction proceeds to the left.
C)The reaction is already at equilibrium.
D)The reaction volume must be specified to answer this question.
E)The value of Kp must be specified to answer this question.
A)The reaction proceeds to the right.
B)The reaction proceeds to the left.
C)The reaction is already at equilibrium.
D)The reaction volume must be specified to answer this question.
E)The value of Kp must be specified to answer this question.
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73
Consider the following hypothetical equilibrium reaction:
A2(g)+ B2(g)⇌ 2 AB(g) where Kc =
The equilibrium constant for the reaction: 2 A2(g)+ 2 B2(g)⇌ 4 AB(g)is ________.
A)
B)Kc4
C)
D)
E)Kc2
A2(g)+ B2(g)⇌ 2 AB(g) where Kc =

The equilibrium constant for the reaction: 2 A2(g)+ 2 B2(g)⇌ 4 AB(g)is ________.
A)

B)Kc4
C)

D)

E)Kc2
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74
At a certain temperature,Kc = 0.0500 and △rH° = +39.6 kJ for the reaction below.
2 MgCl2(s)+ O2(g)⇌ 2 MgO(s)+ 2 Cl2(g)
Calculate Kc for the reaction
MgO(s)+ Cl2(g)⇌ MgCl2(s)+ 1/2 O2(g)
And indicate whether its value will be larger or smaller at a lower temperature.
A)4.47,larger
B)400,smaller
C)0.224,larger
D)0.224,smaller
E)0.0025,smaller
2 MgCl2(s)+ O2(g)⇌ 2 MgO(s)+ 2 Cl2(g)
Calculate Kc for the reaction
MgO(s)+ Cl2(g)⇌ MgCl2(s)+ 1/2 O2(g)
And indicate whether its value will be larger or smaller at a lower temperature.
A)4.47,larger
B)400,smaller
C)0.224,larger
D)0.224,smaller
E)0.0025,smaller
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75
Write the equilibrium constant expression for the following reaction:
6 CO2(g)+ 6 H2O(l)⇌ C6H12O6(s)+ 6 O2(g)
A)Kc =
B)Kc =
C)Kc =
D)Kc =
E)Kc =
6 CO2(g)+ 6 H2O(l)⇌ C6H12O6(s)+ 6 O2(g)
A)Kc =

B)Kc =

C)Kc =

D)Kc =

E)Kc =

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76
Write the equilibrium constant expression for the reaction:
3 Sn(s)+ 4 HNO3(aq)+ H2O(l)⇌ 3 H2SnO3(s)+ 4 NO(g)
A)Kc =
B)Kc =
C)Kc =
D)Kc =
E)Kc =
3 Sn(s)+ 4 HNO3(aq)+ H2O(l)⇌ 3 H2SnO3(s)+ 4 NO(g)
A)Kc =

B)Kc =

C)Kc =

D)Kc =

E)Kc =

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77
In the reaction:
2 N2O(g)+ N2H4(g)⇌ 3 N2(g)+ 2 H2O(g),
One starts with 0.10 mol N2O and 0.25 mol N2H4 in a 10.0 L container.If there are 0.06 mol N2O at equilibrium,how many moles of N2 are present?
A)0.02
B)0.04
C)0.06
D)0.09
E)0.07
2 N2O(g)+ N2H4(g)⇌ 3 N2(g)+ 2 H2O(g),
One starts with 0.10 mol N2O and 0.25 mol N2H4 in a 10.0 L container.If there are 0.06 mol N2O at equilibrium,how many moles of N2 are present?
A)0.02
B)0.04
C)0.06
D)0.09
E)0.07
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78
For 2 NO2(g)⇌ N2O4(g),Kc = [N2O4]/[NO2]2.At equilibrium there are 0.0270 mol N2O4 and 0.450 mol NO2 in a 50.0-L container.What is Kc?
A)0.00267
B)6.81
C)6.67
D)0.133
E)2.45
A)0.00267
B)6.81
C)6.67
D)0.133
E)2.45
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79
Given the following reactions,
2 PCl3(g)⇌ 2 P(g)+ 3 Cl2(g)Kc = 0.0667
PCl3(g)+ Cl2(g)⇌ PCl5(g)Kc = 4.0
Calculate Kc for the reaction below.
2 P(g)+ 5 Cl2(g)⇌ 2 PCl5(g)
A)240
B)1.1
C)60
D)23
E)0.41
2 PCl3(g)⇌ 2 P(g)+ 3 Cl2(g)Kc = 0.0667
PCl3(g)+ Cl2(g)⇌ PCl5(g)Kc = 4.0
Calculate Kc for the reaction below.
2 P(g)+ 5 Cl2(g)⇌ 2 PCl5(g)
A)240
B)1.1
C)60
D)23
E)0.41
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80
For the reaction 2 A(g)⇌ B(g)+ C(g),Kc = 1.25 at 300 K.If a 1.00 L mixture contains 0.619 mol A,0.693 mol B,and 0.689 mol C at 300 K,will the mixture be in equilibrium? If not,in what direction will a net reaction occur?
A)Yes,reaction is at equilibrium.
B)No,net reaction proceeds to the left.
C)No,net reaction proceeds to the right.
D)No,but there is no net reaction.
E)Yes,net reaction proceeds to the right
A)Yes,reaction is at equilibrium.
B)No,net reaction proceeds to the left.
C)No,net reaction proceeds to the right.
D)No,but there is no net reaction.
E)Yes,net reaction proceeds to the right
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