Deck 6: Organic Chemistry
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Deck 6: Organic Chemistry
1
Which of these statements about alkanes is not correct?
A)Alkanes are nonpolar.
B)Alkanes are nonflammable.
C)Carbon must always form four bonds.
D)Alkanes have a general formula CnH2n +2.
E)There are no carbon to carbon double bonds.
A)Alkanes are nonpolar.
B)Alkanes are nonflammable.
C)Carbon must always form four bonds.
D)Alkanes have a general formula CnH2n +2.
E)There are no carbon to carbon double bonds.
Alkanes are nonflammable.
2
Which of these statements about alkanes is not correct?
A)Alkanes are nonpolar.
B)Alkanes have a general formula CnH2n+ 2.
C)Hydrogen is always at a terminal position.
D)Alkanes with a carbon chain of four or less are liquids.
E)There are no carbon to carbon double bonds.
A)Alkanes are nonpolar.
B)Alkanes have a general formula CnH2n+ 2.
C)Hydrogen is always at a terminal position.
D)Alkanes with a carbon chain of four or less are liquids.
E)There are no carbon to carbon double bonds.
Alkanes with a carbon chain of four or less are liquids.
3
Which of these was the first organic compound ever synthesized from an inorganic one?
A)alkane
B)aspirin
C)alcohol
D)gasoline
E)urea
A)alkane
B)aspirin
C)alcohol
D)gasoline
E)urea
urea
4
Which of these elements is the basis for organic chemistry?
A)hydrogen
B)nitrogen
C)sodium
D)carbon
E)chlorine
A)hydrogen
B)nitrogen
C)sodium
D)carbon
E)chlorine
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5
Which of these statements best explains the designation "organic"?
A)Any naturally occurring substance.
B)Any substance which contains carbon.
C)Any substance which contains ionic bonds.
D)Any substance which is formed by synthetic means.
E)A substance which must be formed as a result of vitalism.
A)Any naturally occurring substance.
B)Any substance which contains carbon.
C)Any substance which contains ionic bonds.
D)Any substance which is formed by synthetic means.
E)A substance which must be formed as a result of vitalism.
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6
Which of the following is true of a hydrocarbon?
A)It consists of carbon and hydrogen atoms.
B)It can form a ring structure.
C)It is a good fuel for combustion reactions.
D)It can contain double or triple bonds.
E)All of the above.
A)It consists of carbon and hydrogen atoms.
B)It can form a ring structure.
C)It is a good fuel for combustion reactions.
D)It can contain double or triple bonds.
E)All of the above.
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7
Which of these substances is not an organic compound?
I. Alcohol
II. Asprin
III. Gasoline
IV. Table salt
A)I and II
B)II and III
C)II and IV
D)II, III, and IV
E)IV only
I. Alcohol
II. Asprin
III. Gasoline
IV. Table salt
A)I and II
B)II and III
C)II and IV
D)II, III, and IV
E)IV only
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8
The belief that only living organisms could make organic compounds is known as
A)Wohlerism.
B)evolution.
C)vitalism.
D)alkanes.
E)synthesim.
A)Wohlerism.
B)evolution.
C)vitalism.
D)alkanes.
E)synthesim.
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9
Which of these can be used to represent octane?
A)C8H18
B)CH3(CH2)6CH3
C)CH3CH2CH2CH2CH2CH2CH2CH3
D)All of these are correct.
A)C8H18
B)CH3(CH2)6CH3
C)CH3CH2CH2CH2CH2CH2CH2CH3
D)All of these are correct.
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10
Which of these compounds is an organic substance?
A)CaO
B)H2O
C)PF3
D)CCl4
E)CuCl2
A)CaO
B)H2O
C)PF3
D)CCl4
E)CuCl2
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11
Which of these scientists was the first to synthesize an organic compound?
A)Wohler
B)Lewis
C)Watson
D)Dalton
E)Kekule
A)Wohler
B)Lewis
C)Watson
D)Dalton
E)Kekule
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12
Which of these alkanes would be gases at room temperature?
I. C2H6
II. C3H8
III. C5H10
IV. C6H14
V.CH4
A)I and II
B)I, II, and III
C)III and IV
D)I, II, and V
E)I and V
I. C2H6
II. C3H8
III. C5H10
IV. C6H14
V.CH4
A)I and II
B)I, II, and III
C)III and IV
D)I, II, and V
E)I and V
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13
Which of these is not an alkane?
A)C3H8
B)CH4
C)C2H2
D)C6H14
E)C4H10
A)C3H8
B)CH4
C)C2H2
D)C6H14
E)C4H10
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14
Which of these is the correct name for the structural formula?

A)ethane
B)butane
C)heptane
D)hexane
E)methane

A)ethane
B)butane
C)heptane
D)hexane
E)methane
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15
Which of these is the correct condensed structural formula for butane?
A)CH3CH2CH3
B)CH3CH2CH2CH3
C)CH3CH2=CH2CH3
D)CH3CH2HC=CHCH3
E)CH3CH2CH2CH2CH3
A)CH3CH2CH3
B)CH3CH2CH2CH3
C)CH3CH2=CH2CH3
D)CH3CH2HC=CHCH3
E)CH3CH2CH2CH2CH3
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16
How many hydrogen atoms would a straight chain or branched alkane that has 25 carbon atoms contain?
A)25
B)48
C)50
D)52
E)None of the above.
A)25
B)48
C)50
D)52
E)None of the above.
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17
Which of these is the correct name for the structural formula?

A)ethane
B)butane
C)propane
D)hexane
E)methane

A)ethane
B)butane
C)propane
D)hexane
E)methane
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18
Which of these is not a subfamily of the hydrocarbon family?
A)alkenes
B)alkynes
C)alkanes
D)All of these are correct.
E)A and B are not correct.
A)alkenes
B)alkynes
C)alkanes
D)All of these are correct.
E)A and B are not correct.
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19
Which of these is the correct condensed structural formula for pentane?
A)CH3CH2CH3
B)CH3CH2CH2CH3
C)CH3CH2=CH2CH3
D)CH3CH2HC=CHCH3
E)CH3CH2CH2CH2CH3
A)CH3CH2CH3
B)CH3CH2CH2CH3
C)CH3CH2=CH2CH3
D)CH3CH2HC=CHCH3
E)CH3CH2CH2CH2CH3
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20
Which of these alkanes would be liquids at room temperature?
I. C2H6
II. C3H8
III. C5H10
IV. C6H14
V.CH4
A)I and II
B)I, II, and III
C)III and IV
D)I, II, and V
E)I and V
I. C2H6
II. C3H8
III. C5H10
IV. C6H14
V.CH4
A)I and II
B)I, II, and III
C)III and IV
D)I, II, and V
E)I and V
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21
Which of these statements is correct?
A)Alkanes are saturated hydrocarbons.
B)Alkenes have a general formula CnH2n.
C)Alkynes are hydrocarbon chains which contain a triple bond.
D)Unsaturated hydrocarbons contain at least one multiple bond.
E)All of the above.
A)Alkanes are saturated hydrocarbons.
B)Alkenes have a general formula CnH2n.
C)Alkynes are hydrocarbon chains which contain a triple bond.
D)Unsaturated hydrocarbons contain at least one multiple bond.
E)All of the above.
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22
Which of these is the correct name for CH3CH2HC=CHCH3?
A)Pentene
B)Pentyne
C)Hexene
D)Hexyne
E)Butadiene
A)Pentene
B)Pentyne
C)Hexene
D)Hexyne
E)Butadiene
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23
Which of these represents the general formula for alkynes?
A)CnH2n+2
B)CnH2n − 2
C)CnH2n
D)C2nHn
E)Cn − 2H2n
A)CnH2n+2
B)CnH2n − 2
C)CnH2n
D)C2nHn
E)Cn − 2H2n
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24
If an alkane undergoes a reaction to become an alkene, the newly formed alkene will most likely contain _____ hydrogen atom(s)than the original alkane.
A)one more
B)two more
C)one fewer
D)two fewer
A)one more
B)two more
C)one fewer
D)two fewer
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25
Which of the following has the same molecular formula as hexane?
A)3-methylpentane
B)2,2-dimethylbutane
C)cyclohexane
D)a and b
E)All of the above
A)3-methylpentane
B)2,2-dimethylbutane
C)cyclohexane
D)a and b
E)All of the above
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26
How many carbon atoms are there in a molecule of hexane?
A)4
B)5
C)6
D)7
E)8
A)4
B)5
C)6
D)7
E)8
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27
If an alkene undergoes a reaction to become an alkane, the newly formed alkane will most likely contain _____ hydrogen atom(s)than the original alkene.
A)one more
B)two more
C)one fewer
D)two fewer
A)one more
B)two more
C)one fewer
D)two fewer
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28
Which of these is the correct name for the structure represented?

A)2-methylbutene
B)2-methyl-1-butene
C)2-methyl-2-butene
D)2,3-dimethyl-1-butene
E)2-methyl-3-ethyl-1-butene

A)2-methylbutene
B)2-methyl-1-butene
C)2-methyl-2-butene
D)2,3-dimethyl-1-butene
E)2-methyl-3-ethyl-1-butene
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29
Which of these is the correct name for CH3(CH2)4CH3?
A)Butene
B)Octane
C)Hexane
D)Nonane
E)Heptene
A)Butene
B)Octane
C)Hexane
D)Nonane
E)Heptene
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30
How many hydrogen atoms are there in a molecule of hexane?
A)10
B)11
C)12
D)13
E)14
A)10
B)11
C)12
D)13
E)14
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31
Which of these is the correct name for CH3(CH2)7CH3?
A)Butene
B)Octane
C)Hexane
D)Nonane
E)Heptene
A)Butene
B)Octane
C)Hexane
D)Nonane
E)Heptene
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32
Which of these is the correct name for CH3CH2CCH?
A)Pentene
B)Pentyne
C)Butene
D)Butyne
E)Butadiene
A)Pentene
B)Pentyne
C)Butene
D)Butyne
E)Butadiene
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33
How many isomers of butane exist?
A)2
B)3
C)4
D)5
E)6
A)2
B)3
C)4
D)5
E)6
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34
Molecules with the same chemical formula but different structural formulas are known as _____.
A)isomers
B)hydrocarbons
C)empiricals
D)stereocenters
E)radicals
A)isomers
B)hydrocarbons
C)empiricals
D)stereocenters
E)radicals
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35
How many carbon atoms would a straight chain or branched alkane that has 26 hydrogen atoms contain?
A)26
B)12
C)13
D)14
E)None of the above.
A)26
B)12
C)13
D)14
E)None of the above.
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36
How many structural isomers exist for pentane?
A)1
B)2
C)3
D)4
E)5
A)1
B)2
C)3
D)4
E)5
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37
Determine the number of structural isomers for C3H8.
A)0
B)1
C)2
D)3
E)4
A)0
B)1
C)2
D)3
E)4
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38
Which of these statements about isomers is incorrect ?
A)Isomers have the same chemical formula.
B)Isomers have different structural formulas.
C)Isomers have essentially the same properties.
D)In alkenes and alkynes, the multiple bond may be found in different locations.
E)In alkanes, the greater the number of carbon atoms the greater the number of isomers.
A)Isomers have the same chemical formula.
B)Isomers have different structural formulas.
C)Isomers have essentially the same properties.
D)In alkenes and alkynes, the multiple bond may be found in different locations.
E)In alkanes, the greater the number of carbon atoms the greater the number of isomers.
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39
Determine the number of structural isomers for C5H12.
A)2
B)3
C)4
D)5
E)6
A)2
B)3
C)4
D)5
E)6
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40
Which of these molecules is not an isomer of hexene?
A)
B)
C)
D)
A)

B)

C)

D)

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41
Which of these scientists is credited with proposing the ring structure of benzene?
A)Wohler
B)Lewis
C)Kekule
D)Dalton
E)Bohr
A)Wohler
B)Lewis
C)Kekule
D)Dalton
E)Bohr
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42
Which of these statements about benzene rings is incorrect ?
A)Benzene is a particularly stable structure.
B)Benzene rings are sometimes called aromatic rings.
C)Benzene is a six-membered ring with the formula C6H6.
D)The structure of benzene was first determined by Kekule.
E)Benzene rings are composed of six carbons held together by six double bonds.
A)Benzene is a particularly stable structure.
B)Benzene rings are sometimes called aromatic rings.
C)Benzene is a six-membered ring with the formula C6H6.
D)The structure of benzene was first determined by Kekule.
E)Benzene rings are composed of six carbons held together by six double bonds.
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43
Which of these functional groups does not contain a C=O in its general formula?
A)aldehydes
B)alcohols
C)esters
D)carboxylic acids
E)ketones
A)aldehydes
B)alcohols
C)esters
D)carboxylic acids
E)ketones
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44
Which of these is the correct name for the structure below?

A)butenol
B)isobutanol
C)2-methyl-1-propanol
D)isopropanol
E)Both C and D are correct

A)butenol
B)isobutanol
C)2-methyl-1-propanol
D)isopropanol
E)Both C and D are correct
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45
Which of these scientists is credited with the discovery of carbon's tendency to form four bonds?
A)Wohler
B)Lewis
C)Kekule
D)Dalton
E)Bohr
A)Wohler
B)Lewis
C)Kekule
D)Dalton
E)Bohr
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46
Which of these is not a polycyclic aromatic compound?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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47
Which of these is the correct name of CH3CH2HC=CHCHO?
A)pentanal
B)2-pentenal
C)pentenal
D)2-ethyl-propanal
E)benzaldehyde
A)pentanal
B)2-pentenal
C)pentenal
D)2-ethyl-propanal
E)benzaldehyde
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48
Which of these is the correct name for the structure represented?

A)3-ethyl-2-methylbutane
B)3-ethyl-2-methylpentane
C)2-ethyl-1,3-dimethylbutane
D)1,2,3-trimethylpropane
E)4,5-dimethyl-2-hexane

A)3-ethyl-2-methylbutane
B)3-ethyl-2-methylpentane
C)2-ethyl-1,3-dimethylbutane
D)1,2,3-trimethylpropane
E)4,5-dimethyl-2-hexane
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49
Which of these is the generic symbol for the functional group of aldehydes?
A)R-Cl
B)R-OH
C)
D)
E)
A)R-Cl
B)R-OH
C)

D)

E)

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50
Which of these is not correct?
A)Alkynes always contain a triple bond.
B)Alcohols contain at least one oxygen atom.
C)Amines contain at least on phosphorus atom.
D)Carboxylic acids contain at least two oxygen atoms.
E)An aldehyde contains a double bond.
A)Alkynes always contain a triple bond.
B)Alcohols contain at least one oxygen atom.
C)Amines contain at least on phosphorus atom.
D)Carboxylic acids contain at least two oxygen atoms.
E)An aldehyde contains a double bond.
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51
Which of these is the correct name of the structure below?

A)propanal
B)1-propanone
C)formaldehyde
D)3-propanal
E)benzaldehyde

A)propanal
B)1-propanone
C)formaldehyde
D)3-propanal
E)benzaldehyde
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52
Which of these is the generic symbol for the functional group of alcohols?
A)R-Cl
B)R-OH
C)
D)
E)
A)R-Cl
B)R-OH
C)

D)

E)

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53
Which of these is the correct name of the structure below?

A)2-butanone
B)butanoic acid
C)2-methyl-3-propanone
D)3 methyl-2-butanone
E)2,2-dimethyl-propanal

A)2-butanone
B)butanoic acid
C)2-methyl-3-propanone
D)3 methyl-2-butanone
E)2,2-dimethyl-propanal
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54
Which of these is the generic symbol for the functional group of ketones?
A)R-Cl
B)R-OH
C)
D)
E)
A)R-Cl
B)R-OH
C)

D)

E)

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55
Which of these statements about chlorinated hydrocarbons is incorrect ?
A)Chlorinated hydrocarbons make good solvents.
B)Chlorinated hydrocarbons are used as insecticides.
C)Chlorinated hydrocarbons are relatively unstable and reactive.
D)Chlorinated hydrocarbons decrease the flammability of hydrocarbons.
E)Chlorinated hydrocarbons have been credited with depletion of the ozone.
A)Chlorinated hydrocarbons make good solvents.
B)Chlorinated hydrocarbons are used as insecticides.
C)Chlorinated hydrocarbons are relatively unstable and reactive.
D)Chlorinated hydrocarbons decrease the flammability of hydrocarbons.
E)Chlorinated hydrocarbons have been credited with depletion of the ozone.
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56
Which of these statements about alcohols is incorrect ?
A)Alcohols are polar in nature.
B)Methanol is often used as a solvent.
C)Isopropyl alcohol is used as a disinfectant.
D)Ethanol is a component in alcoholic beverages.
E)All of these statements are correct.
A)Alcohols are polar in nature.
B)Methanol is often used as a solvent.
C)Isopropyl alcohol is used as a disinfectant.
D)Ethanol is a component in alcoholic beverages.
E)All of these statements are correct.
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57
Which of these is the correct name for the structure represented?

A)4-propyl-2-butyne
B)2,3-dimethylhexene
C)2,3-dimethylhexyne
D)1,2,3-trimethylhexyne
E)4,5-dimethyl-2-hexyne

A)4-propyl-2-butyne
B)2,3-dimethylhexene
C)2,3-dimethylhexyne
D)1,2,3-trimethylhexyne
E)4,5-dimethyl-2-hexyne
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58
Which of these scientists is credited with the creation of the insecticide DDT?
A)Wohler
B)Lewis
C)Kekule
D)Muller
E)Bohr
A)Wohler
B)Lewis
C)Kekule
D)Muller
E)Bohr
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59
Which of these does not always have a double bond?
A)Amine
B)Aldehyde
C)Ketone
D)Alkene
E)Carboxylic acid
A)Amine
B)Aldehyde
C)Ketone
D)Alkene
E)Carboxylic acid
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60
Which of these is the correct name for the structure represented?

A)2-methylhexane
B)2-methylpropane
C)2,3-dimethylbutane
D)2,3-dimethylhexane
E)2-methyl-3-ethylbutane

A)2-methylhexane
B)2-methylpropane
C)2,3-dimethylbutane
D)2,3-dimethylhexane
E)2-methyl-3-ethylbutane
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61
Which of these is the correct name of the structure below?

A)2-ethyl-4-butanone
B)2-ethylbutanoic acid
C)2-ethyl-butanal
D)2-ethyl-3-methylpropanal
E)2,3-dimethyl-propanal

A)2-ethyl-4-butanone
B)2-ethylbutanoic acid
C)2-ethyl-butanal
D)2-ethyl-3-methylpropanal
E)2,3-dimethyl-propanal
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62
Which of these families is incorrectly matched to its general formula?

A)I
B)II
C)III
D)IV
E)V

A)I
B)II
C)III
D)IV
E)V
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63
Which of these is the general formula for a carboxylic acid?
A)RCOOH
B)RCOR
C)RCOH
D)ROR
E)RCOHR
A)RCOOH
B)RCOR
C)RCOH
D)ROR
E)RCOHR
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64
Which of these would not contain a carboxylic acid?
A)cinnamon
B)wasp sting
C)sour pickles
D)lemon
E)sweat
A)cinnamon
B)wasp sting
C)sour pickles
D)lemon
E)sweat
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65
Which of these families is incorrectly matched to its general formula?

A)I
B)II
C)III
D)IV
E)V

A)I
B)II
C)III
D)IV
E)V
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66
Which of these families is incorrectly matched to its general formula?

A)I
B)II
C)III
D)IV
E)V

A)I
B)II
C)III
D)IV
E)V
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67
Which of these families is incorrectly matched to its general formula?

A)I
B)II
C)III
D)IV
E)Both I and IV are incorrect.

A)I
B)II
C)III
D)IV
E)Both I and IV are incorrect.
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68
Which of the following elements is not present in an amide?
A)carbon
B)hydrogen
C)nitrogen
D)oxygen
E)An amide contains all of these elements.
A)carbon
B)hydrogen
C)nitrogen
D)oxygen
E)An amide contains all of these elements.
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69
Which of the following types of compounds do not contain oxygen?
A)alcohols
B)aldehydes
C)amines
D)esters
E)ketones
A)alcohols
B)aldehydes
C)amines
D)esters
E)ketones
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70
Which of these statements is not correct?
A)Ketones have the -one ending.
B)Aldehydes have an -ide ending.
C)Ketones have the general formula RCOR.
D)Formaldehyde is used as a biological preservative.
E)Ketones and aldehydes are found in natural flavors and odors.
A)Ketones have the -one ending.
B)Aldehydes have an -ide ending.
C)Ketones have the general formula RCOR.
D)Formaldehyde is used as a biological preservative.
E)Ketones and aldehydes are found in natural flavors and odors.
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71
Which of these is the correct name of the structure below ?

A)Diethyl ether
B)Butanone
C)Ethyl ethlyate
D)1,4-dimethyl ethanone
E)Diethylethanal

A)Diethyl ether
B)Butanone
C)Ethyl ethlyate
D)1,4-dimethyl ethanone
E)Diethylethanal
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